Publications de Joachim Maier | EPFL Graph Search

Mixed ionic-electronic conduction in Ruddlesden-Popper and Dion-Jacobson layered hybrid perovskites with aromatic organic spacers

Michael Graetzel, Davide Moia, Joachim Maier, Jovana Milic, Algirdas Ducinskas, Mina Jung

The understanding of mixed ionic-electronic conductivity in hybrid perovskites has enabled major advances in the development of optoelectronic devices based on this class of materials. While recent investigations revealed the potential of using dimensional ...

Royal Society of Chemistry2024

The Role of Alkyl Chain Length and Halide Counter Ion in Layered Dion−Jacobson Perovskites with Aromatic Spacers

Michael Graetzel, Jacques-Edouard Moser, Davide Moia, Joachim Maier, Loï Charles Carbone, Jovana Milic, George Cameron Fish, Algirdas Ducinskas, Michael Allan Hope

Layered hybrid perovskites based on Dion−Jacobson phases are of interest to various optoelectronic applications. However, the understanding of their structure−property relationships remains limited. Here, we present a systematic study of Dion−Jacobson pero ...

2021

First-principles calculations of iodine-related point defects in CsPbI3

Joachim Maier, Alessandro Senocrate

We present here first principles hybrid functional calculations of the atomic and electronic structure of several iodine-related point defects in CsPbI3, a material relevant for photovoltaic applications. We show that the presence of neutral interstitial I ...

2019

Thermochemical Stability of Hybrid Halide Perovskites

Michael Graetzel, Joachim Maier, Alessandro Senocrate

This contribution discusses the chemical stability of methylammonium (MA) halide perovskites (MAPbI(3), MAPbBr(3), and MAPbCl(3)); it considers degradation processes relevant for devices (vs T, O-2, H2O, voltage, illumination) by outlining their thermodyna ...

2019

Slow CH3NH3+ Diffusion in CH3NH3PbI3 under Light Measured by Solid-State NMR and Tracer Diffusion

Michael Graetzel, Joachim Maier, Alessandro Senocrate

We investigate methylammonium (MA) transport in MA lead iodide under illumination and show this, as in the dark, to be measurable but negligible when compared with the major carriers. H-1 and C-13 nuclear magnetic resonance (NMR) spectra show constant line ...

AMER CHEMICAL SOC2018

Charge carrier chemistry in methylammonium lead iodide

Joachim Maier, Alessandro Senocrate

2018

Interaction of oxygen with halide perovskites

Joachim Maier, Alessandro Senocrate

Royal Society of Chemistry2018

Large tunable photoeffect on ion conduction in halide perovskites and implications for photodecomposition

Joachim Maier, Alessandro Senocrate

2018

The Nature of Ion Conduction in Methylammonium Lead Iodide: A Multimethod Approach

Michael Graetzel, Joachim Maier, Alessandro Senocrate

By applying a multitude of experimental techniques including H-1, N-14, Pb-207 NMR and I-127 NMR/NQR, tracer diffusion, reaction cell and doping experiments, as well as stoichiometric variation, conductivity, and polarization experiments, iodine ions are u ...

Wiley-Blackwell2017

Hill climbing hysteresis of perovskite-based solar cells: a maximum power point tracking investigation

Michael Graetzel, Shaik Mohammed Zakeeruddin, Norman Pellet, Mohammad Ibrahim Dar, Fabrizio Giordano, Joachim Maier

The surge of the power conversion efficiency of metal halide lead perovskite solar cells comes with concerns, such as the long-term ecotoxicity of lead compounds, their sensitivity toward moisture and oxygen, or the scarcity of some of their components. Mo ...

Wiley-Blackwell2017

Proof-of-concept for facile perovskite solar cell recycling

Ulf Anders Hagfeldt, Norman Pellet, Fabrizio Giordano, Joachim Maier, Jeannette Medina Kadro, Othmar Müntener

Perovskite solar cells based on CH3NH3PbI3 and related materials have reached impressive efficiencies that, on a lab scale, can compete with established solar cell technologies, at least in short-term observations. Despite frequently voiced concerns about ...

Royal Soc Chemistry2016

Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange

Michael Graetzel, Joël Teuscher, Norman Pellet, Joachim Maier

We report on rapid halide exchange in metal halide perovskite of the general formula MAPbX(3) (X = Cl, Br, or I). We find that when the perovskite is infiltrated in a mesoscopic scaffold, halide substitution on the perovskite lattice is strikingly fast, be ...

American Chemical Society2015

The Significance of Ion Conduction in a Hybrid Organic-Inorganic Lead-Iodide-Based Perovskite Photosensitizer

Michael Graetzel, Norman Pellet, Joachim Maier

The success of perovskite solar cells has sparked enormous excitement in the photovoltaic community not only because of unexpectedly high efficiencies but also because of the future potential ascribed to such crystalline absorber materials. Far from being ...

Wiley-Blackwell2015

Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting

Michael Graetzel, Mohammad Khaja Nazeeruddin, Norman Pellet, Peng Gao, Joachim Maier

Hybrid organic-inorganic lead halide perovskite APbX(3) pigments, such as methylammonium lead iodide, have recently emerged as excellent light harvesters in solid-state mesoscopic solar cells. An important target for the further improvement of the performa ...

Wiley-Blackwell2014

Nanoionics and Nanoelectronics

Klaus Kern, Joachim Maier

Wiley2009