Publications associées à Matériau auto-cicatrisant

Enabling simultaneous reprocessability and fire protection via incorporation of phosphine oxide monomer in epoxy vitrimer

The conception of epoxy thermosets with both reprocessability and flame retardancy delineates a new horizon in polymer science, offering a material solution that is not only superior in fire safety but is also environment friendly. Herein, a flame-retardan ...

Journal Mater Sci Technol2024

Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2+2] Photocycloaddition and Barrier Properties

Yves Leterrier, Sara Dalle Vacche

A novel-biobased latex was synthesized by redox-initiated emulsion copolymerization of ethoxy dihydroeugenyl methacrylate with 5 wt % of a photosensitive methacrylate containing a coumarin group. A stable copolymer latex having 16 wt % solids content and a ...

Amer Chemical Soc2024

CRACK SHIELDING MECHANISMS OF INTERLAYERED EPOXY MATERIALS UNDER QUASI-STATIC AND FATIGUE LOADING

Anastasios Vassilopoulos, Dharun Vadugappatty Srinivasan

This research explores the capability of PEI and PVDF thermoplastic interlayers to arrest cracks in epoxy materials modified with short-glass fibers and core-shell rubber particles. It also investigates the effect of interlayer position, the number of inte ...

Queen's University Belfast2023

Controlling the Microstructure and Composition of 3D Printed Soft Load-Bearing Hydrogels

Matteo Hirsch

Hydrogels are among the first materials expressly designed for their use in biomedicine. However, state-of-the-art applications of hydrogels are severely limited because they are typically either too soft or too brittle such that they cannot bear significa ...

EPFL2023

Method for manufacturing an active structure for a radiation detector and polymeric mold for the method

Alessandro Mapelli, Arnaud Bertsch, Fabrizio Carbone, Veronica Leccese

A method for manufacturing a scintillation detector structure including the steps of forming a plurality of first structures into a surface of a substrate to form a patterned substrate, filling the plurality of first structures and covering the surface of ...

2023

Multidimensional Electron Imaging of Catalyst Layer Materials

Robin Pierre Alain Girod

The proton exchange membrane fuel cell (PEMFC) is an important technology for clean power generation in a decarbonized hydrogen system and is notably envisioned for applications in heavy-duty transportation. However, for cost and performance competitivenes ...

EPFL2023

Supramolecular Polymer Brushes

Friederike Katharina Metze

Thin polymer coatings present a method to modify the surface properties of underlying substrates. Polymer-coated surfaces have been used as anticorrosive materials, surfaces with special wetting properties, antifriction materials, and as materials for biom ...

EPFL2023

A Novel Method to Quantify Self-Healing Capabilities of Fiber-Reinforced Polymers

Véronique Michaud, Amaël Maximilien Cohades, Robin Samuel Trigueira, Cecilia Scazzoli

The present work investigates a novel and practical method to evaluate the healing efficiency of carbon-reinforced polymer composites. The method should be representative of damage occurring during the lifetime of a composite part, should tend to damage th ...

FRONTIERS MEDIA SA2022

Polymer Translocation through Nanometer Pores

Maria-Alexandra Paun

In this paper the loaded polymer transport and its escape via a nanometer size aperture, virtually by nanomembrane, the polymer being moved by an exterior electrostatic field, has been studied. Assuming a linear dependency of the friction coefficient on th ...

MDPI2022

Stiff, Strong, Tough, and Highly Stretchable Hydrogels Based on Dual Stimuli-Responsive Semicrystalline Poly(urethane–urea) Copolymers

Pascal Alexander Schouwink, Nicolas Candau, Adrien Julien Demongeot, Oguzhan Oguz

There has been a considerable interest in developing stiff, strong, tough, and highly stretchable hydrogels in various fields of science and technology including biomedical and sensing applications. However, simultaneous optimization of stiffness, strength ...

2021

Design and Development of Injectable, Tough and Intrinsically-Adhesive Hydrogels for Biomedical Applications

Peyman Karami

Despite the development of hydrogels with a wide range of mechanical properties, insufficient adhesion between these materials and biological surfaces limits their use in the biomedical applications. Most recent advancements in highly adhesive hydrogel sys ...

EPFL2021

Reversible and Broad-Range Oxygen Sensing Based on Purely Organic Long-Lived Photoemitters

Esther Amstad, René M. Rossi, Efe Armagan

The detection of oxygen (O-2) by optical sensors is of growing importance, for example, in biology, life science, environmental science, and aerodynamics, where the composition of gases is crucial for many applications. Purely organic optical O-2 sensors a ...

2021

Towards tailored cement-based materials with ground calcium carbonates

Emmanuel Denarié, Lionel Sofia

Proportioning the dosage of Ground Calcium Carbonates (GCC) in cementitious materials, beyond current normative levels, is one of the most promising ways towards sustainability of mortar and concrete technology. Performance parameters such as the water/bin ...

2021

A numerical approach to characterize the viscoelastic behaviour of fibre beds and to evaluate the influence of strain deviations on viscoelastic parameter extraction

Véronique Michaud, Vincent Werlen, Christian Rytka

The development of a robust material model able to accurately describe fibre bed compaction at different strain and strain rates is highly desirable because it is essential for the simulation of many composite manufacturing processes. In this study, we inv ...

2021

Adaptive Self-Sealing Suction-Based Soft Robotic Gripper

Metin Sitti, Sukho Song

While suction cups prevail as common gripping tools for a wide range of real-world parts and surfaces, they often fail to seal the contact interface when engaging with irregular shapes and textured surfaces. In this work, the authors propose a suction-base ...

2021

Intermolecular Pd(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes and Other Investigations into the Enantioselective Activation of Challenging C(sp3)-H Bonds

Qui-Hien Nguyen

The direct construction of stereogenic axes by enantioselective C-H arylation has been regarded as a very challenging transformation. Very few examples have been reported, despite the indisputable straight-forwardness of the methodology. This is due to the ...

EPFL2021

Polysulfone Dispersed Liquid Crystals As Promising Materials For Flexible Substrates Of Organic Light Emitting Diodes

Maria-Alexandra Paun

The paper deals with the preparation and investigation of a series of polymer dispersed liquid crystals (PDLCs) based on polysulfone matrix and an azomethine liquid crystal. The PDLC systems were prepared by thermal induced phase separation method. Their m ...

UNIV POLITEHNICA BUCHAREST, SCI BULL2021

Stability of hydrate assemblages and properties of cementitious systems with higher alumina content

Natechanok Chitvoranund

Two low CO2 cement systems are investigated: one made with the use of supplementary cementitious materi-als (SCMs) (metakaolin and limestone) and the other an alternative binder, calcium sulfoaluminate cement (CSA). These two low CO2 cements contain a simi ...

EPFL2021

Coordination-Driven Monolayer-to-Bilayer Transition in Two-Dimensional Metal–Organic Networks

Henning Paul-Julius Stahlberg, Mina Moradi, Patrick Shahgaldian

We report on monolayer-to-bilayer transitions in 2D metal–organic networks (MONs) from amphiphiles supported at the water–air interface. Functionalized calix[4]arenes are assembled through the coordination of selected transition metal ions to yield monomol ...

2021

Tribological properties of gold matrix composite coatings with carbon nanocapsules containing ionic liquid lubricants

Stefano Mischler, Anna Neus Igual Muñoz

Self-lubricating, gold matrix composite coatings were produced by electrochemical codeposition of carbon nanocapsules filled with ionic liquid (IL) from a colloidal galvanic bath on a nickel electrode. The tribological response of the composite coatings wa ...

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