Publications associées à Formation ferrifère rubanée

Photo-Fenton inactivation of MS2 bacteriophage at alkaline pH by Fe salts or nm to μm-sized oxides, and the Janus-faced effects of natural organic matter in surface waters

César Pulgarin, Stefanos Giannakis, Giulio Farinelli, Ogadimma Cassandra Oji-Okoro

In this study, MS2 bacteriophage was inactivated by homogeneous and heterogeneous photo-Fenton processes in an alkaline matrix (pH 8) using low concentrations of H2O2 and iron forms (1 mg/L), including Fe(II), Fe(III), and Fe (hydr)oxides. As a reference, ...

Elsevier2024

Unsupervised Electrofacies Clustering Based on Parameterization of Petrophysical Properties: A Dynamic Programming Approach

François Fleuret, Karthigan Sinnathamby

Electrofacies using well logs play a vital role in reservoir characterization. Often, they are sorted into clusters according to the self-similarity of input logs and do not capture the known underlying physical process. In this paper, we propose an unsupe ...

SOC PETROPHYSICISTS & WELL LOG ANALYSTS-SPWLA2023

Iron phosphate mediated magnetite synthesis: a bioinspired approach

Giulia Mirabello

The biomineralization of intracellular magnetite in magnetotactic bacteria (MTB) is an area of active investigation. Previous work has provided evidence that magnetite biomineralization begins with the formation of an amorphous phosphate-rich ferric hydrox ...

ROYAL SOC CHEMISTRY2021

Fine Particle Iron in Soils and Road Dust Is Modulated by Coal-Fired Power Plant Sulfur

Athanasios Nenes

Transition metal ions, such as water-soluble iron (WS-Fe), are toxic components of fine particles (PM2.5). In Atlanta, from 1998 to 2013, a previous study found that WS-Fe was the PM2.5 species most associated with adverse cardiovascular outcomes. We exami ...

AMER CHEMICAL SOC2020

Enhancing solar disinfection of water in PET bottles by optimized in-situ formation of iron oxide films. From heterogeneous to homogeneous action modes with H2O2 vs. O-2 - Part 2: Direct use of (natural) iron oxides

César Pulgarin, Sami Rtimi, Stefanos Giannakis, Sakine Shekoohiyan

Solar disinfection (SODIS) is a well-accepted intervention method, leading to an improvement in contaminated water sources. In this work, we attempted to further enhance the bacterial inactivation process during light exposure. By means of iron oxide addit ...

ELSEVIER SCIENCE SA2019

Mechanism(s) of electron transfer and metabolic changes during iron reduction by Clostridium acetobutylicum

Cornelia List

Microorganisms catalyze many of the redox transformations driving the iron cycle in the geosphere. For instance, iron cycling includes the reduction of solid-phase and soluble ferric iron (Fe(III)) to ferrous iron (Fe(II)). However, in order to reduce soli ...

EPFL2019

Factors influencing the hydration kinetics of ye'elimite; effect of mayenite

Karen Scrivener, Mohsen Ben Haha, Frank Bullerjahn

The aim of this study was to understand the origin of the variation in the hydraulic reactivity of ye'elimite systems. To this end, the hydration of two clinkers, one composed mainly of synthetic stoichiometric (C(4)A(3)(S) over bar) "Y" and the other of a ...

Pergamon-Elsevier Science Ltd2019

Investigating Earth's Formation History Through Copper and Sulfur Metal-Silicate Partitioning During Core-Mantle Differentiation

James Badro

Identifying extant materials that act as compositional proxies for Earth is key to understanding its accretion. Copper and sulfur are both moderately volatile elements; however, they display different geochemical behavior (e.g., phase affinities). Thus, in ...

AMER GEOPHYSICAL UNION2018

Unravelling the precipitation pathway of biorelevant minerals: from fundamental studies to biomedical applications

Agnese Carino

The formation pathway of biominerals archetypes, namely calcium carbonate (CaC) and calcium phosphates (CaPs), was investigated using a multidisciplinary approach. The time-resolved analytical data were collected using a controlled-composition method and i ...

EPFL2018

Bacterial iron reduction and biogenic mineral formation for the stabilisation of corroded iron objects

Julien Maillard, Arnaud Michel Gelb

Exploiting bacterial metabolism for the stabilisation of corroded iron artefacts is a promising alternative to conventional conservation-restoration methods. Bacterial iron reduction coupled to biogenic mineral formation has been shown to promote the conve ...

Nature Research2018

Recent Advances in the Synthesis and Applications of Multimodal Gold-Iron Nanoparticles

Francesco Stellacci

Bimetallic particles based on gold and iron have been gathering increasing interest in biomedical applications because of the synergic combination of the plasmonic features of the inert gold component with the magnetic properties of the iron or iron oxide ...

