Publications associées à Zirconium

Microstructure et usinabilité d'alliages de titane béta-métastable

Titanium has become in recent years an interesting material in many applications that require a combination of high mechanical properties and low density. It has the peculiarity of undergoing an allotropic transformation at 882°C. Below this temperature, ...

EPFL2023

Liquid metal infiltration of silicon based alloys into porous carbonaceous materials Part-III: Experimental verification of conversion products and infiltration depth by infiltration of Si-Zr alloy into mixed SiC/ graphite preforms

Ludger Weber, Annapaola Parrilli, Caroline Hain, Alberto Ortona, Manoj Kondibhau Naikade

Porous carbonaceous preforms, made from graphite and silicon carbide (SiC) powders, with varying graphite powder mass fractions and particle sizes, were infiltrated at 1500 degrees C and 1700 degrees C by Si-8 at. pct Zr alloy to produce dense Si-Zr-SiC co ...

ELSEVIER SCI LTD2023

Liquid metal infiltration of silicon based alloys into porous carbonaceous materials. Part II: Experimental verification of modelling approaches by infiltration of Si-Zr alloy into idealized microchannels

Ludger Weber, Caroline Hain, Giovanni Bianchi, Alberto Ortona, Manoj Kondibhau Naikade

In this work, the mechanisms leading to the pore closure in reactive melt infiltration (RMI) of carbon by pure silicon and a near eutectic Si-8 at-pct Zr alloy at 1500 and 1700 degrees C under vacuum were studied. Various geometrical configurations of micr ...

ELSEVIER SCI LTD2022

Processability, microstructure and precipitation of a Zr-modified 2618 aluminium alloy fabricated by laser powder bed fusion

Christian Leinenbach, Xavier Maeder

Additive manufacturing offers the opportunity to produce complex geometries from novel alloys with improved properties. Adapting conventional alloys to the process-specific properties can facilitate rapid implementation of these materials in industrial pra ...

2022

Delayed Hydride Cracking in Irradiated and Unirradiated Zircaloy-2 Cladding

Aaron William Colldeweih

Zirconium alloys used in the nuclear industry are exposed to extreme conditions undergoing high levels of irradiation damage and corrosion. Zircaloy-2 is used as nuclear fuel cladding in boiling water reactors and for the encapsulation of the spallation ta ...

EPFL2022

Mapping Catalyst‐Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Nicolai Cramer, Matthew Wodrich, Anne-Clémence Corminboeuf, Miyeon Chang, Simone Gallarati

Group 9 metals, in particular Rh III complexes with cyclopentadienyl ligands, are competent C–H activation catalysts. Recently, a Cp*Rh III catalyzed reaction of alkenes with N -enoxyphthalimides showed divergent outcome based on the solvent, with carboami ...

2022

Effect of dislocations, Al-3(Sc,Zr) distribution and ageing temperature on theta ' precipitation in Al-Cu-(Sc)-(Zr) alloys

Baptiste Thomas Jean Rouxel

The 2xxx series aluminium alloys, which contain Cu as the main addition element, are widely used in the aerospace industry for their high specific strength. The main strengthening contribution in these alloys comes from the formation of theta' precipitates ...

ELSEVIER SCI LTD2020

Aqueous metal-organic solutions for YSZ thin film inkjet deposition

Andreas Stephan Lesch

Inkjet printing of 8% Y2O3-stabilized ZrO2 (YSZ) thin films is achieved by designing a novel water-based reactive ink for Drop-on-Demand (DoD) inkjet printing. The ink formulation is based on a novel chemical strategy that consists of a combination of meta ...

Royal Society of Chemistry2017

Piezoelectric softening by Nb substitution in (Ba,Pb)ZrO

Dragan Damjanovic, Nava Setter, Nicola Marzari, Alberto Biancoli, David Bahati

Donor doping is commonly applied for softening of the piezoelectric and dielectric properties and facilitation of polarization switching in the ubiquitous Pb(Zr,Ti)O-3 [PZT] ceramics. The origin of the donor-dopant effects is not entirely clear. (Pb,Ba)ZrO ...

Wiley-Blackwell2017

Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands

Rosario Scopelliti, Kay Severin, Kurt Schenk, Philip Pattison, Euro Solari, Mathieu Jérémie Marmier, Matthew David Wise

Polycarboxylate ligands are among the most important building blocks for the synthesis of metal–organic frameworks (MOFs). The ability to access these ligands in an efficient way is of key importance for future applications of MOFs. Here, we demonstrate th ...

