Publications associées à Dual system

Editing Tetrasubstituted Carbon: Dual C–O Bond Functionalization of Tertiary Alcohols Enabled by Palladium-Based Dyotropic Rearrangement

Qian Wang, Jieping Zhu, Baochao Yang, Tristan Corentin Pierre Delcaillau

Many elegant asymmetric syntheses of enantioenriched tertiary alcohols have been developed, and both the transition metal-catalyzed and the radical-based peripheral functionalization of tertiary alcohols have attracted intensive research interest in recent ...

2024

A Functional Perspective on Information Measures

Amedeo Roberto Esposito

Since the birth of Information Theory, researchers have defined and exploited various information measures, as well as endowed them with operational meanings. Some were born as a "solution to a problem", like Shannon's Entropy and Mutual Information. Other ...

EPFL2022

Stochastic distributed learning with gradient quantization and double-variance reduction

Sebastian Urban Stich, Konstantin Mishchenko

We consider distributed optimization over several devices, each sending incremental model updates to a central server. This setting is considered, for instance, in federated learning. Various schemes have been designed to compress the model updates in orde ...

TAYLOR & FRANCIS LTD2022

Topological Linear System Identification via Moderate Deviations Theory

Daniel Kuhn, Tobias Sutter, Wouter Jongeneel

Two dynamical systems are topologically equivalent when their phase-portraits can be morphed into each other by a homeomorphic coordinate transformation on the state space. The induced equivalence classes capture qualitative properties such as stability or ...

2022

A Unified Theory of Robust and Distributionally Robust Optimization via the Primal-Worst-Equals-Dual-Best Principle

Daniel Kuhn, Jianzhe Zhen, Wolfram Wiesemann

Robust and distributionally robust optimization are modeling paradigms for decision-making under uncertainty where the uncertain parameters are only known to reside in an uncertainty set or are governed by any probability distribution from within an ambigu ...

2023

Voss surfaces: A design space for geodesic gridshells

Corentin Jean Dominique Fivet, Nicolas Robin Montagne, Olivier Baverel

The design of envelopes with complex geometries often leads to construction challenges. To overcome these difficulties, resorting to discrete differential geometry proved successful by establishing close links between mesh properties and the existence of g ...

2021

Voss Surfaces: A Design Space for Geodesic Gridshells

Corentin Jean Dominique Fivet, Nicolas Robin Montagne, Olivier Baverel

The design of envelopes with complex geometries often leads to construction challenges. To overcome these difficulties, resorting to discrete differential geometry proved successful by establishing close links between mesh properties and the existence of g ...

2020

Dual Dynamically Orthogonal approximation of incompressible Navier Stokes equations with random boundary conditions

Fabio Nobile, Eleonora Musharbash

In this paper we propose a method for the strong imposition of random Dirichlet boundary conditions in the Dynamical Low Rank (DLR) approximation of parabolic PDEs and, in particular, incompressible Navier Stokes equations. We show that the DLR variational ...

Elsevier2018

A Looping-Delooping Adjunction For Topological Spaces

Martina Rovelli

Every principal G-bundle over X is classified up to equivalence by a homotopy class X -> BG, where BG is the classifying space of G. On the other hand, for every nice topological space X Milnor constructed a strict model of its loop space (Omega) over tild ...

Int Press Boston, Inc2017

Polarised black holes in ABJM

João Miguel Augusto Penedones Fernandes

We numerically construct asymptotically AdS(4) solutions to Einstein-Maxwell-dilaton theory. These have a dipolar electrostatic potential turned on at the conformal boundary S-2 x R-t. We find two classes of geometries: AdS soliton solutions that encode th ...

Springer Nature2017

Converse Bounds for Noisy Group Testing with Arbitrary Measurement Matrices

Volkan Cevher, Jonathan Mark Scarlett

We consider the group testing problem, in which one seeks to identify a subset of defective items within a larger set of items based on a number of noisy tests. While matching achievability and converse bounds are known in several cases of interest for i.i ...

Ieee2016

Design of Steerable Wavelets to Detect Multifold Junctions

Michaël Unser, Cédric René Jean Vonesch, Zsuzsanna Püspöki, Virginie Sophie Uhlmann

We propose a framework for the detection of junctions in images. Although the detection of edges and key points is a well examined and described area, the multiscale detection of junction centers, especially for odd orders, poses a challenge in pattern ana ...

IEEE2015

Polymer Brush Guided Formation of Conformal, Plasmonic Nanoparticle-Based Electrodes for Microwire Solar Cells

Harm-Anton Klok, Anna Fontcuberta i Morral, Caroline Sugnaux, Anna Dalmau Mallorquí

This report explores the use of sacrificial thin polymer films prepared by surface-initiated polymerization as a template for the fabrication of highly conformal metal nanoparticle solar cell electrodes. As a first proof-of-principle, the use of this metho ...

Wiley-Blackwell2015

Asymptotic Behavior of Solutions to the Helmholtz Equations with Sign Changing Coefficients

Hoài-Minh Nguyên

This paper is devoted to the study of the behavior of the unique solution u delta is an element of H-0(1)(Omega), as delta -> 0, to the equation div(s(delta)A del u(delta)) + k(2)s(0)Sigma u(delta) = s0 f in Omega, where Omega is a smooth connected bounded ...

American Mathematical Society2015

Trace maps for Mackey algebras

Baptiste Thierry Pierre Rognerud

Let G be a finite group and R be a commutative ring. The Mackey algebra μR(G) shares a lot of properties with the group algebra RG however, there are some differences. For example, the group algebra is a symmetric algebra and this is not always the case fo ...

Elsevier2015

Convex Generalizations of Total Variation Based on the Structure Tensor with Applications to Inverse Problems

Michaël Unser, Stamatios Lefkimmiatis

We introduce a generic convex energy functional that is suitable for both grayscale and vector-valued images. Our functional is based on the eigenvalues of the structure tensor, therefore it penalizes image variation at every point by taking into account t ...

Springer2013

Intricacies of Describing Weak Interactions involving Halogen Atoms within Density Functional Theory

Ursula Röthlisberger, Ivano Tavernelli, Manuel Dömer

In this work we assess the performance of different dispersion-corrected DFT approaches (M06, M06-2X, DFT-D3 and DCACP) in reproducing high-level wave function based benchmark calculations on the weakly bound halogen dimers (X2)2 and X2-Ar (for X=F,Cl,Br,I ...

Amer Chemical Soc2013

A Unifying Parametric Framework for 2D Steerable Wavelet Transforms

Michaël Unser

We introduce a complete parameterization of the family of two-dimensional steerable wavelets that are polar-separable in the Fourier domain under the constraint of self-reversibility. These wavelets are constructed by multiorder generalized Riesz transform ...

Siam Publications2013

Differential peptide binding to CD40 evokes counteractive responses

Giovanni Dietler, Sandor Kasas, Charles Roduit, Livan Bladimir Alonso Sarduy, Bhaskar Saha

The antigen-presenting cell-expressed CD40 is implied in the regulation of counteractive immune responses such as induction of pro-inflammatory and anti-inflammatory cytokines interleukin (IL)-12 and IL-10, respectively. The mechanism of this duality in CD ...

Elsevier2012

Automatic Verification of Parametric Specifications with Complex Topologies

Swen Jacobs

The focus of this paper is on reducing the complexity in verification by exploiting modularity at various levels: in specification, in verification, and structurally. For specifications, we use the modular language CSP-OZ-DC, which allows us to decouple ve ...

2010