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Kyriakos Stylianou

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Publications associées (44)

Photocatalytic system comprising a titanium-based mof

Berend Smit, Kyriakos Stylianou, Christopher Patrick Ireland, Stavroula Kampouri, Ngoc Tú Nguyên

The present invention concerns a photocatalytic system comprising or consisting of: a titanium-based metal-organic framework MOF based on or including a single ligand type or a plurality of different ligand types for generating photo-generated charge carri ...

2019

Guest-dependent negative thermal expansion in a lanthanide-based metal-organic framework

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Andrzej Gladysiak

A lanthanide-based metal-organic framework (MOF) named SION-2 displays strong and tuneable uniaxial negative thermal expansion (NTE). The coefficient of thermal expansion alpha(1) reaches -153(6) MK-1 between 100 and 340 K, which is the highest value repor ...

2019

Nucleobase pairing and photodimerization in a biologically derived metal-organic framework nanoreactor

Berend Smit, Dominik Józef Kubicki, David Lyndon Emsley, Samantha Lynn Anderson, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Ngoc Tú Nguyên

Biologically derived metal-organic frameworks (bio-MOFs) are of great importance as they can be used as models for bio-mimicking and in catalysis, allowing us to gain insights into how large biological molecules function. Through rational design, here we r ...

Nature Research2019

In Situ Formation of Frustrated Lewis Pairs in a Water-Tolerant Metal-Organic Framework for the Transformation of CO2

Paul Joseph Dyson, Fatmah Ebrahim, Kyriakos Stylianou, Serhii Shyshkanov, Ngoc Tú Nguyên

Frustrated Lewis pairs (FLPs) consist of sterically hindered Lewis acids and Lewis bases, which provide high catalytic activity towards non-metal-mediated activation of "inert" small molecules, including CO2 among others. One critical issue of homogeneous ...

Wiley-VCH Verlag GmbH2019

Data-driven design of metal-organic frameworks for wet flue gas CO2 capture

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Christopher Patrick Ireland, Arunraj Chidambaram, Pascal Alexander Schouwink, Enrique Garcia Diez, Susana Garcia Lopez

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation(1). Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions(2), much effort is focused on developing ...

2019

Selective, Fast-Response, and Regenerable Metal-Organic Framework for Sampling Excess Fluoride Levels in Drinking Water

Paul Joseph Dyson, Fatmah Ebrahim, Kyriakos Stylianou, Andrzej Gladysiak, Serhii Shyshkanov, Ngoc Tú Nguyên, Patrick Favre

Prolonged consumption of water contaminated with fluoride ions (F-) at concentrations exceeding 1.5 ppm can lead to considerable health implications, particularly in children and developing embryos. With irreversible and potentially severe forms of fluorid ...

2019

Discovery of a self-healing catalyst for the hydrolytic dehydrogenation of ammonia borane

Mounir Driss Mensi, Emad Oveisi, Fatmah Ebrahim, Kyriakos Stylianou, Andrzej Gladysiak, Bardiya Valizadeh, Ngoc Tú Nguyên, Fatma Pelin Uran

Sustainable catalysts based on earth-abundant elements are considered as economical alternatives to precious-metal-bearing catalysts and could be impactful for many applications. Self-healing sustainable catalysts, which in addition to their 'green' charac ...

Royal Society of Chemistry2019

Selective adsorption of carbon dioxide by a metal-organic framework

Berend Smit, Kyriakos Stylianou, Peter George Boyd, Arunraj Chidambaram

The present invention relates to the removal of carbon dioxide from gases. More particularly, the invention relates to the use of metal-organic frameworks for a selective adsorption of carbon dioxide from a gas. Further, the invention relates to a method f ...

