Publications associées à Réaction exothermique

Revisiting the concept of extents for chemical reaction systems using an enthalpy balance

Dominique Bonvin, Diogo Filipe Mateus Rodrigues

For the investigation of complex reaction systems, it has been proposed to decouple the various rate processes using a linear time-invariant transformation that is constructed from knowledge of stoichiometry, reaction enthalpies, inlet compositions and tem ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Cristian Pezzato

A major goal in the design of synthetic molecular machines is the creation of pumps that can use the input of energy to transport material from a reservoir at low chemical potential to a different reservoir at higher chemical potential, thereby forming and ...

ROYAL SOC CHEMISTRY2020

Fluorinated surfactants in droplet-based microfluidics: Influence of their composition on the properties of emulsion drops

Gianluca Nicolas Etienne

Miniaturization has been a driving force in many areas of science and technology, most notably in the electronics industry. Droplet-based microfluidics, a methode to produce emulsion drops in a controlled way and at high-throughputs, enables the miniaturiz ...

EPFL2019

Fast real time and quantitative gas analysis method for the investigation of the CO2 reduction reaction mechanism

Andreas Züttel, Emanuele Moioli, Wen Luo, Robin Tobias Andreas Mutschler

We present a new fast real time and quantitative gas analysis method by means of mass spectrometry (MS), which has approximately an order of magnitude faster sampling rate in comparison with a traditional gas chromatography. The method is presented and dis ...

AMER INST PHYSICS2018

Combined Exergy Analysis and Energy Integration for the Optimization of Nitrogen Fertilizer Plants

François Maréchal, Daniel Alexander Florez Orrego, Shivom Sharma

Modern ammonia production plants are equipped with efficient energy integration networks able to recover an important fraction of the enthalpy of reaction released by the exothermic chemical systems. However, to fully supply the exergy demands of the highl ...

University of San Diego2017

Alkali Activation of AOD Stainless Steel Slag Under Steam Curing Conditions

Muhammad Salman, Ruben Anton Snellings

Crystalline argon oxygen decarburization slag, in powdery form, was investigated for its hydration potential by alkali activation and curing at 80 degrees C. Na-silicate and K-silicate of the same modulus were used as activators. Isothermal calorimetry at ...

Wiley-Blackwell2015

Fine structuration of low-temperature co-fired ceramic (LTCC) microreactors

Paul Muralt, Albert Renken, Bo Jiang, Lioubov Kiwi, Thomas Maeder, Julien Haber

The development of microreactors that operate under harsh conditions is always of great interest for many applications. Here we present a microfabrication process based on low-temperature co-fired ceramic (LTCC) technology for producing microreactors which ...

Royal Society of Chemistry2015

Nanocalorimetric platform for accurate thermochemical studies in microliter volumes

Martinus Gijs, Thomas Lehnert, Raphaël Etienne Jean Trouillon, Rima Padovani

A straightforward and general way for monitoring chemical reactions is via their thermal signature. Such approach requires however an experimental setup with a high thermal stability that simultaneously allows time-resolved heat detection with high sensiti ...

Royal Soc Chemistry2015

Heat Management for Process Intensification of Fast Exothermic Reactions in Microstructured Reactors

Julien Haber

Nowadays, the production in fine chemical and pharmaceutical industry is mostly carried out in large scale batch reactors having typically dimensions of a few meters to satisfy the demand of the market. Even though this technology has been widely used and ...

EPFL2013

Increasing the Efficiency of Ligands for FK506-Binding Protein 51 by Conformational Control

Ranganath Gopalakrishnan

The design of efficient ligands remains a key challenge in drug discovery. In the quest for lead-like ligands for the FK506-binding protein 51 (FKBP51), we designed two new classes of bicyclic sulfonamides to probe the contribution of conformational energy ...

Amer Chemical Soc2013

Extent-based incremental identification of reaction systems using concentration and calorimetric measurements

Dominique Bonvin, Julien Léo Billeter, Sriniketh Srinivasan, Nirav Pravinbhai Bhatt

Extent-based Incremental Model Identification (IMI) uses the concept of extent of reaction and the integral method of parameter estimation to identify reaction kinetics from transient concentration measurements. This study proposes to incorporate calorimet ...

Elsevier2012

The important role of pressure in supercritical fluid process development revealed by reaction calorimetry

Thierry Meyer, Charalampos Mantelis

The technique of reaction calorimetry adapted for use with reactions in supercritical fluids was used to study some safety aspects of the free-radical dispersion polymerization of methyl methacrylate in scCO2. The reaction heat rate profile was found to ch ...

Wiley-Blackwell2009

Editorial: Failure in multiphase geomaterials

Lyesse Laloui

The contributions assembled in the present volume proceed from the lectures of the 2009 ALERT Geomaterials School devoted to the Failure in the multiphase geomaterials. The multiphase behaviour of geomaterials used to be mainly considered from the point of ...

2009

Compact reactor for continuous multi-phase reactions : solvent-free alkyne hydrogenation as a case study

Martin Grasemann

The objective of this thesis is the development of a compact reactor for continuous three-phase reactions in single-pass configurations. The design is based on a bubble column reactor staged with layers of catalytic material. To make the reactor suitable f ...

EPFL2009

Optimization of reaction calorimetry for monitoring chemical reactions in supercritical fluids

Charalampos Mantelis

The PhD thesis deals with the optimization of the reaction calorimetry technique to monitor chemical reactions in supercritical fluids. The aim is to develop this thermal analysis technique to monitor the heat released by a chemical reaction in a high pres ...

EPFL2008

Optimization of reaction calorimetry with supercritical fluids: A complete term-by-term analysis of the heat flow equation

Thierry Meyer, Charalampos Mantelis

A complete anal. of the heat flow equation in reaction calorimetry with supercrit. fluids is presented. An esp. developed reaction calorimeter is employed to study the challenges introduced by the supercrit. state of the reaction mixt. and the particularit ...

2008

“Sandwich Reactor” for Heterogeneous Catalytic Processes: N2O Decomposition as a Case Study

Albert Renken, Lioubov Kiwi, Bryan Bromley

A novel “sandwich” microreactor designed as a thin (∼ 300

\mu

m) porous plate of sintered metal fibers (SMF), sandwiched between metallic plates is reported. The SMF surface was coated by Fe-ZSM-5 thin film (< 2

\mu

m) rendering a catalyst highly active ...

2008

Free-radical dispersion polymerization of methyl methacrylate in supercritical carbon dioxide: a parametric analysis with reaction calorimetry

Thierry Meyer, Sophie Fortini, Charalampos Mantelis, Raphaël Barbey

In this study, the application of reaction calorimetry, an efficient tool to obtain kinetic and safety data, is presented on the free radical dispersion polymn. of MMA in scCO2. The effect of three major parameters with respect to the reaction evolution ar ...

2007