Publications de Andrzej Gladysiak

Reply to "Inconsistencies in the specific nucleobase pairing motif prone to photodimerization in a MOF nanoreactor"

Berend Smit, Dominik Józef Kubicki, David Lyndon Emsley, Samantha Lynn Anderson, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Ngoc Tú Nguyên

Nature Portfolio2022

Taking lanthanides out of isolation: tuning the optical properties of metal-organic frameworks

Kevin Sivula, Gloria Capano, Muhammad Aiman Bin Rahmanudin Hamdan, Nestor Guijarro Carratala, Berend Smit, Samantha Lynn Anderson, Kyriakos Stylianou, Davide Tiana, Andrzej Gladysiak, Christopher Patrick Ireland, Stavroula Kampouri, Maria Fumanal Quintana

Metal organic frameworks (MOFs) are increasingly used in applications that rely on the optical and electronic properties of these materials. These applications require a fundamental understanding on how the structure of these materials, and in particular t ...

2020

Sustainable Capture of Aromatic Volatile Organic Compounds by a Pyrene-Based Metal-Organic Framework under Humid Conditions

Sylvain Alexandre Marie Sudan, Kyriakos Stylianou, Andrzej Gladysiak, Bardiya Valizadeh

The threat posed by the presence of artificial volatile organic compounds (VOCs) in the environment is a widely acknowledged fact, both for environmental issues and human health concerns. Ever-increasing production requires the continuous development of te ...

AMER CHEMICAL SOC2020

Design of lanthanide-based metal-organic frameworks with enhanced near-infrared emission

Kyriakos Stylianou, Andrzej Gladysiak, Ngoc Tú Nguyên

A strategy based on the use of ligand steric hindrance and metal doping is reported for the design and synthesis of near-infrared (NIR) emitting lanthanide-based metal-organic frameworks (MOFs). The lanthanide ions are free of coordinated solvents, and the ...

Royal Society of Chemistry2020

Incarceration of Iodine in a Pyrene-Based Metal-Organic Framework

Andreas Züttel, Kyriakos Stylianou, Mariana Spodaryk, Andrzej Gladysiak, Ngoc Tú Nguyên

A pyrene-based metal-organic framework (MOF) SION-8 captured iodine (I-2) vapor with a capacity of 460 and 250 mg g(MOF)(-1) at room temperature and 75 degrees C, respectively. Single-crystal X-ray diffraction analysis and van-der-Waals-corrected density f ...

2019

From structure to application: studies on adenine-, pyrene- and lanthanide-based metal-organic frameworks

Andrzej Gladysiak

Metal-organic frameworks (MOFs) are coordination polymer materials in which inorganic metal ions or clusters are linked with multitopic organic ligands by means of coordination bonds. Their structural versatility allows for design of materials based on pre ...

EPFL2019

Guest-dependent negative thermal expansion in a lanthanide-based metal-organic framework

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Andrzej Gladysiak

A lanthanide-based metal-organic framework (MOF) named SION-2 displays strong and tuneable uniaxial negative thermal expansion (NTE). The coefficient of thermal expansion alpha(1) reaches -153(6) MK-1 between 100 and 340 K, which is the highest value repor ...

2019

Nucleobase pairing and photodimerization in a biologically derived metal-organic framework nanoreactor

Berend Smit, Dominik Józef Kubicki, David Lyndon Emsley, Samantha Lynn Anderson, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Ngoc Tú Nguyên

Biologically derived metal-organic frameworks (bio-MOFs) are of great importance as they can be used as models for bio-mimicking and in catalysis, allowing us to gain insights into how large biological molecules function. Through rational design, here we r ...

Nature Research2019

Data-driven design of metal-organic frameworks for wet flue gas CO2 capture

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Christopher Patrick Ireland, Arunraj Chidambaram, Pascal Alexander Schouwink, Enrique Garcia Diez, Susana Garcia Lopez

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation(1). Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions(2), much effort is focused on developing ...

2019

Selective, Fast-Response, and Regenerable Metal-Organic Framework for Sampling Excess Fluoride Levels in Drinking Water

Paul Joseph Dyson, Fatmah Ebrahim, Kyriakos Stylianou, Andrzej Gladysiak, Serhii Shyshkanov, Ngoc Tú Nguyên, Patrick Favre

Prolonged consumption of water contaminated with fluoride ions (F-) at concentrations exceeding 1.5 ppm can lead to considerable health implications, particularly in children and developing embryos. With irreversible and potentially severe forms of fluorid ...

2019

Discovery of a self-healing catalyst for the hydrolytic dehydrogenation of ammonia borane

Mounir Driss Mensi, Emad Oveisi, Fatmah Ebrahim, Kyriakos Stylianou, Andrzej Gladysiak, Bardiya Valizadeh, Ngoc Tú Nguyên, Fatma Pelin Uran

Sustainable catalysts based on earth-abundant elements are considered as economical alternatives to precious-metal-bearing catalysts and could be impactful for many applications. Self-healing sustainable catalysts, which in addition to their 'green' charac ...

Royal Society of Chemistry2019

Lanthanide-based near-infrared emitting metal-organic frameworks with tunable excitation wavelengths and high quantum yields

Gloria Capano, Fatmah Ebrahim, Berend Smit, Kyriakos Stylianou, Andrzej Gladysiak, Arunraj Chidambaram, Bardiya Valizadeh, Ngoc Tú Nguyên

Royal Society of Chemistry2018

Shedding Light on the Protonation States and Location of Protonated N Atoms of Adenine in Metal-Organic Frameworks

Berend Smit, Samantha Lynn Anderson, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Ngoc Tú Nguyên

2018

Biporous Metal-Organic Framework with Tunable CO2/CH4 Separation Performance Facilitated by Intrinsic Flexibility

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Daniele Ongari, Peter George Boyd, Andrzej Gladysiak, Arunraj Chidambaram, Kathryn Suzanne Deeg, Kaili Yee Ordiz

In this work, we report the synthesis of SION-8, a novel metal-organic framework (MOF) based on Ca(II) and a tetracarboxylate ligand TBAPy(4-) endowed with two chemically distinct types of pores characterized by their hydrophobic and hydrophilic properties ...

2018

Rational Design of a Low-Cost, High-Performance Metal-Organic Framework for Hydrogen Storage and Carbon Capture

Berend Smit, Kyriakos Stylianou, Matthew David Witman, Andrzej Gladysiak

We present the in silico design of a MOF-74 analogue, hereon known as M-2(DHFUMA) [M = Mg, Fe, Co, Ni, Zn], with enhanced small-molecule adsorption properties over the original M-2(DOBDC) series. Constructed from 2,3-dihydroxyfumarate (DHFUMA), an aliphati ...

2017

A Recyclable Metal-Organic Framework as a Dual Detector and Adsorbent for Ammonia

Kyriakos Stylianou, Andrzej Gladysiak, Ngoc Tú Nguyên

Recyclable materials for simultaneous detection and uptake of ammonia (NH3) are of great interest due to the hazardous nature of NH3. The structural versatility and porous nature of metal-organic frameworks (MOFs) make them ideal candidates for NH3 capture ...

Wiley-Blackwell2017

Formation pathways of metal–organic frameworks proceeding through partial dissolution of the metastable phase

Pascal Miéville, Berend Smit, Samantha Lynn Anderson, Kyriakos Stylianou, Davide Tiana, Peter George Boyd, Andrzej Gladysiak, Christopher Patrick Ireland, Pascal Alexander Schouwink

2017