Publications de Jocelyn Richard Roth

Precious Metals recovery using novel metal-organic framework (MOF)

Gold plays a dominant role in our modern society. Initially used in coinage and jewelry, it has become an essential metal for the electronics industries. Today, more gold is consumed than mined from virgin ores. Therefore, gold recycling methods have becom ...

EPFL2025

Immobilizing amine species in a Cr-MOF for enhanced selectivity in CO2 cycloaddition reactions

Jocelyn Richard Roth, Wendy Lee Queen, Anita Justin, Till Marian Schertenleib, Jordi Espin Marti

After grafting polyalkylamine species onto the ligand within a Cr 3+ -MOF, the material was tested for catalyzing cycloaddition reactions between CO 2 and 1,2-epoxybutane (EB). ...

Royal Society of Chemistry (RSC)2025

How Reproducible is the Synthesis of Zr-Porphyrin Metal-Organic Frameworks? An Interlaboratory Study

Jocelyn Richard Roth, Wendy Lee Queen, Rawan Al Natour

Metal-organic frameworks (MOFs) are a rapidly growing class of materials that offer great promise in various applications. However, the synthesis remains challenging: for example, a range of crystal structures can often be accessed from the same building b ...

Wiley-V C H Verlag Gmbh2024

Post-Synthetic Modification of a MOF via Continuous Flow Methods for Gold E-Waste Recycling

Jocelyn Richard Roth, Wendy Lee Queen, Olga Trukhina, Till Marian Schertenleib, Timo Markus Oskar Felder

This work represents a pioneering effort in utilizing continuous flow methods for the post-synthetic modification of a nanoporous metal-organic framework (Fe-BTC or MIL-100(Fe)) with short-chain redox-active oligomers (poly-p-phenylenediamine, PpPDA). The ...

2024

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Jocelyn Richard Roth, Wendy Lee Queen, Ilia Kochetygov, Anita Justin, Till Marian Schertenleib, Jordi Espin Marti, Sophia Alessandra Pache, Nazanin Taheri

The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...

Wiley-VCH Verlag GmbH2023