Publications de Philip Pattison

Phase transition in an organic ferroelectric: glycinium phosphite, with and without X-ray radiation damage

Thermal evolution of an organic ferroelectric, namely, glycinium phosphite, was probed by multi-temperature single-crystal diffraction using synchrotron radiation and also by a similar experiment with a laboratory X-ray diffractometer. Both series of measu ...

2021

Hidden Charge Order in an Iron Oxide Square-Lattice Compound

Philip Pattison

Since the discovery of charge disproportionation in the FeO2 square-lattice compound Sr3Fe2O7 by Mossbauer spectroscopy more than fifty years ago, the spatial ordering pattern of the disproportionated charges has remained "hidden" to conventional diffracti ...

2021

One-dimensional composite host-guest structure in BaVS3

Helmuth Berger, László Forró, Gervais Chapuis, Neven Barisic, Alla Arakcheeva, Philip Pattison

A detailed synchrotron X-ray diffraction (XRD) study performed with a single crystal of BaVS3 (barium vanadium trisulfide) in the temperature range between 10 and 295 K is reported. Aside from the known tetragonal–orthorhombic (240 K) and orthorhombic–mono ...

2021

Zero-dimensional hybrid iodobismuthate derivatives: from structure study to photovoltaic application

Mohammad Khaja Nazeeruddin, Kurt Schenk, Philip Pattison, Peng Gao, Farzaneh Fadaei Tirani, Yi Zhang

The quest for lead-free light-absorbing perovskite materials has long been the target of researchers to make the 'star' material friendly to the commercial market. After a summary of different lead-free solar absorbers, we demonstrate a zero-dimensional io ...

ROYAL SOC CHEMISTRY2020

Chirok: a post-refinement tool to analyse absolute structure

Philip Pattison

Chirok is software for a post-refinement test of the absolute structure. The software allows a user to calculate a distribution of the measure of chirality based on intensity quotients and linked to the Flack parameter. The distribution is fitted by a set ...

2020

The influence of the incommensurately modulated structure on the physical properties of Fe1.35Ge

Helmuth Berger, László Forró, Alla Arakcheeva, Philip Pattison, Krunoslav Prsa, Jacim Jacimovic, Sergiy Katrych, Andrea Pisoni

Single crystal growth by chemical vapour transport has resulted samples with Fe1.35Ge stoichiometry. Structural study has shown that the large number of vacancies introduces an incommensuately modulated structure. The electrical resistivity is in the 200 m ...

2019

Influence of the organic cation disorder on photoconductivity in ethylenediammonium lead iodide, NH3CH2CH2NH3PbI4

László Forró, Alla Arakcheeva, Bálint Náfrádi, Philip Pattison, Endre Horvath, Pavao Roko Andricevic, Anastasiia Glushkova, Márton Kollár

We report the synthesis and crystal structure of an organic–inorganic compound, ethylenediammonium lead iodide, NH3CH2CH2NH3PbI4. Synchrotron-based single crystal X-ray diffraction experiments revealed that the pristine and thermally treated crystals diffe ...

2018

Reentrant magnetism at the borderline between long-range antiferromagnetic order and spin-glass behavior in the B-site disordered perovskite system Ca2-x SrxFeRuO6

Philip Pattison

We report on the coexistence of magnetic order and disorder in the atomically disordered double perovskites Ca2FeRuO6 and CaSrFeRuO6. Powder x-ray and neutron diffraction were used to investigate the crystal structure and magnetic ordering of these oxides. ...

AMER PHYSICAL SOC2018

Incommensurate atomic density waves in the high-pressure IVb phase of barium

Gervais Chapuis, Alla Arakcheeva, Philip Pattison, Vladimir Dmitriev

The host–guest structures of elements at high pressure discovered a decade ago still leave many open questions due to the lack of precise models based on full exploitation of the diffraction data. This concerns in particular Ba IV, which is stable in the r ...

