Publications de Diego Carnevale

Runaway electron beam control

Basil Duval, Stefano Coda, Diego Carnevale, Georgios Pappas, Joan Decker, Umar Sheikh, Cristian Galperti, Filippo Bagnato, Gergely Papp

Post-disruption runaway electron (RE) beams in tokamaks with large current can cause deep melting of the vessel and are one of the major concerns for ITER operations. Consequently, a considerable effort is provided by the scientific community in order to t ...

IOP PUBLISHING LTD2019

Validation of the ICRF antenna coupling code RAPLICASOL against TOPICA and experiments

Patrick Blanchard, Roland Behn, Basil Duval, Timothy Goodman, Pierre Jacquot, Bruno Marchand, Yves Martin, Pascal Morel, Jean-Marc Moret, Richard Pitts, Olivier Sauter, Holger Reimerdes, Stefano Coda, Alberto Bottino, Marco Wischmeier, Jan Horacek, Andrea Scarabosio, Hartmut Zohm, Alexander Karpushov, Laurie Porte, Yanis Andrebe, Yann Camenen, Thomas Binderup Jensen, Duccio Testa, Telmo David Ribeiro Da Costa, Benoît Labit, Emiliano Fable, Patrycja Nowak-Sliwinska, Javier García Hernández, Ben McMillan, Marc Gruber, Christian Gabriel Theiler, Federico Alberto Alfredo Felici, Jose Felix Vega Stavro, Lenke Horváth, Dávid Wágner, Attila Bencze, Thomas Riedl, Lorenzo Anton-Louis Talà, Diego Carnevale, , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ,

Columnar self-assembly of N,N ',N ''-trihexylbenzene-1,3,5-tricarboxamides investigated by means of NMR spectroscopy and computational methods in solution and the solid state

Diego Carnevale, Mathieu Baudin

The columnar self-assembly resulting from units of N, N', N"-trihexylbenzene-1,3,5-tricarboxamide is investigated in solution and the solid state by means of NMR spectroscopy. A parallel computational study utilizing both semiempirical and DFT methods allo ...

Royal Soc Chemistry2017

Exciting Wide NMR Spectra of Static Solid Samples with Weak Radiofrequency Fields

Geoffrey Bodenhausen, Diego Carnevale, Srinivas Chinthalapalli

Trains of short pulses in the manner of `delays alternating with nutations for tailored excitation' (DANTE) have been applied to the Pake patterns of protons of water molecules trapped in a static powdered sample of barium chlorate monohydrate. The spin dy ...

Walter De Gruyter Gmbh2017

NMR spectroscopy and DFT calculations of a self-assembled arene ruthenium rectangle obtained from a combination of coordination and hydrogen bonds

Diego Carnevale

The hydrogen-bonded arene ruthenium metalla-rectangle, (p-cymene)(2)Ru-2(OOnOO)(UPy)(2)(4+), obtained from 1-(4-oxo-6-undecyl-1,4-dihydropyrimidin-2-yl)-3-(pyridin-4-ylmethyl)urea (UPy) and the dinuclear arene ruthenium clip (p-cymene)(2)Ru-2(OOnOO)Cl ...

Royal Soc Chemistry2016

Homonuclear decoupling for spectral simplification of carbon-13 enriched molecules in solution-state NMR enhanced by dissolution DNP

Geoffrey Bodenhausen, Sami Jannin, Aurélien Bornet, Diego Carnevale, Srinivas Chinthalapalli

Complex overlapping multiplets due to scalar couplings (n)J(C-13, C-13) in fully C-13-enriched molecules can be simplified by polychromatic irradiation of selected spins. The signal intensities of the remaining non-irradiated signals are proportional to th ...

Royal Society of Chemistry2016

Rotation-induced recovery and bleaching in magnetic resonance

Geoffrey Bodenhausen, Diego Carnevale, Srinivas Chinthalapalli, Angel Joaquin Perez Linde

Thurber and Tycko recently described a 'bleaching effect' that occurs in magnetic resonance when solid samples that are doped with paramagnetic agents are subjected to rotation by magic angle spinning (MAS) in a static magnetic field with a rotation period ...

Royal Society of Chemistry2015

Challenges in preparing, preserving and detecting para-water in bulk: overcoming proton exchange and other hurdles

Geoffrey Bodenhausen, Sami Jannin, Aurélien Bornet, Jonas Milani, Nicola Salvi, Diego Carnevale, Roberto Buratto, Daniele Mammoli, Estel Canet Martinez

Para-water is an analogue of para-hydrogen, where the two proton spins are in a quantum state that is antisymmetric under permutation, also known as singlet state. The populations of the nuclear spin states in para-water are believed to have long lifetimes ...

Royal Society of Chemistry2015

Insights into the Catalytic Activity of Nitridated Fibrous Silica (KCC-1) Nanocatalysts from N-15 and Si-29 NMR Spectroscopy Enhanced by Dynamic Nuclear Polarization

Geoffrey Bodenhausen, Diego Carnevale, Angel Joaquin Perez Linde

Fibrous nanosilica (KCC-1) oxynitrides are promising solid-base catalysts. Paradoxically, when their nitrogen content increases, their catalytic activity decreases. This counterintuitive observation is explained here for the first time using N-15-solid-sta ...

