Publications associées à Hypothèse du fusil à clathrates

Active lithoautotrophic and methane-oxidizing microbial community in an anoxic, sub-zero, and hypersaline High Arctic spring

Lost Hammer Spring, located in the High Arctic of Nunavut, Canada, is one of the coldest and saltiest terrestrial springs discovered to date. It perennially discharges anoxic (

2022

Microbial-induced carbonate precipitation applicability with the methane hydrate-bearing layer microbe

Alexandra Clarà Saracho

Production of methane gas from the methane-hydrate-bearing layer below the deep-ocean floor is expected to be crucial in the future of energy resources worldwide. During the methane gas-production phase from the methane hydrate with the depressurisation me ...

ELSEVIER SCI LTD2020

Observation of methane filled hexagonal ice stable up to 150 GPa

Philippe Gillet, Richard Gaal, Livia Eleonora Bove Kado, Umbertoluca Ranieri

Gas hydrates consist of hydrogen-bonded water frameworks enclosing guest gas molecules and have been the focus of intense research for almost 40 y, both for their fundamental role in the understanding of hydrophobic interactions and for gas storage and ene ...

National Academy of Sciences2019

Lateral variations and vertical structure of the microbial methane cycle in the sediment of Lake Onego (Russia)

Natacha Tofield-Pasche, Nathalie Dubois

The significance of methane production by lakes to the global production of greenhouse gas is well acknowledged while underlying processes sustaining the lacustrine methane budget remain largely unknown. We coupled biogeochemical data to functional and phy ...

2019

Site Selective Detection of Methane Dissociation on Stepped Pt Surfaces

Rainer Beck, Ana Gutiérrez González

We report a combined experimental and theoretical study comparing methane dissociation on three di erent platinum surfaces Pt(111), Pt(211), and Pt(110)-(1 × 2). Re ection absorption infrared spectroscopy (RAIRS) was used to detect chemisorbed methyl speci ...

2019

Guest dynamics in methane hydrates and hydrogen hydrates under high pressure

Umbertoluca Ranieri

Hydrates of gas are non-stoichiometric inclusion compounds constituted of water and gas. Therein, the water molecules are hydrogen-bonded and form three-dimensional crystalline networks incorporating different kinds of polar or nonpolar guest gas molecules ...

EPFL2018

Dynamics of methane dissociation on transition metals

Rainer Beck

One of the many contributions of Harold Winters to surface science was his pioneering ultrahigh vacuum study on the kinetics of the technologically important dissociation of CH4 on transition metals in the 1970s. He observed a dramatic activation of the di ...

A V S Amer Inst Physics2017

Controls on subsurface methane fluxes and shallow gas formation in Baltic Sea sediment (Aarhus Bay, Denmark)

Sabine Flury McGinnis

Shallow gas accumulates in coastal marine sediments when the burial rate of reactive organic matter beneath the sulfate zone is sufficiently high and the methanogenic zone is sufficiently deep. We investigated the controls on methane production and free me ...

Elsevier2016

Clathrate structure-type recognition: Application to hydrate nucleation and crystallisation

Simone Meloni

For clathrate-hydrate polymorphic structure-type (sI versus sII), geometric recognition criteria have been developed and validated. These are applied to the study of the rich interplay and development of both sI and sII motifs in a variety of hydrate-nucle ...

Amer Inst Physics2015

State-Resolved Methane Dissociation on Pt(111) Studied by Reflection Absorption Infrared Spectroscopy

Rainer Beck, Hirokazu Ueta, Li Chen

The dissociation of methane on Pt(111) was studied using quantum state-resolved methods and reflection absorption infrared spectroscopy (RAIRS), at a surface temperature of 150 K where the nascent reaction products methyl(ads) and H(ads) are stable and acc ...

2015

Observational constraints on the distribution, seasonality, and environmental predictors of North American boreal methane emissions

Jed Oliver Kaplan, Bowen Zhang

Wetlands comprise the single largest global source of atmospheric methane, but current flux estimates disagree in both magnitude and distribution at the continental scale. This study uses atmospheric methane observations over North America from 2007 to 200 ...

Amer Geophysical Union2014

Methane Clathrate Hydrate Nucleation Mechanism by Advanced Molecular Simulations

Simone Meloni

The nucleation mechanisms of methane hydrates are studied using well-tempered metadynamics and restrained molecular dynamics. The collective variables we used to follow the process are the methane-methane and methane-water coordination numbers, from which ...

Amer Chemical Soc2014

Summer methane fluxes from a boreal bog in northern Quebec, Canada, using eddy covariance measurements

Marc Parlange, Daniel Nadeau

A boreal bog located in the James Bay lowlands, Canada, was instrumented with an open-path gas analyzer to monitor the turbulent fluxes of methane throughout the summer of 2012. The mostly continuous eddy covariance measurements permitted the study of meth ...

Elsevier2013

Spatial Heterogeneity of Methane Ebullition in a Large Tropical Reservoir

Alfred Johny Wüest, Bernhard Wehrli

Tropical reservoirs have been identified as important methane (CH4) sources to the atmosphere, primarily through turbine and downstream degassing. However, the importance of ebullition (gas bubbling) remains unclear. We hypothesized that ebullition is a di ...

Amer Chemical Soc2011

Seasonal Net Ecosystem Carbon Exchange of a Regenerating Cutaway Bog: How Long Does it Take to Restore the C-Sequestration Function?

Alexandre Buttler, Andy Siegenthaler, Edward Mitchell

We measured the net ecosystem exchange (NEE) and respiration rates and modeled the photosynthesis and respiration dynamics in a cutover bog in the Swiss Jura Mountains during one growing season at three stages of regeneration (29, 42, and 51 years after pe ...

Wiley-Blackwell2011

Magnitude and seasonality of wetland methane emissions from the Hudson Bay Lowlands (Canada)

Jed Oliver Kaplan, Isabelle Bey, Jérôme Drevet

The Hudson Bay Lowlands (HBL) is the second largest boreal wetland ecosystem in the world and an important natural source of global atmospheric methane. We quantify the HBL methane emissions by using the GEOS-Chem chemical transport model to simulate aircr ...

Copernicus Publications2011

Growth of carbon nanotubes and microfibers over stainless steel mesh by cracking of methane

Albert Renken, Lioubov Kiwi

The

{La}_{2}{NiO}_{4}

film was synthesized on the 304 stainless steel (SS) mesh. The hydrogen reduction of La2NiO4 generated homogeneous nanocatalyst particles (probably

{Ni}/{La}_2{O}_{3}

) over which methane was cracked, producing carbon notubes/micro ...

2008

Influence of temperature and high acetate concentrations on methanogenensis in lake sediment slurries

Christof Holliger, Bernhard Wehrli

Methanogenesis from main methane precursors H2/CO2 and acetate was investigated in a temperature range of 2–70 °C using sediments from Lake Baldegg, Switzerland. Psychrophilic, psychrotrophic, mesophilic, and thermophilic methanogenic microbial communities ...

Blackwell Publishing Ltd, Oxford2007