Publications associées à Analyse gravimétrique

Adding Color to Mass Spectra of Biopolymers: Charge Determination Analysis (CHARDA) Assigns Charge State to Every Ion Peak

Yury Tsybin, Natalia Gasilova, Laure Menin, Anton Kozhinov, Konstantin Nagornov

Traditionally, mass spectrometry (MS) output is the ion abundance plotted versus the ionic mass-to-charge ratio m/z. While employing only commercially available equipment, Charge Determination Analysis (CHARDA) adds a third dimension to MS, estimating for ...

Amer Chemical Soc2024

Modular Multiplatform Compatible Air Measurement System (MoMuCAMS): a new modular platform for boundary layer aerosol and trace gas vertical measurements in extreme environments

Julia Schmale, Andrea Baccarini, Roman Pohorsky

The Modular Multiplatform Compatible Air Measurement System (MoMuCAMS) is a newly developed in situ aerosol and trace gas measurement platform for lower-atmospheric vertical profiling. MoMuCAMS has been primarily designed to be attached to a Helikite, a ru ...

2024

Cloud Condensation Nuclei (CCN) concentrations measured in the Swiss container during MOSAiC 2019/2020

Julia Schmale, Benjamin Jérémy Laurent Heutte, Nora Bergner, Ivo Fabio Beck, Hélène Paule Angot, Lubna Dada

This dataset contains CCN concentrations at five supersaturation levels, averaged to 1 min time resolution, measured during the year-long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition from October 2019 to Septem ...

2023

Electron Beam Induced Copper Deposition from Carboxylate Precursors and the Study of Underlying Growth Mechanisms

Luisa Berger

The fabrication of defined and high-quality metal nanostructures is an ongoing topic of research. Direct-write deposition of copper nanostructures is of great value for many fields of research and industrial applications. Focused electron beam induced depo ...

EPFL2020

Fast real time and quantitative gas analysis method for the investigation of the CO2 reduction reaction mechanism

Andreas Züttel, Emanuele Moioli, Wen Luo, Robin Tobias Andreas Mutschler

We present a new fast real time and quantitative gas analysis method by means of mass spectrometry (MS), which has approximately an order of magnitude faster sampling rate in comparison with a traditional gas chromatography. The method is presented and dis ...

AMER INST PHYSICS2018

CO2 hydrogenation reaction over pristine Fe, Co, Ni, Cu and Al2O3 supported Ru: Comparison and determination of the activation energies

Andreas Züttel, Noris André Gallandat, Emanuele Moioli, Wen Luo, Robin Tobias Andreas Mutschler

Fe, Co, Ni and Cu are the main non-noble industrially significant catalysts in the CO2 and CO gas phase hydrogenation reaction towards hydrocarbons and alcohols. These catalysts are typically supported on metal oxides such as SiO2, TiO2, Al2O3 and ZnO, in ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2018

Synthesis and In Vitro (Anticancer) Evaluation of eta(6)-Arene Ruthenium Complexes Bearing Stannyl Ligands

Paul Joseph Dyson, Tina Riedel

Treatment of the known half-sandwich complexes of the type [(eta(6)-C6H6)RuCl2(P(OR)(3))] (R = Me or Ph) with SnCl2 yielded three new half-sandwich ruthenium complexes (C1-C3): [(eta(6)-C6H6)RuCl(SnCl3)(P(OMe)(3))] (C1), [(eta(6)-C6H6)RuCl(SnCl3)(P(OPh)(3) ...

2017

Benzimidazolium salt-based solid-state electrolytes afford efficient quantum-dot sensitized solar cells

Paul Joseph Dyson, Zhaofu Fei, Zhangjun Huang, Yefeng Wang

A novel solid-state electrolyte based on 1,3-dihexylbenzimidazolium ([DHexBIm]) cations combined with Br-, BF4- or SCN- anions is used in CdS/CdSe sensitized quantum dot sensitized solar cells (QDSSCs). A power conversion efficiency of 4.26% was achieved w ...

Royal Society of Chemistry2017

Effect of cement substitution by limestone on the hydration and microstructural development of ultra-high performance concrete (UHPC)

Karen Scrivener, Mohammadhadi Kazemi Kamyab, Wei Sun, Wei Huang

The effect of limestone on the hydration and microstructural development of ultra high performance concrete (UHPC) with different levels of replacement (34%, 54% and 74% by volume) was investigated. Up to 54% replacement of cement by limestone the mixes sh ...