Wiley-Blackwell2015

Probing Al-27-C-13 proximities in metal-organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy

Geoffrey Bodenhausen, Diego Carnevale

We show how Al-27-C-13 proximities in the microporous metal-organic framework MIL-100(Al) can be probed using advanced Al-27-C-13 NMR methods boosted by Dynamic Nuclear Polarization. ...

Royal Society of Chemistry2014

Solid-state NMR measurements and DFT calculations of the magnetic shielding tensors of protons of water trapped in barium chlorate monohydrate

Geoffrey Bodenhausen, Diego Carnevale

The magnetic shielding tensors of protons of water in barium chlorate monohydrate are investigated at room temperature by means of solid-state NMR spectroscopy, both for static powders and under magic-angle spinning conditions, using one- and two-dimension ...

RSC Publishing2014

Solid-state carbon-13 NMR and computational characterization of the N719 ruthenium sensitizer adsorbed on TiO2 nanoparticles

Michael Graetzel, Geoffrey Bodenhausen, Nicola Salvi, Julien Edouard Frey, Diego Carnevale

The ruthenium-containing sensitizing dye N719 grafted on TiO2 nanoparticles was investigated by solidstate NMR. The carbon resonances are assigned by means of 13C cross-polarized dipolar dephasing experiments. DFT calculations of the carbon magnetic shield ...

Royal Society of Chemistry2014

Solid-state NMR enhanced by dynamic nuclear polarization as a novel tool for ribosome structural biology

Geoffrey Bodenhausen, Marc Anthony Caporini, Diego Carnevale

The impact of Nuclear Magnetic Resonance (NMR) on studies of large macromolecular complexes hinges on improvements in sensitivity and resolution. Dynamic nuclear polarization (DNP) in the solid state can offer improved sensitivity, provided sample preparat ...

Springer Verlag2013

Fourier tickling for homonuclear decoupling in nmr

Geoffrey Bodenhausen, Diego Carnevale

PROBLEM TO BE SOLVED: To provide an effective and speedy method for decoupling of homonuclear couplings.SOLUTION: This invention concerns a method for high resolution NMR (nuclear magnetic resonance) measurements comprising the application of excitation pu ...

2013

How to Tickle Spins with a Fourier Transform NMR Spectrometer

Geoffrey Bodenhausen, Diego Carnevale

In the long bygone days of continuous-wave nuclear magnetic resonance (NMR) spectroscopy, a selected transition within a multiplet of a high-resolution spectrum could be irradiated by a highly selective continuous-wave (CW) radio-frequency (rf) field with ...

Wiley-Blackwell2013

Broadband excitation in solid-state NMR using interleaved DANTE pulse trains with N pulses per rotor period

Geoffrey Bodenhausen, Simone Ulzega, Diego Carnevale

We analyze the direct excitation of wide one-dimensional spectra of nuclei with spin I = 1/2 or 1 in rotating solids submitted to pulse trains in the manner of Delays Alternating with Nutations for Tailored Excitation (DANTE), either with one short rotor-s ...

Academic Press Inc - Elsevier Science2013

Analysis of sensitivity enhancement by dynamic nuclear polarization in solid-state NMR: a case study of functionalized mesoporous materials

Geoffrey Bodenhausen, Diego Carnevale

We systematically studied the enhancement factor (per scan) and the sensitivity enhancement (per unit time) in C-13 and Si-29 cross-polarization magic angle spinning (CP-MAS) NMR boosted by dynamic nuclear polarization (DNP) of functionalized mesoporous si ...

Royal Society of Chemistry2013

Mesoporous Silica Nanoparticles Loaded with Surfactant: Low Temperature Magic Angle Spinning C-13 and Si-29 NMR Enhanced by Dynamic Nuclear Polarization

Geoffrey Bodenhausen, Diego Carnevale

We show that dynamic nuclear polarization (DNP) can be used to enhance NMR signals of C-13 and Si-29 nuclei located in mesoporous organic/inorganic hybrid materials, at several hundreds of nanometers from stable radicals (TOTAPOL) trapped in the surroundin ...

American Chemical Society2013

Solid-state proton NMR of paramagnetic metal complexes: DANTE spin echoes for selective excitation in inhomogeneously broadened lines

Geoffrey Bodenhausen, Diego Carnevale, Gerald Bauer, Angel Joaquin Perez Linde

The paramagnetic complex bis(oxazolinylphenyl)amine-Fe(III)Cl-2 is investigated by means of solid-state proton NMR at 18.8 T (800 MHz) using magic-angle spinning at 65 kHz. Spin echoes that are excited and refocused by combs of rotor-synchronized pulses in ...

Elsevier2013

Broadband excitation in solid-state NMR of paramagnetic samples using Delays Alternating with Nutation for Tailored Excitation ('Para-DANTE')

Geoffrey Bodenhausen, Diego Carnevale

This Letter shows that interleaved sequences of short pulses in the manner of 'Delays Alternating with Nutation for Tailored Excitation' (DANTE) with N = 1,2,3 . . . equidistant pulses per rotor period extending over K rotor periods can be used to excite, ...

Elsevier2012