Publications de José Luis Bila

Incorporation of Clathrochelate-Based Metalloligands in Metal-Organic Frameworks by Solvent-Assisted Ligand Exchange

Kay Severin, Rosario Scopelliti, Farzaneh Fadaei Tirani, José Luis Bila, Ophélie Marie Planes, Pascal Alexander Schouwink

Iron(II) cage complexes with terminal 4-pyridyl groups can be incorporated in metal-organic frameworks (MOFs) via solvent-assisted ligand exchange (SALE). Paddle -wheeled MOFs with N,N'-di-4-pyridylnaphthalenete-tracarboxydiimide pillars were used as start ...

2020

Synthesis and characterization of iron-clathrochelates and their applications in materials science

José Luis Bila

This thesis focuses on the design and the synthesis of mono- and dinuclear iron clathrochelate complexes and their applications in materials science. Dinuclear iron clathrochelate complexes can be synthesized in different oxidation states: i. as negative ...

EPFL2020

Porous networks based on iron(ii) clathrochelate complexes

Kay Severin, Rosario Scopelliti, Emilie Baudat, Farzaneh Fadaei Tirani, José Luis Bila, Andrea Luca Ramorini, Joffrey Vincent Michel Pijeat

Microporous networks based on boronate ester-capped iron(II) clathrochelate complexes are described. The networks were obtained by covalent cross-linking of tetrabrominated clathrochelate complexes via Suzuki–Miyaura polycross-coupling reactions with dibor ...

2019

Homo- and Heterodinuclear Iron Clathrochelate Complexes with Functional Groups in the Ligand Periphery

Andrzej Sienkiewicz, Kay Severin, Rosario Scopelliti, Henrik Moodysson Rønnow, Ivica Zivkovic, Mathieu Jérémie Marmier, Konstantin Zhurov, Cornel Fink, José Luis Bila

2018

Orthogonal Bodipy Trimers as Photosensitizers for Photodynamic Action

José Luis Bila

Orthogonally linked BODIPY units shale exceptional intersystem crossing efficiencies. We now report orthogonal BODIPY trimers with strong absorption in the visible region and high singlet oxygen generation capability. The X-ray diffraction structure confir ...

Amer Chemical Soc2016

Neutral Aminyl Radicals Derived from Azoimidazolium Dyes

Andrzej Sienkiewicz, Kay Severin, Rosario Scopelliti, Euro Solari, Philip Pattison, Laurent Alexis Clément Vannay, Henrik Moodysson Rønnow, Léonard Yannick Maurice Eymann, Ivica Zivkovic, Matthew Wodrich, Alexander Tskhovrebov, José Luis Bila

The synthesis and characterization of a new class of neutral aminyl radicals is reported. Monoradicals were obtained by reduction of azoimidazolium dyes with potassium. Structural, spectroscopic, and computational data suggest that the spin density is cent ...

2016

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

Kay Severin, Rosario Scopelliti, Euro Solari, Bálint Náfrádi, Philip Pattison, Henrik Moodysson Rønnow, Ivica Zivkovic, Mathieu Jérémie Marmier, Giacomo Cecot, José Luis Bila

Dinuclear clathrochelate complexes with two, three, four, or five cyano groups in the ligand periphery were prepared following two distinct synthetic strategies: (a) zinc(II)- or cobalt(II)-templated polycondensation reactions of CN-functionalized arylboro ...

2016