Elsevier2017

A New 1,3,4-Oxadiazole-Based Hole-Transport Material for Efficient CH3NH3PbBr3 Perovskite Solar Cells

Michael Graetzel, Ulf Anders Hagfeldt, Antonio Abate, Juan-Pablo Correa-Baena

A new hole-transport material (HTM) based on the 1,3,4-oxadiazole moiety (H1) was prepared through a single-step synthetic pathway starting from commercially available products. Thanks to a deep HOMO level, H1 was used as HTM in CH3NH3PbBr3 perovskite sola ...

Wiley-V C H Verlag Gmbh2016

Novel Approaches in Cold Ion Spectroscopy for Structural Characterization of Biomolecules in the Gas Phase

Vladimir Kopysov

Mass spectrometry is a powerful analytical technique, which has become invaluable across a wide range of scientific fields, such as "omics" sciences (e.g., proteomics), doping control and forensic sciences, drug development, environmental analysis, geologi ...

EPFL2016

Effect of treatment on the microstructural characteristics of bio-improved sand

Lyesse Laloui, Dimitrios Terzis

Bio-chemical processes have recently become the core of several studies in the geoengineering field, where the emphasis is placed on new and emerging applications. Microbially Induced Calcite Precipitation has been introduced as an alternative cementation ...

IOS Press, 20152015

Syntheses, structures and properties of cobalt and manganese complexes based on pyridine-2,3,5,6-tetracarboxylic acid

Chi Wai Cheung, Weijin Wang, Hong-Ling Gao

Two new complexes based on pyridine-2,3,5,6-tetracarboxylic acid(H(4)pdtc) as ligand, {[Co-2(pdtc)(H2O)(4)]center dot H2O}(n) (1) and {Mn-2(pdtc)(H2O)(4)}(n) (2), have been obtained by hydrothermal syntheses and characterized by IR, elemental analysis, X-r ...

Elsevier Science Bv2015

Advances in Structural Elucidation of Small Molecules via High Performance Mass Spectrometry

Konstantin Zhurov

Qualitative and quantitative analyte analysis is omnipresent: from quality control in food, pharmaceutical, biotechnology industries, to new molecular syntheses, detection of explosives and drugs, as well as natural compound mixture analysis, such as crude ...

EPFL2014

LSPR properties of metal nanoparticles adsorbed at a liquid–liquid interface

Hubert Girault, Pingping Fang

Unlike the solid–air and solid–liquid interfaces, the optical properties of metal nanoparticles adsorbed at the liquid–liquid interface have not been theoretically exploited to date. In this work, the three dimensional finite difference time domain (3D-FDT ...

Royal Soc Chemistry2013

Characterization of Silver Nanoparticle Products Using Asymmetric Flow Field Flow Fractionation with a Multidetector Approach - a Comparison to Transmission Electron Microscopy and Batch Dynamic Light Scattering

Christian Ludwig, Andrea Ulrich, Harald Hagendorfer

Due to the already prevalent and increasing use of silver-nanoparticle (Ag-NP) products and the raised concerns in particular for the aquatic environment, analytical techniques for the characterization of such products are of need. However, because Ag-NP p ...

2012

Comparison of naphthalene bioavailability determined by whole-cell biosensing and availability determined by extraction with Tenax

Jan Roelof van der Meer, Stefanie Kohlmeier, Robin Tecon

A rapid biological method for the determination of the bioavailability of naphthalene was developed and its value as an alternative to extraction-based chemical approaches demonstrated. Genetically engineered whole-cell biosensors are used to determine bio ...

2008

Nondestructive Characterization by Advanced Synchrotron Light Techniques: Spectromicroscopy and Coherent Radiology

Giorgio Margaritondo

The advanced characteristics of synchrotron light has led in recent years to the development of a series of new experimental techniques to investigate chemical and physical properties on a microscopic scale. Although originally developed for materials scie ...

2008

Phosphate adsorption by mineral weathering particles in oligotrophic waters of high particle content

Alfred Johny Wüest, Beat Mueller

We investigated the interactions of dissolved reactive phosphorus (DRP) and dissolved nonreactive phosphorus (DNRP) with suspended and settled aquatic particles. The sorption to minerogenic particles from an alpine catchment collected in rivers, hydropower ...

Amer Geophysical Union2006

Ageing of porous carbon electrodes

Manxi Zhu

Ultracapacitors, also called electrochemical double layer capacitors (EDLC) or supercapacitors, may improve the performance of conventional electrolytic capacitors in terms of specific energy, or improve the performance of rechargeable batteries in terms o ...

EPFL2006