2016

Intrinsic structural transitions of the pyramidal I 〈c+a〉 dislocation in magnesium

William Curtin, Zhaoxuan Wu

The stability of a mixed < c + a > dislocation on the pyramidal I plane in magnesium is studied using molecular dynamics simulations. The dislocation is metastable and undergoes a thermally-activated transition to either a sessile, basal-dissociated < c + ...

Elsevier2016

Morphology, structural and optical properties of iron oxide thin film photoanodes in photoelectrochemical cell: Effect of electrochemical oxidation

Yelin Hu, Artur Braun

Hematite (alpha-Fe2O3) is a promising semiconductor as photoanode in solar hydrogen production from photoelectrolysis of water due to its appropriate band gap, low cost and high electrochemical stability in aqueous caustic electrolytes. Operation of such p ...

Elsevier Science Bv2016

Critical scattering of synchrotron radiation in lead zirconate-titanate with low titanium concentrations

Alexander Tagantsev

Diffuse scattering in the lead zirconate-titanate single crystal with a titanium concentration of 0.7 at % has been studied by the synchrotron radiation scattering method. Measurements have been performed both in the vicinity of the Brillouin zone center a ...

Maik Nauka/Interperiodica/Springer2015

Structure and the Electrical Properties of Pb(Zr,Ti)O3 - Zirconia Composites

Dragan Damjanovic, Marija Kosec

In this work, the effect of introducing tetragonal yttria-stabilized zirconia (TZ) particles in soft [Pb0.98Ba0.01][(Zr0.53Ti0.47)(0.98)Nb-0.02]O-3 (PZT) was investigated. Both microstructure and electrical properties of the PZT-xTZ (x = 0, 2, 5, 10, 20 vo ...

Wiley-Blackwell2012

Tribocorrosion behavior of beta titanium alloys in physiological solutions containing synovial components

Stefano Mischler

In this work, the tribocorrosion behavior of Ti-12.5Mo, Ti-13Nb-13Zr and Ti-29Nb-13Ta-4.6Zr beta titanium alloys which are candidate biomaterials for joint prostheses is studied against ultra high molecular weight polyethylene in Hank's balanced salt solut ...

2011

Fretting-corrosion behavior of beta titanium alloys in simulated synovial fluid

Stefano Mischler

Fretting-corrosion is a material degradation process resulting from the combined action of a corrosive environment and small displacement fretting wear. In this work, the fretting-corrosion behavior of Ti-12.5Mo, Ti-13Nb-13Zr, and Ti-29Nb-13Ta-4.6Zr, beta ...

2011

Broadband Dielectric Response in Hard and Soft PZT : Understanding Softening and Hardening Mechanisms

Li Jin

Lead zirconate titanate (Pb(Zr1-xTix)O3 or PZT) ferroelectric ceramics have been widely used in transducers, actuators, and sensors, since they posses high dielectric and piezoelectric properties with a relatively high temperature of operation. Commerciall ...

EPFL2011

Structure of Zirconocene Complexes Relevant for Olefin Catalysis: Infrared Fingerprint of the Zr(C5H5)(2)(OH)(CH3CN)(+) Cation in the Gas Phase

Ulrich Lorenz

Cationic zirconocene complexes are active species in Ziegler-Natta catalysis for olefin polymerization. structure and metal-ligand bond strength strongly influence their activity. In the present work, the multiphoton dissociation (IRMPD) spectrum of mass s ...

2010

Accurate and versatile modeling of electromagnetic scattering on periodic nanostructures with a surface integral approach

Olivier Martin, Benjamin Gallinet, Andreas Kern

A surface integral formulation for light scattering on periodic structures is presented. Electric and magnetic field equations are derived on the scatterers' surfaces in the unit cell with periodic boundary conditions. The solution is calculated with the m ...

2010

Microprobe analysis of neutron irradiated and autoclaved zirconium niobium claddings using synchrotron-based hard X-ray imaging and spectroscopy

Camelia Borca

Two zirconium alloys (Zr-2.5%Nb) - one oxidized in a pressurized water reactor, the other oxidized in autoclave and used as reference - are analyzed by combining synchrotron-based scanning transmission and fluorescence X-ray microscopy and micro-X-ray abso ...

Elsevier2009