Chlorure de fer(III)

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Publications associées (29)

Synthesis, Structure, and Anticancer Activity of Arene-Ruthenium(II) Complexes with Acylpyrazolones Bearing Aliphatic Groups in the Acyl Moiety

Paul Joseph Dyson, Rosario Scopelliti, Tina Riedel

A series of neutral ruthenium(II) arene complexes [(arene)Ru(Q(R))Cl] (arene = p-cymene (cym) or hexamethylbenzene (hmb)) containing 4-acyl-5-pyrazolonate Q(R) ligands with different electronic and steric substituents (R = 4-cyclohexyl, 4-stearoyl, or 4-ad ...

American Chemical Society2016

Enhancing the photo-Fenton treatment of contaminated water by use of ultrasound and iron-complexing agents

Stefanos Papoutsakis

The photo-Fenton process is a promising emerging technology for the treatment of contaminated water streams. It is based on the generation of reactive oxygen species that are capable of destroying recalcitrant contaminants otherwise unaffected by conventio ...

EPFL2016

[4+2]-Annulations of Aminocyclobutanes

Jérôme Waser, Florian Patrick Marie Daniel De la Barre De Nanteuil, Sophie Lucie Racine, Jérémy Vuilleumier, Daniele Perrotta

The first [4 + 2]-annulation between aminocyclobutanes and aldehydes to access tetrahydropyranyl amines is reported. With phthalimido cyclobutane dicarboxylates and aromatic aldehydes, tetrahydropyrans were obtained in 53-92% yield and 3:1-17:1 dr using sc ...

American Chemical Society2015

Modulating the Anticancer Activity of Ruthenium(II)-Arene Complexes

Paul Joseph Dyson, Rosario Scopelliti, Patrycja Nowak-Sliwinska, Catherine Marie Amélie Clavel, Emilia Paunescu

Following the identification of [Ru(eta(6)-p-cymene)Cl-2(1H,1H,2H,2H-perfluorodecyl-3-(pyridin-3-yl)propanoate)], a ruthenium(II)arene complex with a perfluoroalkyl-modified ligand that displays remarkable in vitro cancer cell selectivity, a series of stru ...

Amer Chemical Soc2015

Hydrogen Storage in the Carbon Dioxide - Formic Acid Cycle

Gabor Laurenczy, Cornel Fink, Mickael Montandon-Clerc

This year Mankind will release about 39 Gt carbon dioxide into the earth's atmosphere, where it acts as a greenhouse gas. The chemical transformation of carbon dioxide into useful products becomes increasingly important, as the CO2 concentration in the atm ...

Swiss Chemical Soc2015

Fast synthesis of platinum nanopetals and nanospheres for highly-sensitive non-enzymatic detection of glucose and selective sensing of ions

Giovanni De Micheli, Sandro Carrara, Irene Taurino

Novel methods to obtain Pt nanostructured electrodes have raised particular interest due to their high performance in electrochemistry. Several nanostructuration methods proposed in the literature use costly and bulky equipment or are time-consuming due to ...

Nature Publishing Group2015

Methane Production from Microalgae via Continuous Catalytic Supercritical Water Gasification: Development of Catalysts and Sulfur Removal Techniques

Gaël Peng

This doctoral thesis aims at demonstrating the technical feasibility of methane production from microalgae via continuous catalytic supercritical water gasification (CSCWG). This work focuses on three different research approaches: (i) assessment and impro ...

EPFL2015

Z-Selective Olefin Synthesis via Iron-Catalyzed Reductive Coupling of Alkyl Halides with Terminal Arylalkynes

Xile Hu, Chi Wai Cheung, Fedor Zhurkin

Selective catalytic synthesis of Z-olefins has been challenging. Here we describe a method to produce 1,2-disubstituted olefins in high Z selectivity via reductive cross-coupling of alkyl halides with terminal arylalkynes. The method employs inexpensive an ...

American Chemical Society2015

Graphene : from Growth to Devices

Laurent Syavoch Bernard

We report a full study of graphene synthesis by CVD on Cu surface. Two CVD methods have been developed. The first is a static one, which yields monolayer of graphene at low pressure of methane in 3 minutes at 1000 C. The second one is an equimolar method w ...

EPFL2015

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