Publications associées à Cathode chaude

Contrasting Views of the Electric Double Layer in Electrochemical CO2 Reduction: Continuum Models vs Molecular Dynamics

In the field of electrochemical CO2 reduction, both continuum models and molecular dynamics (MD) models have been used to understand the electric double layer (EDL). MD often focuses on the region within a few nm of the electrode, while continuum models ca ...

Amer Chemical Soc2024

Plasmonic Nanostructures for Photocatalysis: Material, Photonic and Electronic Effects

Fateme Kiani Shahvandi

Plasmonic photochemistry has a large potential to replace energy-intensive chemical processes with low-temperature, low-pressure light-driven chemical reactions. Plasmonic nanostructures have emerged as promising photocatalysts with exceptional and tunable ...

EPFL2024

A pre-fatigue training strategy to stabilize LiCoO2 at high voltage

Lei Zhang, Kangning Zhao, Rui Xia

Layered cathodes are among the most promising cathodes for high-energy-density Li-ion batteries, yet hindered by the structural degradation from both bulk strain and surface oxygen loss at high voltage (above 4.5 V). Herein, we report a pre-fatigue trainin ...

Royal Soc Chemistry2024

Gas generating membrane-less electrolyser

Demetri Psaltis, Pooria Hadikhani, Steven Alexandre Schenk

Electrolyser including a reactor (2) comprising a housing (4), fluidic channels (6a, 6b, 6c) within the housing, and electrodes (16a, 16c) comprising an anode (16a) and a cathode (16c). The fluidic channels include an inter-electrode channel (6b) arranged ...

2023

Raising the temperature on electrodes for anion exchange membrane electrolysis-activity and stability aspects

Jan Van Herle, Peter Hugh Middleton, Thomas Benjamin Ferriday

The membrane electrode assembly is the powerhouse of the anion exchange membrane water electrolyser (AEMWE), thereby placing a great importance on the associated preparation conditions. This paper investigated how annealing temperature and time impacted ac ...

ELSEVIER2023

Voltage-driven Reactivity of Liquid Ga and CuGa Nanoparticles for Electrocatalytic CO2 Reduction and Synthesis

Valery Okatenko

The rising atmospheric level of carbon dioxide, CO2, contributes to climate change and poses urgent need to find scalable solutions both to decrease its emissions and to be able to recycle it, if the goals of Paris Agreement to limit the temperature rise a ...

EPFL2023

Voltage-driven Chemical Reactions Enable the Synthesis of Tunable Liquid Ga – Metal Nanoparticles

Raffaella Buonsanti, Anna Loiudice, Pascal Alexander Schouwink, Krishna Kumar, Coline Marie Agathe Boulanger, Valery Okatenko, Alexander Nicolas Chen

Nanosized particles of liquid metals are emerging materials which hold promise for applications spanning from microelectronics to catalysis. Yet, the knowledge of their chemical reactivity is largely unknown. Here, we study the reactivity of liquid Ga and ...

2023

Versatile Electroluminescence Color-Tuning Strategy of an Efficient Light-Emitting Electrochemical Cell (LEC) by an Ionic Additive

Mohammad Khaja Nazeeruddin, Narges Yaghoobi Nia

The color-tuning strategies of solid-state light-emitting devices (ss-LEDs) are mainly focused on engineering molecular structures. In this paper, for the first time, we developed a facile strategy for tuning the electroluminescence (EL) color from orange ...

AMER CHEMICAL SOC2022

Ultrafast dynamic switching of optical response based on nonlinear hyperbolic metamaterial platform

Jiaye Wu, Qian Li

The pursuit of high-speed and on-chip optical communication systems has promoted extensive exploration of all-optical control of light-matter interactions via nonlinear optical processes. Here, we have numerically investigated the ultrafast dynamic switchi ...

Optica Publishing Group2022

Atomic doping & coating for Electrocatalysis & Li-ion batteries

Albert Claude Jean-Pierre Daubry

Molybdenum atomic-doping on bio-waste derived nitrogen-doped conductive carbon electrocatalyst was synthesized and investigated for the dinitrogen reduction to ammonia in alkaline media. The assessment of the catalytic activity was found to be non-trivial ...

