Publications de Juan-Pablo Correa-Baena

How far does the defect tolerance of lead-halide perovskites range? The example of Bi impurities introducing efficient recombination centers

Björn Niesen, Simone Meloni, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Zaiwei Wang, Mozhgan Yavari, Chien-Jen Yang, Firouzeh Ebadi Garjan

One of the key properties of lead-halide perovskites employed in solar cells is the defect tolerance of the materials, in particular regarding intrinsic point defects, which mainly form shallow traps. Considering that high luminescence yields and photovolt ...

Royal Society of Chemistry2019

Phosphonic Acid Modification of the Electron Selective Contact: Interfacial Effects in Perovskite Solar Cells

Ulf Anders Hagfeldt, Rebecca Hill, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Silver Hamill Turren Cruz

The role electron-transport layers (ETLs) play in perovskite solar cells (PSCs) is still widely debated. Conduction band alignment at the perovskite/ETL interface has been suggested to be an important role for the performance of the solar cells. However, l ...

AMER CHEMICAL SOC2019

Enhanced charge carrier mobility and lifetime suppress hysteresis and improve efficiency in planar perovskite solar cells

Matthew Thomas Mayer, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba, Silver Hamill Turren Cruz

2018

Low-Temperature Nb-Doped SnO2 Electron-Selective Contact Yields over 20% Efficiency in Planar Perovskite Solar Cells

Shaik Mohammed Zakeeruddin, Ludmilla Steier, Matthew Thomas Mayer, Wolfgang Richard Tress, Jingshan Luo, Juan-Pablo Correa-Baena, Jiyoun Seo, Elham Halvani Anaraki, Silver Hamill Turren Cruz

2018

Perovskite Solar Cells: From the Atomic Level to Film Quality and Device Performance

Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

Wiley-VCH Verlag GmbH2018

Perovskite Solar Cells: From the Laboratory to the Assembly Line

Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

2018

Planar Perovskite Solar Cells with High Open-Circuit Voltage Containing a Supramolecular Iron Complex as Hole Transport Material Dopant

Shaik Mohammed Zakeeruddin, Wolfgang Richard Tress, Yasemin Saygili, Juan-Pablo Correa-Baena, Michael Saliba, Marina Freitag, Bartholomeus Wilhelmus Henricus Saes, Silver Hamill Turren Cruz

2018

High Temperature-Stable Perovskite Solar Cell Based on Low-Cost Carbon Nanotube Hole Contact

Michael Graetzel, Ulf Anders Hagfeldt, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

Mixed ion perovskite solar cells (PSC) are manufactured with a metal-free hole contact based on press-transferred single-walled carbon nanotube (SWCNT) film infiltrated with 2,2,7,-7-tetrakis(N, N-di-p-methoxyphenylamine)-9,90-spirobifluorene (Spiro-OMeTAD ...

Wiley-Blackwell2017

Globularity-Selected Large Molecules for a New Generation of Multication Perovskites

Michael Graetzel, Ulf Anders Hagfeldt, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba, Filippo de Angelis, Silver Hamill Turren Cruz

Perovskite solar cells (PSCs) use perovskites with an APbX(3) structure, where A is a monovalent cation and X is a halide such as Cl, Br, and/or I. Currently, the cations for high-efficiency PSCs are Rb, Cs, methylammonium (MA), and/or formamidinium (FA). ...

Wiley-Blackwell2017

Chemical Distribution of Multiple Cation (Rb+, Cs+, MA(+), and FA(+)) Perovskite Materials by Photoelectron Spectroscopy

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Michael Saliba, Silver Hamill Turren Cruz

Lead-based mixed perovskite materials have emerged in the last couple of years as promising photovoltaic materials. Recently, it was shown that improved material stability can be achieved by incorporating small amounts of inorganic cations (Cs+ and Rb+), p ...

American Chemical Society2017

Identifying and suppressing interfacial recombination to achieve high open-circuit voltage in perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba, Elham Halvani Anaraki, Silver Hamill Turren Cruz

With close to 100% internal quantum efficiency over the absorption spectrum, photocurrents in perovskite solar cells (PSCs) are at their practical limits. It is therefore imperative to improve open-circuit voltages (VOC) in order to go beyond the current 1 ...

Royal Society of Chemistry2017

Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Ulf Anders Hagfeldt, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba, Filippo de Angelis, Silver Hamill Turren Cruz

Perovskites have been demonstrated in solar cells with a power conversion efficiency of well above 20%, which makes them one of the strongest contenders for next generation photovoltaics. While there are no concerns about their efficiency, very little is ...

Royal Soc Chemistry2017

The rapid evolution of highly efficient perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba, Tor Jesper Jacobsson

Perovskite solar cells (PSCs) have attracted much attention because of their rapid rise to 22% efficiencies. Here, we review the rapid evolution of PSCs as they enter a new phase that could revolutionize the photovoltaic industry. In particular, we describ ...

Royal Society of Chemistry2017

Promises and challenges of perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

The efficiencies of perovskite solar cells have gone from single digits to a certified 22.1% in a few years' time. At this stage of their development, the key issues concern how to achieve further improvements in efficiency and long-term stability. We revi ...

American Association for the Advancement of Science2017

Valence Level Character in a Mixed Perovskite Material and Determination of the Valence Band Maximum from Photoelectron Spectroscopy: Variation with Photon Energy

Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Tor Jesper Jacobsson

A better understanding of the electronic structure of perovskite materials used in photovoltaic devices is essential for their development and optimization. In this investigation, synchrotron-based photoelectron spectroscopy (PES) was used to experimentall ...

American Chemical Society2017

Perovskite solar cell - electrochemical double layer capacitor interplay

Michael Graetzel, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Michael Saliba, Silver Hamill Turren Cruz

We demonstrate that by a proper design of a system comprising a perovskite solar cell (PSC) coupled to an electrochemical double-layer capacitor (EDLC), it is possible to simultaneously improve both the PSC and EDLC performance and outperform each single u ...

Elsevier2017

Nondestructive Probing of Perovskite Silicon Tandem Solar Cells Using Multiwavelength Photoluminescence Mapping

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Michael Saliba, Elham Halvani Anaraki

In this paper, spatially resolved photoluminescence (PL) spectroscopy with various excitation wavelengths is presented as a nondestructive and versatile technique providing access to the individual subcells of multijunction solar cells. This method is demo ...

Ieee-Inst Electrical Electronics Engineers Inc2017

Spontaneous crystal coalescence enables highly efficient perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Amita Ummadisingu, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

Perovskite solar cells have recently reached staggering efficiencies, through efforts focused on reducing grain boundaries, by enlarging the size of the crystalline domains that constitute the perovskite films. Here, we demonstrate that smaller crystallite ...

Elsevier Science Bv2017

Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells

Ulf Anders Hagfeldt, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Silver Hamill Turren Cruz

Several aspects on the photophysical characterization of lead halide hybrid organic inorganic perovskite solar cells remain unsolved. It has been observed that ionic transport and polarization of the interfaces cause very slow changes that interfere with t ...

Amer Chemical Soc2017

Room Temperature as a Goldilocks Environment for CH3NH3PbI3 Perovskite Solar Cells: The Importance of Temperature on Device Performance

Ulf Anders Hagfeldt, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Tor Jesper Jacobsson

Terrestrial applications of solar cells during day-night cycling as well as operation in winter and summer involve substantial temperature variations, which influence the photophysics as well as the charge separation and transport properties in the various ...

American Chemical Society2016