Publications associées à Death metal

Optical absorption properties of metal-organic frameworks: solid stateversusmolecular perspective

Berend Smit, Ivano Tavernelli, Anne-Clémence Corminboeuf, Maria Fumanal Quintana

The vast chemical space of metal and ligand combinations in Transition Metal Complexes (TMCs) gives rise to a rich variety of electronic excited states with local and non-local character such as intra-ligand (IL), metal-centered (MC), metal-to-ligand (MLCT ...

2020

Electron Beam Induced Copper Deposition from Carboxylate Precursors and the Study of Underlying Growth Mechanisms

Luisa Berger

The fabrication of defined and high-quality metal nanostructures is an ongoing topic of research. Direct-write deposition of copper nanostructures is of great value for many fields of research and industrial applications. Focused electron beam induced depo ...

EPFL2020

Heat-transfer at the interface between a metal and a non-metal: influence of ultra-thin interlayers, interface chemistry and atomic order

Maïté Blank

The Thermal Boundary Conductance (TBC) at the interface between metals and dielectrics is of key importance for heat transport in structures heterogeneous on a scale from 100 µm downwards. In this thesis the TBC of a large number of metal/dielectric couple ...

EPFL2019

Quantifying the role of surface plasmon excitation and hot carrier transport in plasmonic devices

Giulia Tagliabue

Harnessing photoexcited “hot” carriers in metallic nanostructures could define a new phase of non-equilibrium optoelectronics for photodetection and photocatalysis. Surface plasmons are considered pivotal for enabling efficient operation of hot carrier dev ...

Nature Research2018

Suppressing Nucleation in Metal–Organic Chemical Vapor Deposition of MoS2

Andras Kis, Dmitry Ovchinnikov, Dmitrii Unuchek, Hokwon Kim, Davide Deiana

Toward the large-area deposition of MoS2 layers, we employ metal–organic precursors of Mo and S for a facile and reproducible van der Waals epitaxy on c-plane sapphire. Exposing c-sapphire substrates to alkali metal halide salts such as KI or NaCl together ...

American Chemical Society (ACS)2017

Varying the metal to ethacrynic acid ratio in ruthenium(ii)/osmium(ii)-p-cymene conjugates

Paul Joseph Dyson, Catherine Marie Amélie Clavel, Mylène Soudani, Emilia Paunescu

Following the identification of a ruthenium(II)-arene complex with an ethacrynic acid-modified imidazole ligand, which inhibits glutathione transferase (GST) and is cytotoxic to chemo-resistant cancer cells, a series of structurally related ruthenium(II)- ...

Elsevier2017

Microfluidic and Electrokinetic Manipulation of Single Cells

Samuel Kilchenmann

Traditional cell assays report on the average results of a cell population. However, a wide range of new tools are being developed for a fundamental understanding of single cell's functionality. Nonetheless, the current tools are either limited in their th ...

EPFL2017

Photo-transformation of pedogenic humic acid and consequences for Cd(II), Cu(II) and Pb(II) speciation and bioavailability to green microalga

Pascal Miéville

Humic substances (HS) play key role in toxic metal binding and protecting aquatic microorganisms from metal-induced stress. Any environmental changes that could alter HS concentration and reactivity can be expected to modify metal complexation and thus aff ...

Pergamon-Elsevier Science Ltd2015

Ultrafast Photophysics of Transition Metal Complexes

Majed Chergui

CONSPECTUS: The properties of transition metal complexes are interesting not only for their potential applications in solar energy conversion, OLEDs, molecular electronics, biology, photochemistry, etc. but also for their fascinating photophysical properti ...

American Chemical Society2015

Two-Dimensional Metal-Organic Networks as a New Class of Electrocatalysts

Benjamin Wurster

This thesis deals with the electrocatalytic properties of two-dimensional metal organic coordination networks (2D-MOCNs) self-assembled on electrode surfaces and catalytic activity of 2D-MOCNs is demonstrated for the first time. The low-coordinated metal c ...