Bentham Science Publishers2017

Iron oxide-mediated semiconductor photocatalysis vs. heterogeneous photo-Fenton treatment of viruses in wastewater. Impact of the oxide particle size

César Pulgarin, Michaël Bensimon, Sami Rtimi, Stefanos Giannakis, Anna Carratala Ripolles, Masoud Talebi Amiri, Siting Liu

The photo-Fenton process is recognized as a promising technique towards microorganism disinfection in wastewater, but its efficiency is hampered at near-neutral pH operating values. In this work, we overcome these obstacles by using the heterogeneous photo ...

Elsevier2017

Castles fall from inside: Evidence for dominant internal photo-catalytic mechanisms during treatment of Saccharomyces cerevisiae by photo-Fenton at near-neutral pH

César Pulgarin, Sami Rtimi, Stefanos Giannakis, Cristina del Socorro Lonfat

In this work, the antimicrobial effects of the photo-Fenton process on yeast cells were tested (Saccharomyces cerevisiae), an essential eukaryotic unicellular model of living cells. Near-neutral pH was used in all studies, while iron sulfate and iron citra ...

Elsevier2016

Bacterial inactivation with iron citrate complex: A new source of dissolved iron in solar photo-Fenton process at near-neutral and alkaline pH

César Pulgarin, Andrzej Sienkiewicz, Cristina del Socorro Lonfat

This study reports the first application of Fe-citrate-based photo-Fenton chemistry for the inactivation of Escherichia coil. Promising results of bacterial inactivation at near-neutral and alkaline pH conditions were obtained, while using low iron concent ...

Elsevier2016

Composition and structure of Fe(III)-precipitates formed by Fe(II) oxidation in water at near-neutral pH: Interdependent effects of phosphate, silicate and Ca

Janet Gordon Hering

We studied the interdependent effects of phosphate, silicate and Ca on the formation of Fe(III)-precipitates by oxidation of 0.5 mM Fe(II) in near-neutral bicarbonate-buffered aqueous solutions at concentrations relevant for natural water resources. Comple ...

Pergamon-Elsevier Science Ltd2015

Shift from heterogeneous to homogeneous catalysis during resorcinol degradation using the solar photo-Fenton process initiated at circumneutral pH

César Pulgarin, Luis Ferney Gonzalez Bahamon

The photo-Fenton process (Fe-2+,Fe-3+/H2O2/hv) is known to degrade aqueous organic compounds at acidic pHs. Nevertheless, recent studies have shown that this process also occurs at circumneutral pHs. Dihydroxybenzene isomers (i.e., resorcinol, hydroquinone ...

Elsevier Science Bv2015

Continuous Polyol Synthesis of Metal and Metal Oxide Nanoparticles Using a Segmented Flow Tubular Reactor (SFTR)

Paul Bowen, Andrea Testino, Christoph Stähli, Jose Enrico Quijano Quinsaat, Frank Pilger

Over the last years a new type of tubular plug flow reactor, the segmented flow tubular reactor (SFTR), has proven its versatility and robustness through the water-based synthesis of precipitates as varied as CaCO3, BaTiO3, Mn((1-x))Ni(x)C(2)O(4)2H(2)O, YB ...

Molecular Diversity Preservation International2015

Uranium redox transition pathways in acetate-amended sediments

Rizlan Bernier-Latmani, Elena Suvorova Buffat, Daniel Scott Alessi, Malgorzata Alicja Stylo

Redox transitions of uranium [from U(VI) to U(IV)] in low-temperature sediments govern the mobility of uranium in the environment and the accumulation of uranium in ore bodies, and inform our understanding of Earth's geochemical history. The molecular-scal ...

National Academy of Sciences2013

Photoinactivation of virus on iron-oxide coated sand: enhancing inactivation in sunlit waters

Tamar Kohn, Brian Pecson, Loïc Decrey

Adsorption onto iron oxides can enhance the removal of waterborne viruses in constructed wetlands and soils. If reversible adsorption is not coupled with inactivation, however, infective viruses may be released when changes in solution conditions cause des ...

Elsevier2012

Products of abiotic U(VI) reduction by biogenic magnetite and vivianite

Rizlan Bernier-Latmani, Elena Suvorova Buffat, Harish Veeramani, Jonathan Sharp, Daniel Scott Alessi

Reductive immobilization of uranium by the stimulation of dissimilatory metal-reducing bacteria (DMRB) has been investigated as a remediation strategy for subsurface U(VI) contamination. In those environments, DMRB may utilize a variety of electron accepto ...

Elsevier2011