Publications associées à Acrylonitrile

Biocompatible and Biodegradable 3D Printing from Bioplastics: A Review

There has been a lot of interest in developing and producing biodegradable polymers to address the current environmental problem caused by the continued usage of synthetic polymers derived from petroleum products. Bioplastics have been identified as a poss ...

MDPI2023

Slot-Die Coating of an On-the-Shelf Polymer with Increased Dielectric Permittivity for Stack Actuators

Yauhen Sheima

Nitrile-butadiene rubbers (NBR) have been extensively used as dielectric materials due to their commercial availability, excellent mechanical properties, glass transition temperature below 0 degrees C, and increased dielectric permittivity owing to the pre ...

AMER CHEMICAL SOC2022

Static and dynamic mechanical properties of nanosilica and multiwalled carbon nanotube reinforced acrylonitrile butadiene styrene composites: theoretical mechanism of nanofiller reinforcement

Thomas Keller, Harish Mohan Thettemmel

Experimental and theoretical approaches were employed to analyze the static and dynamic mechanical properties of acrylonitrile butadiene styrene (ABS) nanocomposites reinforced with multiwalled carbon nanotube (MWCNT) and nanosilica. Enhanced stiffness and ...

SPRINGER2021

Vinyl and Alkynyl Triazenes: Synthesis, Reactivity, and Applications

Kay Severin, Abdusalom Suleymanov

Aromatic compounds containing triazenyl groups (N3RR′) have a profound impact on synthetic organic and medicinal chemistry. In contrast, the chemistry of vinyl and alkynyl triazenes was a largely uncharted territory until recently. The situation has change ...

Wiley-VCH Verlag GmbH2021

Palladium-Catalyzed Synthesis of Ketenimines from Isocyanides and Synthetic Studies Towards the Total Synthesis of Mersilongine

Mathias Mamboury

In the first chapter of this thesis, the development of two new reactions for the synthesis of vinyl ketenimines and alpha-oxo-ketenimines from isocyanides is presented. These palladium-catalyzed transformations both feature an isocyanide insertion / beta- ...

EPFL2019

Data-Driven Model for the Dynamic Characteristics of O-Rings for Gas Bearing Supported Rotors

Jürg Alexander Schiffmann, Philipp Kaspar Bättig

The measurement results of various nitrile butadiene rubber (NBR) O-Ring sizes are pre-sented, and reduced-order models are developed in order to predict the stiffness and damping coefficient as a function of O-Ring geometry, Shore hardness, squeeze, and e ...

2019

Mild synthesis of mercaptonitriles from vinyl nitriles and their cyclization reactions

Frank Nüesch, Antonia Neels

Thiol-ene addition of thioacetic acid A is widely used in the synthesis of thiols from vinyl precursors, but so far has not been conducted on non-conjugated vinyl nitriles. The challenge when vinyl nitriles are used is to selectively conduct the thiol-ene ...

Royal Soc Chemistry2016

Preparation of Well-Defined Ibuprofen Prodrug Micelles by RAFT Polymerization

Jeffrey Alan Hubbell, Jutta Christine Wandrey, Urara Hasegawa

Nonsteroidal anti-inflammatory drugs (NSAIDs) are widely used to treat acute pain, fever, and inflammation and are being explored in a new indication in cancer. Side effects associated with long-term use of NSAIDs such as gastrointestinal damage and elevat ...

American Chemical Society2013

Styrene oxidation by hydrogen peroxide in ionic liquids: the role of the solvent on the competition between two Pd-catalyzed processes, oxidation and dimerization

Paul Joseph Dyson, Cinzia Chiappe

A series of hydrophilic N,N-dimethylpyrrolidinium-and N,N-dimethylpiperidinium-based ionic liquids (ILs) have been prepared and applied as reaction media in the Wacker oxidation of styrene by hydrogen peroxide using PdCl2 as the catalyst. The efficiency of ...

2011

Synthesis of Unusual Oxime Ethers by Reaction of Tetranitromethane with B-Alkylcatecholboranes

Philippe Renaud, Kurt Schenk

The reaction of tetranitromethane with B-alkylcatecholboranes leads to the formation of unusual dinitrooxime ethers. A tentative mechanism is provided, which suggests the involvement of extremely fast addition of alkyl radicals to tetranitromethane. The su ...

2010

Metallocene Catalyzed Polyolefins For Improving Thermal And Mechanical Properties Of Bitumen Blends

John Christopher Plummer, Chiara Spadaro

Bitumen is a complex viscoelastic material used as a binder in applications ranging from road paving to waterproof membranes for roofing [1]. In such applications, bitumen is often blended with a polymer in order to improve its elasticity. The resulting po ...

2010

Mechanical spectroscopy in carbon nanotube reinforced ABS

Daniele Mari, Robert Schaller

Mechanical spectroscopy has been used to qualify possible improvements of the mechanical properties of acrylonitrile-butadiene-styrene-carbon nanotubes (ABS-CNTs) composites. The properties of ABS matrix are first investigated. Two relaxations that mark th ...

2009

Chelating NHC Ruthenium(II) Complexes as Robust Homogeneous Hydrogenation Catalysts

Gabor Laurenczy, Antonia Neels

A series of ruthenium(II) N-heterocyclic carbene chelate complexes were prepd. by using bidentate chelating alkene-carbene, thioether-carbene, carboxylate-carbene and bis-carbene ligands. Metalation of 1-R-3-X-imidazolium salts (1-3, R = Me, X = allyl, MeS ...

2009

Fracture mechanisms in polystyrene/laponite nanocomposites prepared by emulsion polymerization

John Christopher Plummer, Riccardo Ruggerone

Transmission electron microscopy (TEM) has been used to investigate the effect of laponite clay on microdeformation in thin latex-based polystyrene (PS) films, in which the laponite was concentrated at the original interfaces between the PS particles. At r ...

2009

Effect of cell media on polymer coated superparamagnetic iron oxide nanoparticles (SPIONs): Colloidal stability, cytotoxicity, and cellular uptake studies

Heinrich Hofmann, Alke Fink, Benedikt Steitz, Andrija Finka, Jatuporn Salaklang

The influence of the composition of the polymer coated polyvinyl alcohol (PVA), vinyl alcohol/vinyl amine copolymer (A-PVA) and polyethylenimine (PEI) coated superparamagnetic iron oxide nanoparticles (SPIONs) on the colloidal stability, cytotoxicity and c ...

2008

Plastics

Thierry Meyer, Philip Nising

A review in 4 sections comprising synthetic methods and prodn. processes of plastics (section I), apparatuses for prodn., processing, and making of plastics (section II), manufg. processes for the most important plastics (section III), and processing of th ...

Wiley-VCH2005