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Publications associées (30)

Microhydration of Dibenzo-18-Crown-6 Complexes with K+, Rb+, and Cs+ Investigated by Cold UV and IR Spectroscopy in the Gas Phase

Thomas Rizzo, Yoshiya Inokuchi

In this Article, we examine the hydration structure of dibenzo-18-crown-6 (DB18C6) complexes with K+, Rb+, and Cs+ ion in the gas phase. We measure well-resolved UV photodissociation (UVPD) spectra of K+·DB18C6·(H2O)n, Rb+·DB18C6·(H2O)n, and Cs+·DB18C6·(H2 ...

2018

Characterisation and hydration of ye'elimite containing cements

Frank Bullerjahn

Calcium sulphoaluminate cements (CSA) with the main phase yeâ elimite are a promising class of non-Portland cements which are gaining increasing interest from the cement industry. However, the hydration kinetics of CSA cements varies strongly, even for ce ...

EPFL2018

Hydration Study of Limestone Calcined Clay Cement (LC3) Using Various Grades of Calcined Kaolinitic Clays

Karen Scrivener, François Henri Avet

In this study, the influence of the calcined kaolinite content of calcined clay on the hydration of Limestone Calcined Clay Cement (LC3-50) is investigated. It is shown that with the increase of the calcined kaolinite content of the calcined clay, the clin ...

SPRINGER2018

Reactivity and Performance of Limestone Calcined-Clay Cement (LC3) Cured at Low Temperature

Karen Scrivener, Franco Alberto Zunino Sommariva

Limestone calcined-clay cements (LC3) take advantage of the synergetic effects of calcium carbonate reaction with the additional aluminium provided by the calcined clay. As temperature decreases, calcium carbonate solubility increase, therefore, the early- ...

SPRINGER2018

Evaluating the Critical Roles of Precursor Nature and Water Content When Tailoring Magnetic Nanoparticles for Specific Applications

Assil Bouzid, Carlo Massobrio

Because of the broad range of application of iron oxide nanoparticles (NPs), the control of their size and shape on demand remains a great challenge, as these parameters are of upmost importance to provide NPs with magnetic properties tailored to the targe ...

AMER CHEMICAL SOC2018

Phase assemblage of composite cements

Karen Scrivener, Mohsen Ben Haha, Pawel Tadeusz Durdzinski

The phase assemblage of binary Portland cements with 45 wt% replacement by calcareous fly ash and slag has been investigated by experiment, mass balance and thermodynamic simulations. The input for these calculations was based on clinker reaction measured ...

Pergamon-Elsevier Science Ltd2017

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy

Yixing Chen, Sylvie Roke, Halil Ibrahim Okur, Chung-Wen Liang

Specific ion effects in aqueous solutions are investigated at the molecular, nanoscopic and macroscopic levels. Femtosecond elastic second harmonic scattering (fs-ESHS) is used here to assess the chemical effects of ions on molecular and nanoscopic length ...

2017

Molecular Effects of Concentrated Solutes on Protein Hydration, Dynamics, and Electrostatics

Matteo Dal Peraro, Enrico Spiga, Luciano Andres Abriata

Most studies of protein structure and function are performed in dilute conditions, but proteins typically experience high solute concentrations in their physiological scenarios and biotechnological applications. High solute concentrations have well-known e ...

Cell Press2016

Atomistic Simulations of Silicate Species Interaction with Portlandite Surfaces

Paul Bowen, Sandra Caroline Galmarini, Aslam Kunhi Mohamed

Portlandite (Ca(OH)(2), CH) is the second most abundant hydrate formed in the reaction of Portland cement with water, making it an important component in the built environment. Formation of CH is closely linked to the growth of the main hydrate phase, calc ...

American Chemical Society2016

Development of a new rapid, relevant and reliable (R-3) test method to evaluate the pozzolanic reactivity of calcined kaolinitic clays

Karen Scrivener, Ruben Anton Snellings, Mohsen Ben Haha, François Henri Avet, Adrian Alujas Diaz

The present paper introduces a new rapid, relevant and reliable (R-3) test to predict the pozzolanic activity of calcined clays with kaolinite contents ranging from 0 to 95%. The test is based on the correlation between the chemical reactivity of calcined ...

Pergamon-Elsevier Science Ltd2016

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