Publications associées à Apparatus for salt separation under supercritical water conditions

Continuous Supercritical Water Impregnation Method for the Preparation of Metal Oxide on Activated Carbon Composite Materials

Metal oxide (MexOy) nanomaterials are used as catalysts and/or sorbents in processes taking place in supercritical water (scH2O), which is the “green” solvent needed to obtain energy-relevant products. Their properties are significantly influenced by the s ...

2024

Investigation of Biomass Hydrothermal Conversion Products by HRMS

Daniil Salionov

The dependency on fossil fuels and their impact on the environment is a matter of great concern for the future sustainability of modern society. The development of the "green" technologies which utilize renewable energy sources is now under investigation. ...

EPFL2023

Spin Evolution in the Born-Oppenheimer Approximation

Jean-Philippe Ansermet, Klaus Maschke, François Reuse

The first part of this article attempts to highlight in chronological order some prominent papers that have direct connexion with the Born-Oppenheimer approximation. This timeline successively points to the role of level crossing, the notions of gauge fiel ...

WILEY-V C H VERLAG GMBH2022

The capture technology matters: Composition of municipal wastewater solids drives complexity of microbial community structure and volatile fatty acid profile during anaerobic fermentation

Pierre Rossi, Arnaud Michel Gelb

The production of volatile fatty acids (VFAs) represents a relevant option to valorize municipal wastewater (MWW). In this context, different capture technologies can be used to recover organic carbon from wastewater in form of solids, while pre-treatment ...

2022

Quantum vibronic effects on the electronic properties of solid and molecular carbon

François Gygi, Michele Ceriotti, Han Yang

We study the effect of quantum vibronic coupling on the electronic properties of carbon allotropes, including molecules and solids, by combining path integral first principles molecular dynamics (FPMD) with a colored noise thermostat. In addition to avoidi ...

AMER PHYSICAL SOC2021

Two-dimensional modelling of transient capillary driven damped micro-oscillations and self-alignment of objects in microassembly

François Gallaire

In the fields of microgripping and microassembly, the self-alignment motion of a solid micro-object linked by a liquid meniscus to a substrate or a tool is an inexpensive way to overcome the current limitations of the assembly processes at microscale by ge ...

Cambridge University Press2021

Aggregate dissolution in different pore solutions

Mahsa Bagheri

The occurrence of cracking due to alkali silica reaction (ASR) affects the service life of concrete structures. The dissolution of silica-containing minerals within aggregates causes the formation of ASR products, which fill macroscopic cracks and cause th ...

EPFL2021

Quantum yield and brightness

Jean-Claude Bünzli

Brightness has different meaning in different contexts and some of these are reviewed. The scientific definition of brightness does not represent our perception. The current definition is that from the IUPAC Gold Book and is mainly restricted to solutions. ...

2020

Solidity without inhomogeneity: perfectly homogeneous, weakly coupled, UV-complete solids

Angelo Esposito

Solid-like behavior at low energies and long distances is usually associated with the spontaneous breaking of spatial translations at microscopic scales, as in the case of a lattice of atoms. We exhibit three quantum field theories that are renormalizable, ...

Springer Nature2020

Homonuclear Decoupling in H-1 NMR of Solids by Remote Correlation

David Lyndon Emsley, Federico Maria Paruzzo, Gabriele Stevanato, Pinelopi Moutzouri, Bruno Simões de Almeida

The typical linewidths of H-1 NMR spectra of powdered organic solids at 111 kHz magic-angle spinning (MAS) are of the order of a few hundred Hz. While this is remarkable in comparison to the tens of kHz observed in spectra of static samples, it is still th ...

Wiley-VCH Verlag GmbH2020

Aqueous effluent treatment system

Jeremy Luterbacher, Frédéric Edouard Juillard, Gaël Peng, Lionel Bertschy

Aqueous effluent treatment system (2) including a separation reactor (4) having a reactor chamber fluidly connected to an aqueous effluent source (3), connected via a pump (5) to an inlet (34) of the reactor chamber, a fluid extraction system (6) connected ...

2020

Visualization of supercritical water pseudo-boiling at Widom line crossover

Andrea Testino, Christian Ludwig

Supercritical water is a green solvent used in many technological applications including materials synthesis, nuclear engineering, bioenergy, or waste treatment and it occurs in nature. Despite its relevance in natural systems and technical applications, t ...

Nature Research2019

Supercritical water anomalies in the vicinity of the Widom line

Christian Ludwig

Supercritical water is used in a variety of chemical and industrial applications. As a consequence, a detailed knowledge of the structure-properties correlations is of uttermost importance. Although supercritical water was considered as a homogeneous fluid ...

Nature Research2019

Fast and ultrafast electron microscopies for skyrmions and plasmonics

Gabriele Berruto

In recent years, topology gained a central role in physics. We learnt that energetics could be often explained better by classes of objects defined by having qualitative differences. In today's jargon, we say they are topologically distinct. The process of ...

EPFL2019

Multiple Inflow Branches at Supercritical-Type Vortex Drop Shaft

Jean-Marc Ribi, Thierry Fuchsmann, Michael Pfister, Corrado Gisonni, Gaetano Crispino

Vortex drop shafts serve to overcome important elevation differences in drainage systems. If well designed, they are performant in terms of energy dissipation and safety. However, the standard design requires well-defined approach flow conditions to ensure ...

ASCE-AMER SOC CIVIL ENGINEERS2018

Full Phase Diagram of Active Brownian Disks: From Melting to Motility-Induced Phase Separation

Ignacio Pagonabarraga Mora, Pasquale Digregorio

We establish the complete phase diagram of self-propelled hard disks in two spatial dimensions from the analysis of the equation of state and the statistics of local order parameters. The equilibrium melting scenario is maintained at small activities, with ...

2018

Multi-objective Optimization of Supercritical Water Gasification of Leftover Brazilian Ginseng Roots After Phytochemical Recovery Steps

François Maréchal, Alberto Mian, Adriano Viana Ensinas, Diego Tresinari dos Santos, Juliana Queiroz Albarelli

The present study aims at studying the supercritical water gasification (SCWG) of the leftover Brazilian ginseng roots after phytochemicals extraction for synthetic natural gas (SNG) production, envisioning the development of a promising Brazilian ginseng ...

2017

The impact of sorbent geometry on the sulphur adsorption under supercritical water conditions: a numerical study

Andrea Testino, Christian Ludwig

A numerical model to show the impact of the adsorption bed geometry on the desulfurization process of wet biomass under supercritical water (SCW) gasification process has been developed. Three different geometries, straight channels (pipe), sharp-edged cha ...

Springer Heidelberg2017

Thermo-economic and environmental comparison of supercritical water and enzymatic hydrolysis of sugarcane bagasse in a biorefinery concept

François Maréchal, Adriano Viana Ensinas

In this study, we discuss the difference regarding thermo-economic and environmental (water intake) aspects between two methods of biomass hydrolysis. A thermo-economic model was developed using Aspen Plus® and MATLAB software in order to analyze the energ ...

2017

Photocatalytic and Electrocatalytic Reduction of Carbon Dioxide in Pressurized Systems

Patrick Voyame

The depletion of carbon-based fossil fuels and the rise in atmospheric carbon dioxide concentration will force an inevitable change in the future global energy landscape. CO2 reduction presents the advantages of decreasing its atmospheric concentration and ...

EPFL2016