Publications associées à Thermoplastic Toughening of a Semiaromatic Polyamide with an Amino-telechelic Polyethylene

Reinforced Supramolecular Networks of End Functionalized Polymers for Tailored Thermomechanical Property Profiles

Thermoset rubbers give rise to elastomers with tunable stiffness and high resilience but are not recyclable. Thermoplastic elastomers can address this problem but their broad applicability is impeded by either limited operating temperatures or inferior ela ...

EPFL2023

Influence of the molecular weight and physical properties of a thermoplastic polymer on its dynamic wetting behavior

Valentin Rougier

The wetting dynamics of molten thermoplastic polymers, which are known to influence the force balance of the triple line, are not understood properly despite their importance in many industrial processes. In particular, the influence of the molecular weigh ...

Elsevier2023

Supramolecular Modifications of Semicrystalline Polymers

Michael Alan Giffin

Supramolecular interactions play an important role in defining the structure and the resulting mechanical properties of materials. For instance, interchain hydrogen-bonding in PAs gives them superior strength and stiffness in engineering materials, while t ...

EPFL2023

Biocompatible and Biodegradable 3D Printing from Bioplastics: A Review

Sandro Carrara

There has been a lot of interest in developing and producing biodegradable polymers to address the current environmental problem caused by the continued usage of synthetic polymers derived from petroleum products. Bioplastics have been identified as a poss ...

MDPI2023

Incorporation of Lignin in Bio-Based Resins for Potential Application in Fiber-Polymer Composites

Mário Alexandre De Jesus Garrido, Mateus De Assunção Hofmann

Bio-based resins, obtained from renewable raw materials, are a more sustainable alternative to oil-based resins for fiber-reinforced polymer (FRP) composites. The incorporation of lignin in those resins has the potential to enhance their performance. This ...

MDPI2023

Inferring the flow properties of epithelial tissues from their geometry

Marko Popovic, Valentin Camille Druelle, Matthieu Wyart

Amorphous materials exhibit complex material properties with strongly nonlinear behaviors. Below a yield stress they behave as plastic solids, while they start to yield above a critical stress sigma(c). A key quantity controlling plasticity which is, howev ...

2021

Static and dynamic mechanical properties of nanosilica and multiwalled carbon nanotube reinforced acrylonitrile butadiene styrene composites: theoretical mechanism of nanofiller reinforcement

Thomas Keller, Harish Mohan Thettemmel

Experimental and theoretical approaches were employed to analyze the static and dynamic mechanical properties of acrylonitrile butadiene styrene (ABS) nanocomposites reinforced with multiwalled carbon nanotube (MWCNT) and nanosilica. Enhanced stiffness and ...

SPRINGER2021

Evaluation of the Effect of Backsheet Properties on PV Encapsulant Degradation under Ultraviolet-Damp-Heat Conditions

Djamel Eddine Mansour

The reliability of photovoltaic (PV) modules is highly determined by the durability of the polymeric components (backsheet and encapsulant). The power degradation and failure of PV modules can be caused by changes in the physical, chemical, and mechanical ...

EPFL2021

Microstructural controls of anticrack nucleation in highly porous brittle solids

Henning Löwe, Johan Alexandre Philippe Gaume, Jonas Ritter

Porous brittle solids have the ability to collapse and fail even under compressive stresses. In fracture mechanics, this singular behavior, often referred to as anticrack, demands for appropriate continuum models to predict the catastrophic failure. To ide ...

Nature Research2020

Bridging scales in wear modeling with volume integral methods for elastic-plastic contact

Lucas Henri Galilée Frérot

All mechanical systems, naturally occurring or human-produced, are subjected to friction and wear at the interface of solid constituents. Large portions of energy dissipation and loss of material, in every-day life and industrial applications alike, are du ...

EPFL2020

Electrochemically polymerized poly (3, 4-phenylenedioxythiophene) as efficient and transparent counter electrode for dye sensitized solar cells

Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Lin Yang, Jiahuan Zhang, Yan Hao

A new conducting polymer poly (3, 4-phenylenedioxythiophene) is synthesized by the electrochemical polymerization technique with different solvents. We find that solvents used in electrochemical polymerization play important roles for the catalytic activit ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Investigations and numerical modeling of mechanical properties of tempered martensitic steel Eurofer97 at various loading rates, temperatures and after spallation irradiation

Serafin Knitel

The reduced activation tempered martensitic steel Eurofer97 is a reference steel for a structural applica-tions in fusion reactors. The first-wall and blanket materials will be subjected to high thermal and neutron fluxes and will experience very complex, ...

EPFL2018

Functional composites with damage control and repair

Amaël Maximilien Cohades

Fibre Reinforced Polymer (FRP) composite structures are subjected during service to low energy impacts or unexpected loads, leading to damage. Microcracks are generally first formed in the matrix and can reach up to several hundred microns in thickness. In ...

EPFL2018

High-temperature copolyamides obtained by the efficient transamidation of crystalline-crystalline polyamide blends

John Christopher Plummer, Véronique Michaud, Holger Frauenrath, Sylvain Cyril Claude Galland

High-performance thermoplastic composites based on semiaromatic polyamides are prime candidates for metal replacement in lightweight structural applications. However, the low ductility and toughness of semiaromatic polyamides remain major obstacles to thei ...

Wiley-Blackwell2017

Efficiency Factors for Plastic Design in Concrete: Influence of Brittleness in Compression, High Tech Concrete: Where Technology and Engineering Meet

Aurelio Muttoni, Miguel Fernández Ruiz, Francesco Rafael Alberto Moccia

A large number of design approaches for structural concrete rely on the applicability of limit analysis. This is for instance the case of bending and shear design in members with transverse reinforcement, where it is assumed that plastic compression fields ...

2017

Effect of charging/discharging on plasticity and fracture in Si anodes for batteries

Seyed Mostafa Khosrownejad

Lithium-ion batteries provide the power for portable electronics and found many other interesting applications. It is desirable to design batteries with high energy density and long cycle life. Silicon is among the highest Li-storing anode materials in bat ...

EPFL2017

Studies on large scale bridging in delamination of unidirectional and cross-ply laminates

Ebrahim Farmand Ashtiani

Delamination propagation in fibrous laminates is often accompanied by development of a damage zone, within which intact fibers bridge the crack faces that constitutes a major toughening mechanism. A direct experimental assessment of the crack closure tract ...

EPFL2016

Tailoring self-assembly and optoelectronic properties of organic semiconductors via macromolecular engineering

Andrea Gasperini

Conjugated polymers and small molecules are a promising class of semiconducting materials for application in macroelectronic and energy conversion devices. The development of high performance devices employing this class of semicrystalline materials ultima ...

EPFL2016

Avoiding compositional drift during the RAFT copolymerization of N-(2-hydroxypropyl)methacrylamide and N-acryloxysuccinimide: towards uniform platforms for post-polymerization modification

Harm-Anton Klok, Hedi Ketari, Ioana-Maria Simionca, John Moraes

Controlled radical polymerization techniques such as RAFT allow fine control over polymer molecular weight and architecture. These techniques, however, do not eliminate compositional drifts in copolymerizations, which are the consequence of differences in ...

Royal Society of Chemistry2015

Delamination in cross-ply laminates: Identification of traction-separation relations and cohesive zone modeling

Joël Cugnoni, John Botsis, Ebrahim Farmand Ashtiani, David Enrique Alanis Rojas

Identification of traction separation relations is at the forefront of damage and fracture mechanics of composite laminates. Such relations are of particular interest in fracture of laminates consisting of layers of different fiber orientations. In this st ...

Elsevier2015