EPFL2015

LSPR Chip for Parallel, Rapid, and Sensitive Detection of Cancer Markers in Serum

Sebastian Maerkl, Jose Luis Garcia Cordero

Label-free biosensing based on metallic nano-particles supporting localized surface plasmon resonances (LSPR) has recently received growing interest (Anker, J. N., et al. Nat. Mater. 2008, 7, 442-453). Besides its competitive sensitivity (Yonzon, C. R., et ...

Amer Chemical Soc2014

Basic investigations of electrostatic turbulence and its interaction with plasma and suprathermal ions in a simple magnetized toroidal plasma

Ambrogio Fasoli, Ivo Furno, Paolo Ricci, Christian Gabriel Theiler, Joaquim Loizu Cisquella, Fabio Avino, Nicola Vianello, Sébastien Jolliet, Fabio Riva, Kyle Gustafson, Alexandre Dominique Bovet

Progress in basic understanding of turbulence and its influence on the transport both of the plasma bulk and of suprathermal components is achieved in the TORPEX simple magnetized torus. This configuration combines a microwave plasma production scheme with ...

IOP Publishing Ltd2013

Porous metal article and method of producing a porous metal article

Andreas Mortensen

A process for producing a metal article containing at least 10% interconnected porosity, using a preform (11), comprising: mixing an organic binder, a wetting agent and a granular material, to obtain a mouldable paste that combines 10 vol. pct. or more of ...

2012

Convective cells and blob control in a simple magnetized plasma

Ambrogio Fasoli, Ivo Furno, Joaquim Loizu Cisquella, Christian Gabriel Theiler

Blob control by creating convective cells using biased electrodes is demonstrated in simple magnetized toroidal plasmas. A two-dimensional array of electrodes is installed on a metal limiter to obtain different biasing schemes. Detailed two-dimensional mea ...

American Physical Society2012

Preform to produce metallic foam

Andreas Mortensen

A process for producing a metal article containing at least 10% interconnected porosity, using a preform (11), comprising: mixing an organic binder, a wetting agent and a granular material, to obtain a mouldable paste that combines 10 vol. pct. or more of ...

2010

Cu and Pb accumulation by the marine diatom Thalassiosira weissflogii in the presence of humic acids

Metal complexation by dissolved organic matter, as humic acids, is considered to decrease metal bioavailability by lowering the free metal ion concentration. However, dissolved organic matter adsorption on cell surfaces can modify cell membrane properties, ...

2010

Micro-, meso- and macrostructures in replicated microcellular aluminium

Yves Conde

This thesis is focused on the properties of microcellular aluminium, produced by replication processing, at the micro, meso and macrostructural level. The replication process is based on the infiltration of a porous sodium chloride (NaCl) perform with molt ...

EPFL2009

Power Distribution Paths for 3-D IC

Giovanni De Micheli, Vasileios Pavlidis

Distributing power and ground to a vertically integrated system is a complex and difficult task. Interplane communication and power delivery are achieved by through silicon vias (TSVs) in most of the manufacturing techniques for three-dimensional (3-D) cir ...

ACM Order Department, P.O. Box 64145, Baltimore, MD 21264 USA2009

Matthiessen's rule in MgB2: Resistivity and T-c as a function of point defect concentration

László Forró, Richard Gaal, Balazs Sipos, Janusz Andrzej Karpinski, Neven Barisic

We present the results of a systematic study of the temperature-dependent resistivity and of T-c of a single crystal MgB2 sample as a function of point defect concentration. We have found linear, albeit weak, correlation between the decreasing superconduct ...

2007

Nanofibres de carbone sur filtre métallique comme support catalytique structuré

Pascal Tribolet

The main objectives of this work are 2-fold : The development of a novel type of composite material based on carbon nanofibers supported on sintered metal fibers filters (CNF/SMF) and to explore the use of this material as a catalytic support for a model r ...

EPFL2006