Publications de Anita Justin | EPFL Graph Search

Immobilizing amine species in a Cr-MOF for enhanced selectivity in CO2 cycloaddition reactions

Jocelyn Richard Roth, Wendy Lee Queen, Anita Justin, Till Marian Schertenleib, Jordi Espin Marti

After grafting polyalkylamine species onto the ligand within a Cr 3+ -MOF, the material was tested for catalyzing cycloaddition reactions between CO 2 and 1,2-epoxybutane (EB). ...

Royal Society of Chemistry (RSC)2025

Post-Synthetic Covalent Grafting of Amines to NH2-MOF for Post-Combustion Carbon Capture

Mounir Driss Mensi, Wendy Lee Queen, Ilia Kochetygov, Anita Justin, Andres Adolfo Ortega Guerrero, Till Marian Schertenleib, Miriam Jasmin Pougin, Jordi Espin Marti

Herein, a post-synthetic modification strategy is used to covalently graft polyamines, including ethylenediamine (ED), diethylenetriamine (DETA), tris(2-aminoethyl)amine (TAEA), and polyethyleneimine (PEI) to the amino-ligand inside of a Cr-MOF, NH2-Cr-BDC ...

Wiley-V C H Verlag Gmbh2024

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Jocelyn Richard Roth, Wendy Lee Queen, Ilia Kochetygov, Anita Justin, Till Marian Schertenleib, Jordi Espin Marti, Sophia Alessandra Pache, Nazanin Taheri

The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...

Wiley-VCH Verlag GmbH2023

3D vs. turbostratic: controlling metal-organic framework dimensionality via N-heterocyclic carbene chemistry

Mounir Driss Mensi, Emad Oveisi, Mehrdad Asgari, Wendy Lee Queen, Ilia Kochetygov, Vikram Vinayak Karve, Shuliang Yang, Anita Justin, Till Marian Schertenleib

Using azolium-based ligands for the construction of metal-organic frameworks (MOFs) is a viable strategy to immobilize catalytically active N-heterocyclic carbenes (NHC) or NHC-derived species inside MOF pores. Thus, in the present work, a novel copper MOF ...

ROYAL SOC CHEMISTRY2022

Amine Functionalization in Porous Adsorbents for Carbon Capture and Conversion

Anita Justin

Metal-organic Frameworks (MOFs) are a class of crystalline porous materials with exceptionally high surface area, chemical tunability and stability. Due to alarming CO2 emission and global concern, research is focused on developing porous materials like MO ...

EPFL2022

A Two Step Postsynthetic Modification Strategy: Appending Short Chain Polyamines to Zn-NH2-BDC MOF for Enhanced CO2 Adsorption

Mehrdad Asgari, Wendy Lee Queen, Olga Trukhina, Ilia Kochetygov, Anita Justin, Jordi Espin Marti

Functionalizing metal–organic frameworks (MOFs) with amines is a commonly used strategy to enhance their performance in CO2 capture applications. As such, in this work, a two-step strategy to covalently functionalize NH2-containing MOFs with short chain po ...

2021

Enhancing MOF performance through the introduction of polymer guests

Mehrdad Asgari, Daniel Teav Sun, Wendy Lee Queen, Li Peng, Olga Trukhina, Ilia Kochetygov, Vikram Vinayak Karve, Shuliang Yang, Anita Justin, Jordi Espin Marti

In this contribution, recent advances in the construction of MOF-polymer composites and their corresponding applications are briefly reviewed. The appearance of such architectures is becoming prominent in recent literature, due to the fact that the union o ...

2020

Preparation of Highly Porous Metal-Organic Framework Beads for Metal Extraction from Liquid Streams

Emad Oveisi, Daniel Teav Sun, Wendy Lee Queen, Li Peng, Olga Syzgantseva, Olga Trukhina, Ilia Kochetygov, Shuliang Yang, Anita Justin, Hassan Abedini, Guanchu Lu

Metal-organic frameworks (MOFs) offer great promise in a variety of gas- and liquid-phase separations. However, the excellent performance on the lab scale hardly translates into pilot- or industrial-scale applications due to the microcrystalline nature of ...

AMER CHEMICAL SOC2020