Publications associées à Propriété universelle

Densification and shaping of pure Cu-BTC powders using a solid-state chemical transformation

Wendy Lee Queen, Jordi Espin Marti, Mehrdad Asgari, Mathieu Soutrenon, Vikram Vinayak Karve, Alexandre Mabillard

MOFs are a class of porous crystalline materials whose unique properties have led to applicability in several fields ranging from gas adsorption to drug delivery. Despite their high potential, MOFs are usually found as fine powders, a property that can lim ...

Iop Publishing Ltd2024

Co-Design Optimisation of Morphing Topology and Control of Winged Drones

Dario Floreano, Valentin Wüest, Fabio Bergonti

The design and control of winged aircraft and drones is an iterative process aimed at identifying a compromise of mission-specific costs and constraints. When agility is required, shape-shifting (morphing) drones represent an efficient solution. However, m ...

IEEE2024

Energy Efficient Logic and Memory Design With Beyond-CMOS Magnetoelectric Spin-Orbit (MESO) Technology Toward Ultralow Supply Voltage

Kyojin Choo

Devices based on the spin as the fundamental computing unit provide a promising beyond-complementary metal-oxide-semiconductor (CMOS) device option, thanks to their energy efficiency and compatibility with CMOS. One such option is a magnetoelectric spin-or ...

Ieee-Inst Electrical Electronics Engineers Inc2023

Conditional Flatness, Fiberwise Localizations, And Admissible Reflections

Jérôme Scherer

We extend the group-theoretic notion of conditional flatness for a localization functor to any pointed category, and investigate it in the context of homological categories and of semi-abelian categories. In the presence of functorial fiberwise localizatio ...

CAMBRIDGE UNIV PRESS2023

Opportunities, Challenges, and Pitfalls in Making, Characterizing, and Understanding Polymer Brushes

Harm-Anton Klok

Polymer brushes have been theoretically described, their behavior under diverse conditions has been modeled, and their preparation via surface-initiated polymerizations (SIPs) has been progressively refined. However, despite three decades of research endea ...

American Chemical Society2023

Enriching the Computational Toolbox for Organocatalysis

Simone Gallarati

Organocatalysis has evolved significantly over the last decades, becoming a pillar of synthetic chemistry, but traditional theoretical approaches based on quantum mechanical computations to investigate reaction mechanisms and provide rationalizations of ca ...

EPFL2023

UNDERGRAD: A Universal Black-Box Optimization Method with Almost Dimension-Free Convergence Rate Guarantees

Volkan Cevher, Kimon Antonakopoulos

Universal methods for optimization are designed to achieve theoretically optimal convergence rates without any prior knowledge of the problem’s regularity parameters or the accurarcy of the gradient oracle employed by the optimizer. In this regard, existin ...

2022

The native oxide skin of liquid metal Ga nanoparticles prevents their rapid coalescence during electrocatalysis

Raffaella Buonsanti, Anna Loiudice, Dragos-Constantin Stoian, Jan Vávra, Valery Okatenko, Laia Castilla Amorós

Liquid metals (LMs) have been used in electrochemistry since the 19th century, but it is only recently that they have emerged as electrocatalysts with unique properties, such as inherent resistance to coke-poisoning, which derives from the dynamic nature o ...

2022

Role of electric currents in the Fano resonances of connected plasmonic structures

Olivier Martin, Marco Riccardi

In this work, we use finite elements simulations to study the far field properties of two plasmonic structures, namely a dipole antenna and a cylinder dimer, connected to a pair of nanorods. We show that electrical, rather than near field, coupling between ...

2021

Local invertibility and sensitivity of atomic structure-feature mappings

Michele Ceriotti, Sergey Pozdnyakov

Background: The increasingly common applications of machine-learning schemes to atomic-scale simulations have triggered efforts to better understand the mathematical properties of the mapping between the Cartesian coordinates of the atoms and the variety o ...

2021

Adaptation in Stochastic Algorithms: From Nonsmooth Optimization to Min-Max Problems and Beyond

Ahmet Alacaoglu

Stochastic gradient descent (SGD) and randomized coordinate descent (RCD) are two of the workhorses for training modern automated decision systems. Intriguingly, convergence properties of these methods are not well-established as we move away from the spec ...

EPFL2021

Development of New Strategies of Umpolung with Cyclic Hypervalent Iodine Reagents

Paola Caramenti

Organic chemistry is essential for the development of a modern society and technical progress requires the continuous development of synthetic methodologies Novel, efficient, selective and flexible protocols are employed to access complex frameworks from s ...

EPFL2019

Unique decomposition of homogeneous languages and application to isothetic regions

Nicolas René Jean Ninin

A language is said to be homogeneous when all its words have the same length. Homogeneous languages thus form a monoid under concatenation. It becomes freely commutative under the simultaneous actions of every permutation group G(n) on the collection of ho ...

2019

Silicon nanostructures for bright field full color prints

Jürgen Brugger, Valentin Flauraud, Miguel Arnold Reyes

Nanoscale color printing has recently emerged as a unique alternative to traditional pigments by providing record spatial resolution, angular independent, durable and single material colors. Widely based on plasmonic nanostructures, numerous efforts in the ...

Amer Chemical Soc2017

Splines Are Universal Solutions of Linear Inverse Problems with Generalized TV Regularization

Michaël Unser, Julien René Pierre Fageot, John Paul Ward

Splines come in a variety of flavors that can be characterized in terms of some differential operator L. The simplest piecewise-constant model corresponds to the derivative operator. Likewise, one can extend the traditional notion of total variation by con ...

2017

Enantioselective Access to Spirocyclic Sultams by Chiral Cp-x-Rhodium(III)-Catalyzed Annulations

Nicolai Cramer, Van Manh Pham

Chiral spirocyclic sultams are a valuable compound class in organic and medicinal chemistry. A rapid entry to this structural motif involves a [3+2] annulation of an N-sulfonyl ketimine and an alkyne. Although the directing-group properties of the imino gr ...

Wiley-Blackwell2016

Laser-assisted morphing of complex three dimensional objects

Yves Bellouard, Jakub Drs

Morphing commonly refers to the smooth transition from a specific shape into another one, in which the initial and final shapes can be significantly different. In this study, we show that the concept of morphing applied to laser micro-manufacturing offers ...

Spie-Int Soc Optical Engineering2016

Scaling for hard-sphere colloidal glasses near jamming

Eric DeGiuli

Hard-sphere colloids are model systems in which to study the glass transition and universal properties of amorphous solids. Using covariance matrix analysis to determine the vibrational modes, we experimentally measure here the scaling behavior of the dens ...

IOP Publishing - EPL Association2016

Conditionally flat functors on spaces and groups

Jérôme Scherer

Consider a fibration sequence of topological spaces which is preserved as such by some functor , so that is again a fibration sequence. Pull the fibration back along an arbitrary map into the base space. Does the pullback fibration enjoy the same property? ...

Springer-Verlag Italia Srl2015

Le foncteur de bi-ensembles des modules de p-permutation

Mélanie Baumann

Let k be an algebraically closed field of characteristic p, where p is a prime number or 0. Let G be a finite group and ppk(G) be the Grothendieck group of p-permutation kG-modules. If we tensor it with C, then Cppk becomes a C-linear biset functor. Recall ...

EPFL2012