Publications de Aditya Mishra | EPFL Graph Search

Stabilization of highly efficient perovskite solar cells with a tailored supramolecular interface

Michael Graetzel, Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Masaud Hassan S Almalki, Aditya Mishra, Felix Thomas Eickemeyer, Michael Allan Hope, Anurag Krishna, Zhiwen Zhou, Chenxu Zhao

The presence of defects at the interface between the perovskite film and the carrier transport layer poses significant challenges to the performance and stability of perovskite solar cells (PSCs). Addressing this issue, we introduce a dual host-guest (DHG) ...

Nature Research2024

Axial-Equatorial Halide Ordering in Layered Hybrid Perovskites from Isotropic-Anisotropic 207Pb NMR

Manuel Cordova, David Lyndon Emsley, Aditya Mishra, Michael Allan Hope, Ümmügülsüm Günes

Bandgap-tuneable mixed-halide 3D perovskites are of interest for multi-junction solar cells, but suffer from photoinduced spatial halide segregation. Mixed-halide 2D perovskites are more resistant to halide segregation and are promising coatings for 3D per ...

Wiley-VCH Verlag GmbH2024

Light-Induced Metallic and Paramagnetic Defects in Halide Perovskites from Magnetic Resonance

David Lyndon Emsley, Aditya Mishra, Michael Allan Hope

Halide perovskites are promising next-generation solar cell materials, but their commercialization is hampered by their propensity to degrade under operating conditions, particularly under heat, humidity, and light. Identifying degradation products and lin ...

2024

Hydrogen Diffusion in Hybrid Perovskites from Exchange NMR

David Lyndon Emsley, Aditya Mishra

Ion migration is an important phenomenon affecting the performance of hybrid perovskite solar cells. It is particularly challenging, however, to disentangle the contribution of H+ diffusion from that of other ions, and the atomic-scale mechanism remains un ...

AMER CHEMICAL SOC2024

Light-Induced Halide Segregation in 2D and Quasi-2D Mixed-Halide Perovskites

Manuel Cordova, David Lyndon Emsley, Aditya Mishra, Michael Allan Hope

Photoinduced halide segregation hinders widespread application of three-dimensional (3D) mixed-halide perovskites. Much less is known about this phenomenon in lower-dimensional systems. Here, we study photoinduced halide segregation in lower-dimensional mi ...

AMER CHEMICAL SOC2023

Cooperative passivation of perovskite solar cells by alkyldimethylammonium halide amphiphiles

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Thomas Paul Baumeler, David Lyndon Emsley, Essa Awadh R Alharbi, Mathias Dankl, Aditya Mishra, Felix Thomas Eickemeyer, Michael Allan Hope, Anurag Krishna, Olivier Ouellette, Lukas Pfeifer, Nikolaos Lempesis, Georgios Kakavelakis

2023

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

Dominik Józef Kubicki, David Lyndon Emsley, Gabriele Stevanato, Aditya Mishra, Michael Allan Hope

NMR, EPR, XRD datasets and SEM image for the research article titled "Dynamic Nuclear Polarization of Inorganic Halide Perovskites". For further details see the readme.txt file. ...

Zenodo2023

A Complete Picture of Cation Dynamics in Hybrid Perovskite Materials from Solid-State NMR Spectroscopy

Michael Graetzel, David Lyndon Emsley, Aditya Mishra, Michael Allan Hope

The organic cations in hybrid organic-inorganic perovskites rotate rapidly inside the cuboctahedral cavities formed by the inorganic lattice, influencing optoelectronic properties. Here, we provide a complete quantitative picture of cation dynamics for for ...

AMER CHEMICAL SOC2023

Optically Enhanced Solid-State H-1 NMR Spectroscopy

Jean-Philippe Ansermet, Jonas Milani, Dominik Józef Kubicki, David Lyndon Emsley, Aaron James Rossini, Claudia Esther Avalos, Gabriele Stevanato, Aditya Mishra, Michael Allan Hope, Federico De Biasi, Moreno Lelli, Saumya Badoni

Low sensitivity is the primary limitation to extendingnuclearmagnetic resonance (NMR) techniques to more advanced chemical andstructural studies. Photochemically induced dynamic nuclear polarization(photo-CIDNP) is an NMR hyperpolarization technique where ...

AMER CHEMICAL SOC2023

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

Dominik Józef Kubicki, David Lyndon Emsley, Gabriele Stevanato, Aditya Mishra, Michael Allan Hope

The intrinsic low sensitivity of nuclear magnetic resonance (NMR) experiments limits their utility for structure determination of materials. Dynamic nuclear polarization (DNP) under magic angle spinning (MAS) has shown tremendous potential to overcome this ...

2023

Dynamic Nuclear Polarization Enables NMR of Surface Passivating Agents on Hybrid Perovskite Thin Films

Michael Graetzel, Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Masaud Hassan S Almalki, Aditya Mishra, Michael Allan Hope, Lukas Pfeifer

Surface and bulk molecular modulators are the key to improving the efficiency and stability of hybrid perovskite solar cells. However, due to their low concentration, heterogeneous environments, and low sample mass, it remains challenging to characterize t ...