2019

Photocatalytic hydrogen generation from a visible-light responsive metal–organic framework system: the impact of nickel phosphide nanoparticles

László Forró, Andrzej Sienkiewicz, Kevin Sivula, Gloria Capano, Fatmah Ebrahim, Nestor Guijarro Carratala, Berend Smit, Kyriakos Stylianou, Daniele Ongari, Christopher Patrick Ireland, Bardiya Valizadeh, Stavroula Kampouri, Amber Kashan Mace, Ngoc Tú Nguyên

Royal Society of Chemistry2018

Lanthanide-based near-infrared emitting metal-organic frameworks with tunable excitation wavelengths and high quantum yields

Gloria Capano, Fatmah Ebrahim, Berend Smit, Kyriakos Stylianou, Andrzej Gladysiak, Arunraj Chidambaram, Bardiya Valizadeh, Ngoc Tú Nguyên

Royal Society of Chemistry2018

Porous Metal-Organic Framework@Polymer Beads for Iodine Capture and Recovery Using a Gas-Sparged Column

Berend Smit, Kyriakos Stylianou, Bardiya Valizadeh, Ngoc Tú Nguyên

2018

Shape engineering of metal-organic frameworks

Kyriakos Stylianou, Bardiya Valizadeh, Ngoc Tú Nguyên

2018

Shedding Light on the Protonation States and Location of Protonated N Atoms of Adenine in Metal-Organic Frameworks

Berend Smit, Samantha Lynn Anderson, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Ngoc Tú Nguyên

2018

Mixed-phase MOF-derived Titanium Dioxide for Photocatalytic Hydrogen Evolution: The Impact of the Templated Morphology

Mounir Driss Mensi, Emad Oveisi, Kyriakos Stylianou, Christopher Patrick Ireland, Bardiya Valizadeh, Stavroula Kampouri, Pascal Alexander Schouwink

2018

Biporous Metal-Organic Framework with Tunable CO2/CH4 Separation Performance Facilitated by Intrinsic Flexibility

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Daniele Ongari, Peter George Boyd, Andrzej Gladysiak, Arunraj Chidambaram, Kathryn Suzanne Deeg, Kaili Yee Ordiz

In this work, we report the synthesis of SION-8, a novel metal-organic framework (MOF) based on Ca(II) and a tetracarboxylate ligand TBAPy(4-) endowed with two chemically distinct types of pores characterized by their hydrophobic and hydrophilic properties ...

2018

Photoluminescent, upconversion luminescent and nonlinear optical metal-organic frameworks: From fundamental photophysics to potential applications

Fatmah Ebrahim, Kyriakos Stylianou, Ngoc Tú Nguyên

Metal-organic frameworks (MOFs) are a class of porous materials prepared by the self-assembly of metal ions or clusters with organic ligands. The unique characteristics of MOFs, including structural tunability, high surface areas, low densities and tailore ...

2018

Electronic metal–organic framework sensors

Kyriakos Stylianou, Arunraj Chidambaram

Metal–organic frameworks (MOFs), a class of crystalline and porous materials, are synthesized through the self-assembly of organic ligands and inorganic metal nodes (ions or clusters). For the past few years, MOFs have been in the limelight due to their st ...

2018

Photocatalytic Hydrogen Generation from a Visible-Light-Responsive Metal–Organic Framework System: Stability versus Activity of Molybdenum Sulfide Cocatalysts

Berend Smit, Andreas Züttel, Kyriakos Stylianou, Daniele Ongari, Ophélie Marie Planes, Bardiya Valizadeh, Stavroula Kampouri, Wen Luo, Ngoc Tú Nguyên

We report the use of two earth abundant molybdenum sulfide-based cocatalysts, Mo(3)S(13)(2-)clusters and 1T-MoS2 nanoparticles (NPs), in combination with the visible-light active metal-organic framework (MOF) MIL-125-NH2 for the photocatalytic generation o ...

2018

Rational Design of a Low-Cost, High-Performance Metal-Organic Framework for Hydrogen Storage and Carbon Capture

Berend Smit, Kyriakos Stylianou, Matthew David Witman, Andrzej Gladysiak

We present the in silico design of a MOF-74 analogue, hereon known as M-2(DHFUMA) [M = Mg, Fe, Co, Ni, Zn], with enhanced small-molecule adsorption properties over the original M-2(DOBDC) series. Constructed from 2,3-dihydroxyfumarate (DHFUMA), an aliphati ...

2017

Biologically derived metal organic frameworks

Samantha Lynn Anderson, Kyriakos Stylianou

Metal organic frameworks (MOFs) are extended structures composed of a network of organic ligands and metal ions or clusters connected to each other via coordination bonds. The numerous choices of organic ligands and metal coordination geometries have led t ...

Elsevier2017

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