EPFL2022

Energy Level Alignment at the Cobalt Phosphate/Electrolyte Interface: Intrinsic Stability vs Interfacial Chemical Reactions in 5 V Lithium Ion Batteries

Nicola Marzari, Matteo Cococcioni

The intrinsic stability of the 5 V LiCoPO4-LiCo2P3O10 thin-film (carbon-free) cathode material coated with MoO3 thin layer is studied using a comprehensive synchrotron electron spectroscopy in situ approach combined with firstprinciple calculations. The at ...

AMER CHEMICAL SOC2022

Sodium Superionic Conductors (NASICONs) as Cathode Materials for Sodium-Ion Batteries

Kangning Zhao, Guangwei He, Minmin Liu

Sodium-ion batteries (SIBs) have developed rapidly owing to the high natural abundance, wide distribution, and low cost of sodium. Among the various materials used in SIBs, sodium superion conductor (NASICON)-based electrode materials with remarkable struc ...

SPRINGERNATURE2021

Dielectric elastomer actuator

Yves Perriard, Yoan René Cyrille Civet, Jonathan André Jean-Marie Chavanne, Morgan Almanza

A dielectric elastomer actuator (1) comprising: a plurality of polymer layer (2);a plurality of stretchable electrode layers (3), each polymer layer (2) being sandwiched between two electrode layers (3) so as to control the electric field within the polyme ...

2021

Cu/Metal Oxide Hybrid Nanocrystals as Electrocatalysts for the CO2 Reduction Reaction

Seyedehbehnaz Varandili

The electrochemical CO2 reduction reaction (CO2RR) is envisioned to play a significant role in achieving carbon neutrality while contributing to storing renewable energies. Cu-based materials are among the most promising electrocatalysts. However, 16 diffe ...

EPFL2021

Towards reproducible lithium-ion battery cycling using liquid-phase transmission electron microscopy

Jing Hou

Electric vehicles (EVs) have gained widespread attention in recent years as the dominant strategy for curbing CO2 emissions through transport electrification. Lithium-ion batteries (LIBs) are currently the most suitable and almost exclusively employed ener ...

EPFL2021

Radiative cooling of carbon cluster anions C-2n+1(-) (n=3-5)

Eduardo Carrascosa Casado

Radiative cooling of carbon cluster anions C(2n+1)(-)C2n+1- (n = 3-5) is investigated using the cryogenic electrostatic ion storage ring DESIREE. Two different strategies are applied to infer infrared emission on slow (milliseconds to seconds) and ultraslo ...

SPRINGER2020

Key Performance Indicators for Decision Making in Building Energy Systems

François Maréchal, Luc Girardin, Luise Middelhauve, Alessio Santecchia

Policy makers and energy operator have the responsibility to select indicators for their mission to lead the renewable energy transition ensuring energy independence and security of supply in the context of decarbonisation of the energy mix and and/or nucl ...

2020

On-Chip Fully Integrated Field Emission Arrays for High-Voltage MEMS Applications

Vivek Subramanian

Vacuum-sealed fully integrated diode and triode field emission arrays based on Ti Spindt-type field emitters have been developed in a scalable, CMOS-compatible process directly on Si. Diode characterization in air demonstrates effective vacuum sealing and ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2020

Tribocorrosion behaviour of pure titanium in bovine serum albumin solution: A multiscale study

Anna Neus Igual Muñoz

Tribocorrosion behaviour of pure titanium in phosphate buffer saline (PBS) solution has been investigated systematically as a function of surface chemistry and bovine serum albumin (BSA) content in the solution. A ball-on-disk tribometer coupled with an el ...

ELSEVIER2020

System and method for ground consolidation

Lyesse Laloui, Dimitrios Terzis, Patrick Gabriel Yihsiu-Ming Hicher

The present invention relates to a method for inducing ground consolidation. The method comprises providing a first chamber (7) in a first hole (3) in the ground (5), and a second chamber (7) in a second hole (3) in the ground (5), the first and second cha ...

2020