Int Union Crystallography2017

High-Temperature Ferrimagnetism with Large Coercivity and Exchange Bias in the Partially Ordered 3d/5d Hexagonal Perovskite Ba2Fe1.12Os0.88O6

Philip Pattison

Double perovskite oxides A(2)BB'O-6 combining 3d and 4d or 5d transition metal ions at the B and B' sites feature a variety of magnetic and magneto-electric properties. Targeting Ba2FeOsO6, we synthesized powder samples of nonstoichiometric Ba2Fe1.12Os0.88 ...

American Chemical Society2017

The Intricate Structural Chemistry of MII2nLn-Type Assemblies

Kay Severin, Rosario Scopelliti, Euro Solari, Philip Pattison, Mathieu Jérémie Marmier, Farzaneh Fadaei Tirani, Giacomo Cecot

The reaction of cis-blocked, square-planar MII complexes with tetratopic N-donor ligands is known to give metallasupramolecular assemblies of the formula M2nLn. These assemblies typically adopt barrel-like structures, with the ligands paneling the sides of ...

2017

Discovery of S···C≡N Intramolecular Bonding in a Thiophenylcyanoacrylate-Based Dye: Realizing Charge Transfer Pathways and Dye···TiO

Philip Pattison, Lei Zhang

2017

Crystal growth, structure and magnetic properties of Ca10Cr7O28

Philip Pattison, Sándor Tóth, Yogesh Singh

Institute of Physics2017

Application of micro X-ray diffraction to investigate the reaction products formed by the alkali–silica reaction in concrete structures

Gervais Chapuis, Alla Arakcheeva, Philip Pattison

Alkali-silica reaction (ASR) is one of the most important deterioration mechanisms in concrete leading to substantial damages of structures worldwide. Synchrotron-based micro-X-ray diffraction (micro-XRD) was employed to characterize the mineral phases for ...

Pergamon-Elsevier Science Ltd2016

Thermal induced structural properties of silver(I) sulphate (Ag2SO4)

Philip Pattison

The crystal structures of silver(I) sulphate, Ag2SO4, have been investigated as a function of temperature. A main feature is the phase transition from the low-temperature ordered phase, F ddd, to the high-temperature disordered phase, P63/mmc. In particula ...

Wiley-Blackwell2016

Surface functionalization of dinuclear clathrochelates via Pd-catalyzed cross-coupling reactions: facile synthesis of polypyridyl metalloligands

Kay Severin, Rosario Scopelliti, Euro Solari, Philip Pattison, Mathieu Jérémie Marmier, Giacomo Cecot

Dinuclear clathrochelate complexes are easily accessible by reaction of zinc(II) triflate or cobalt(II) nitrate with arylboronic acids and phenoldioximes. The utilization of brominated arylboronic acids and/or brominated phenoldioximes allows preparing cla ...

2016

The Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages

Kay Severin, Rosario Scopelliti, Euro Solari, Philip Pattison, Konstantin Zhurov, Matthew David Wise, Alba Finelli, Giacomo Cecot, Suzanne Maria Jansze

It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is demonstrated for a series of iron- and palladium-based coordination cages. Functionalized clathrochelate com ...

2016

Probing structural chirality with high-energy synchrotron radiation

Philip Pattison

International Union of Crystallography2016

Neutral Aminyl Radicals Derived from Azoimidazolium Dyes

Andrzej Sienkiewicz, Kay Severin, Rosario Scopelliti, Euro Solari, Philip Pattison, Laurent Alexis Clément Vannay, Henrik Moodysson Rønnow, Léonard Yannick Maurice Eymann, Ivica Zivkovic, Matthew Wodrich, Alexander Tskhovrebov, José Luis Bila

The synthesis and characterization of a new class of neutral aminyl radicals is reported. Monoradicals were obtained by reduction of azoimidazolium dyes with potassium. Structural, spectroscopic, and computational data suggest that the spin density is cent ...

2016

Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands

Kay Severin, Rosario Scopelliti, Euro Solari, Kurt Schenk, Philip Pattison, Mathieu Jérémie Marmier, Matthew David Wise

Polycarboxylate ligands are among the most important building blocks for the synthesis of metal–organic frameworks (MOFs). The ability to access these ligands in an efficient way is of key importance for future applications of MOFs. Here, we demonstrate th ...

2016