Publications associées à Processus isochore

Updates on Hydrogen Value Chain: A Strategic Roadmap

A strategic roadmap for noncarbonized fuels is a global priority, and the reduction of carbon dioxide emissions is a key focus of the Paris Agreement to mitigate the effects of rising temperatures. In this context, hydrogen is a promising noncarbonized fue ...

WILEY-V C H VERLAG GMBH2023

Why five decades of massive research on heterogeneous photocatalysis, especially on TiO2, has not yet driven to water disinfection and detoxification applications? Critical review of drawbacks and challenges

César Pulgarin, Julian Andrés Rengifo Herrera

For fifty years, heterogeneous photocatalysis has been considered as having potential to remove organic and microbiological pollutants from water under either artificial UV light or sunlight irradiation. However, after tens of thousands of published resear ...

Elsevier Science Sa2023

80 K cryogenic stage for ice lithography

Danick Briand, Rubaiyet Iftekharul Haque, Jaemin Kim

We present a cryogenic system design and development for ice lithography. The cryo-stage is designed with embedded channels to allow direct liquid nitrogen flow, enabling fast cryogenic cooling, and low sample temperature. The stage cools down to 78.8 K in ...

ELSEVIER2022

Tensor network investigation of frustrated Ising models

Jeanne Colbois

In spin systems, geometrical frustration describes the impossibility of minimizing simultaneously all the interactions in a Hamiltonian, often giving rise to macroscopic ground-state degeneracies and emergent low-temperature physics. In this thesis, combin ...

EPFL2022

On the Application of Small-Scale Turbines in Industrial Steam Networks

François Maréchal, Jürg Alexander Schiffmann, Ivan Daniel Kantor, Ansgar Weickgenannt

This study investigates the technical and economic feasibility of replacing throttling valves with smale-scale, oil-free turbomachinery in industrial steam networks. This is done from the perspective of the turbomachine, which has to be integrated into a n ...

2021

Visualization of supercritical water pseudo-boiling at Widom line crossover

Christian Ludwig, Andrea Testino

Supercritical water is a green solvent used in many technological applications including materials synthesis, nuclear engineering, bioenergy, or waste treatment and it occurs in nature. Despite its relevance in natural systems and technical applications, t ...

Nature Research2019

Hydrogen Diffusion and Trapping in α-Iron: The Role of Quantum and Anharmonic Fluctuations

Michele Ceriotti, Bingqing Cheng

We investigate the thermodynamics and kinetics of a hydrogen interstitial in magnetic α-iron, taking account of the quantum fluctuations of the proton as well as the anharmonicities of lattice vibrations and hydrogen hopping. We show that the diffusivity o ...

2018

Accelerating path integral evaluation of equilibrium and kinetic isotope effects

Konstantin Karandashev

Investigating the effect of isotope substitution on equilibrium and kinetic properties of molecules has become an important tool for estimating the importance of nuclear quantum effects. In this work, we discuss calculating both equilibrium and kinetic iso ...

EPFL2018

How Rhodopsin Tunes the Equilibrium between Protonated and Deprotonated Forms of the Retinal Chromophore

Ursula Röthlisberger, Siri Camee van Keulen, Alicia Solano

Rhodopsin is a photoactive G-protein-coupled receptor (GPCR) that converts dim light into a signal for the brain, leading to eyesight. Full activation of this GPCR is achieved after passing through several steps of the protein's photoactivation pathway. Ke ...

2017

Multi-Directional Structural Component Hybrid Testing System for the Assessment of the Seismic Response of Steel I-Shaped Columns

Dimitrios Lignos, Ahmed Mohamed Ahmed Elkady, Ali Imanpour

The Multi-Directional Hybrid Testing System (MDHTS) at Polytechnique Montreal is an advanced structural testing system that can be used to study the response of large-scale structural components such as columns, walls, or bridge piers subjected to any comb ...

2016

Who Activates the Nucleophile in Ribozyme Catalysis? An Answer from the Splicing Mechanism of Group II Introns

Ursula Röthlisberger, Giulia Palermo, Lorenzo Casalino

Group II introns are Mg2+-dependent ribozymes that are considered to be the evolutionary ancestors of the eukaryotic spliceosome, thus representing an ideal model system to understand the mechanism of conversion of premature messenger RNA (mRNA) into matur ...

2016

Cyclic test data of six unreinforced masonry walls with different boundary conditions

Katrin Beyer, Sarah Petry

Previous test data on unreinforced masonry walls focused on the global response of the wall. A new data set (Petry and Beyer 2014a; D01:10.5281/zenodo.8443) on six wall tests, which is publicly available, allows for linking global to local deformations of ...

2015

Property changes in thermo-hydro-mechanical processing COST Action FP0904 2010-2014: Thermo-hydro-mechanical wood behavior and processing

Parviz Navi

Thermo-hydro-mechanical (THM) treatment is a combined action of temperature, moisture, and mechanical force, which leads to modified wood (THMW). Various types of eco-friendly THM processes have been developed to enhance wood properties and generate new ma ...

Walter De Gruyter Gmbh2015

Force-displacement response of unreinforced masonry walls for seismic design

Sarah Petry

In regions with low to moderate seismicity, unreinforced masonry (URM) is commonly used for the construction of low to mid-rise buildings. When these structures are subjected to seismic loading, the stiff URM walls attract considerable part of the lateral ...

EPFL2015

Kinetic isotope effect in malonaldehyde determined from path integral Monte Carlo simulations

Jiri Vanicek, Marcin Rafal Buchowiecki, Jing Huang

The primary H/D kinetic isotope effect on the intramolecular proton transfer in malonaldehyde is determined from quantum instanton path integral Monte Carlo simulations on a fully dimensional and validated potential energy surface for temperatures between ...

Royal Society of Chemistry2014

Direct path integral estimators for isotope fractionation ratios

Michele Ceriotti, Bingqing Cheng

Fractionation of isotopes among distinct molecules or phases is a quantum effect which is often exploited to obtain insights on reaction mechanisms, biochemical, geochemical, and atmospheric phenomena. Accurate evaluation of isotope ratios in atomistic sim ...

American Institute of Physics2014

Monte Carlo evaluation of the equilibrium isotope effects using the Takahashi-Imada factorization of the Feynman path integral

Jiri Vanicek, Marcin Rafal Buchowiecki

The Feynman path integral approach for computing equilibrium isotope effects and isotope fractionation corrects the approximations made in standard methods, although at significantly increased computational cost. We describe an accelerated path integral ap ...

Elsevier2013

Decreasing the size of printed comb electrodes by the introduction of a dielectric interlayer for capacitive gas sensors on polymeric foil: Modeling and fabrication

Nico de Rooij, Danick Briand, Francisco Molina Lopez

In this work we present a novel strategy to fabricate printed comb electrodes devices with decreased size by the introduction of a thin dielectric layer between the two combs. The electrical insulation of the two polarities prevents short-cuts occurring be ...

Elsevier2013

Heat Management for Process Intensification of Fast Exothermic Reactions in Microstructured Reactors

Julien Haber

Nowadays, the production in fine chemical and pharmaceutical industry is mostly carried out in large scale batch reactors having typically dimensions of a few meters to satisfy the demand of the market. Even though this technology has been widely used and ...

EPFL2013

Regulatory Uncertainty and Nonmarket Capabilities : An Investigation of the Electricity Generation Sector

Bastian Wolfgang Schwark

In 2005, the Economist Intelligence Unit conducted a survey with Chief Risk Officers worldwide across all industries and asked about the biggest threat to their businesses. Interestingly, regulatory risk ranked first. It dominated all other types of risk, ...

EPFL2011