2022

Magnetic Resonance and Hyperpolarization Methods for Perovskite Photovoltaics

Aditya Mishra

Solid-state NMR can provide information about the atomic-level microstructure and dynamics in materials as it directly probes the local nuclear environment. In the last decade, halide perovskites have drawn intense interest because of their intriguing opto ...

EPFL2022

Interplay of Kinetic and Thermodynamic Reaction Control Explains Incorporation of Dimethylammonium Iodide into CsPbI3

Ursula Röthlisberger, Marko Mladenovic, Dominik Józef Kubicki, David Lyndon Emsley, Ariadni Boziki, Mathias Dankl, Aditya Mishra

CsPbI3 is a promising material for optoelectronics owing to its thermal robustness and favorable bandgap. However, its fabrication is challenging because its photoactive phase is thermodynamically unstable at room temperature. Adding dimethylammonium (DMA) ...

AMER CHEMICAL SOC2022

Benzylammonium‐Mediated Formamidinium Lead Iodide Perovskite Phase Stabilization for Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Dominik Józef Kubicki, David Lyndon Emsley, Zaiwei Wang, Anwar Qasem M Alanazi, Jovana Milic, Dan Ren, Masaud Hassan S Almalki, Aditya Mishra, Felix Thomas Eickemeyer, Hong Zhang

There is an ongoing surge of interest in the use of formamidinium (FA) lead iodide perovskites in photovoltaics due to their exceptional optoelectronic properties. However, thermodynamic instability of the desired cubic perovskite (α-FAPbI3) phase at ambie ...

2021

Unravelling the Behavior of Dion-Jacobson Layered Hybrid Perovskites in Humid Environments

Michael Graetzel, David Lyndon Emsley, Jovana Milic, Algirdas Ducinskas, Aditya Mishra, Michael Allan Hope

Layered hybrid halide perovskites are known to be more environmentally stable than their 3D analogues. The enhanced stability is particularly relevant for Dion-Jacobson-type layered perovskites due to their promising photovoltaic performances. However, in ...

2021

Multimodal host–guest complexation for efficient and stable perovskite photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Marko Mladenovic, David Lyndon Emsley, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Zaiwei Wang, Jovana Milic, Dan Ren, Aditya Mishra, Felix Thomas Eickemeyer, Hong Zhang, Zhaowen Dong, Jinming Guo, Michael Allan Hope, Anurag Krishna, Olivier Ouellette, Tzu-Sen Su, Zhiwen Zhou

Formamidinium lead iodide perovskites are promising light-harvesting materials, yet stabilizing them under operating conditions without compromising optimal optoelectronic properties remains challenging. We report a multimodal host–guest complexation strat ...

Nature Research2021

Nanoscale Phase Segregation in Supramolecular π-Templating for Hybrid Perovskite Photovoltaics from NMR Crystallography

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Marko Mladenovic, Dominik Józef Kubicki, Manuel Cordova, David Lyndon Emsley, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Loï Charles Carbone, Yuhang Liu, Brian Irving Carlsen, Jovana Milic, Rashmi Runjhun, Aditya Mishra, Toru Nakamura, Michael Allan Hope, Thomas Schneeberger

The use of layered perovskites is an important strategy to improve the stability of hybrid perovskite materials and their optoelectronic devices. However, tailoring their properties requires accurate structure determination at the atomic scale, which is a ...

2021

Multi-Length Scale Structure of 2D/3D Dion-Jacobson Hybrid Perovskites Based on an Aromatic Diammonium Spacer

Michael Graetzel, Thomas La Grange, Amita Ummadisingu, Dominik Józef Kubicki, David Lyndon Emsley, Jovana Milic, Algirdas Ducinskas, Aditya Mishra

Dion-Jacobson (DJ) iodoplumbates based on 1,4-phenylenedimethanammonium (PDMA) have recently emerged as promising light absorbers for perovskite solar cells. While PDMA is one of the simplest aromatic spacers potentially capable of forming a DJ structure b ...

2021

Naphthalenediimide/Formamidinium-Based Low-Dimensional Perovskites

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Vincent Henri Guillaume Dufoulon, Marko Mladenovic, Dominik Józef Kubicki, David Lyndon Emsley, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Pascal Alexander Schouwink, Jovana Milic, George Cameron Fish, Marco Alejandro Ruiz Preciado, Masaud Hassan S Almalki, Aditya Mishra, Thomas Schneeberger

Low-dimensional hybrid perovskites have emerged as promising materials for optoelectronic applications. Although these materials have already demonstrated enhanced stability as compared to their three-dimensional perovskite analogues, their functionality h ...

2021

Vapor-assisted deposition of highly efficient, stable black-phase FAPbI(3) perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Xiong Li, Wolfgang Richard Tress, David Lyndon Emsley, Paramvir Ahlawat, Claudia Esther Avalos, Zaiwei Wang, Yuhang Liu, Anand Agarwalla, Brian Irving Carlsen, Fan Fu, Aditya Mishra, Haizhou Lu, Felix Thomas Eickemeyer, Xianfu Zhang, Likai Zheng, Ying Yang

Mixtures of cations or halides with FAPbI(3) (where FA is formamidinium) lead to high efficiency in perovskite solar cells (PSCs) but also to blue-shifted absorption and long-term stability issues caused by loss of volatile methylammonium (MA) and phase se ...

American Association for the Advancement of Science2020