Publications associées à Methods for determination of degree of reaction of slag in blended cement pastes

Characterisation and hydration kinetics of beta-C2S synthesised with K2SO4 as dopant

Karen Scrivener, Shashank Bishnoi, Franco Alberto Zunino Sommariva, Sreejith Krishnan

In this study, a protocol for synthesising beta-C2S using K2SO4 as a dopant has been reported. Quantitative X-Ray diffraction was used to characterise synthesised samples. It was observed that it is possible to synthesise beta-C2S with high purity (>96 wt% ...

Pergamon-Elsevier Science Ltd2023

Melting pseudosymmetry and thermal expansion in 3-benzoylpropionic acid

Tomasz Poreba

The thermal behavior of 3-benzoylpropionic acid (BPA) was investigated using single-crystal and synchrotron powder X-diffraction, as well as differential scanning calorimetry analysis. The study revealed the existence of two subtly distinct structures of B ...

ROYAL SOC CHEMISTRY2023

Tailor-made Piezoelectric Elastomer Materials

Francis Owusu

Recent advancements in miniature devices with higher computational capabilities and ultralow power consumption have accelerated the development of wearable sensors, actuators, and energy harvesters everywhere. The ultimate aim of such a technological revol ...

EPFL2023

A long-term study on structural changes in calcium aluminate silicate hydrates

Christian Ludwig, Barbara Lothenbach, Sonya Barzgar, Yu Yan, Mohamed Tarik

Production of blended cements in which Portland cement is combined with supplementary cementitious materials (SCM) is an effective strategy for reducing the CO2 emissions during cement manufacturing and achieving sustainable concrete production. However, t ...

SPRINGER2022

Second harmonic scattering of water in a biological context

Tereza Schönfeldová

Water is one of the most abundant molecules in the universe. It forms a hydrogen bond network with unique structure and dynamics. Hydrogen bonding is highly relevant to many biological processes including membrane formation, protein folding, adsorption, an ...

EPFL2022

Coupled segregation mechanisms of Sc, Zr and Mn at theta ' interfaces enhances the strength and thermal stability of Al-Cu alloys

Baptiste Thomas Jean Rouxel, Lu Jiang

The refinement and thermal stability of intermediate theta-prime (theta') precipitates are critical in the development of new high strength 2xxx series aluminium-copper (Al-Cu) alloys for high temperature applications. In this work, we use trace additions ...

PERGAMON-ELSEVIER SCIENCE LTD2021

Promoting Persistent Superionic Conductivity in Sodium Monocarba-closo-dodecaborate NaCB11H12 via Confinement within Nanoporous Silica

Mirjana Dimitrievska

Superionic phases of bulk anhydrous salts based on large cluster-like polyhedral (carba)borate anions are generally stable only well above room temperature, rendering them unsuitable as solid-state electrolytes in energy-storage devices that typically oper ...

AMER CHEMICAL SOC2021

Characterization of untransformed ferrite in 10Cr and 12Cr ODS steels

Roland Logé

Two new ferrito-martensitic oxide dispersion strengthened (ODS) steels reinforced with (Y, Ti, O) nanoparticles were elaborated using a high-energy attritor. The milled powder was consolidated by hot extrusion at 1050 degrees C. The two types of ODS steels ...

ELSEVIER SCI LTD2021

Evaluation of the Effect of Backsheet Properties on PV Encapsulant Degradation under Ultraviolet-Damp-Heat Conditions

Djamel Eddine Mansour

The reliability of photovoltaic (PV) modules is highly determined by the durability of the polymeric components (backsheet and encapsulant). The power degradation and failure of PV modules can be caused by changes in the physical, chemical, and mechanical ...

EPFL2021

Effects of Ball Milling and TiF3 Addition on the Dehydrogenation Temperature of Ca(BH4)2 Polymorphs

Andreas Züttel

The changes introduced by both ball milling and the addition of small amounts of TiF3 in the kinetics of the hydrogen desorption of three different Ca(BH4)2 polymorphs (α, β and γ) have been systematically investigated. The samples with different polymorph ...

2020

Structural and Dynamical Properties of Potassium Dodecahydro-monocarba-closo-dodecaborate: KCB11H12

Wei Zhou, Mirjana Dimitrievska

MCB11H12 (M: Li, Na) dodecahydro-monocarba-closo-dodecaborate salt compounds are known to have stellar superionic Li+ and Na+ conductivities in their high-temperature disordered phases, making them potentially appealing electrolytes in all-solid-state batt ...

AMER CHEMICAL SOC2020

Characterization of interfacial transition zone in concrete prepared with carbonated modeled recycled concrete aggregates

Karen Scrivener

Treatment by accelerated carbonation has been widely studied to enhance the quality of recycled concrete aggregates (RCA) and hence the performance of new concrete produced with the RCA. This is often ascribed to the densification of RCA. This study invest ...

Pergamon-Elsevier Science Ltd2020

Effect of a novel starch-based temperature rise inhibitor on cement hydration and microstructure development

Karen Scrivener, Cheng Yu, Alexandre Reda Constantin William Caleb Ouzia, Yu Yan

This study investigates the mechanism by which a novel starch-based admixture named Temperature Rise Inhibitor (TRI) modifying cement hydration and limiting heat evolution. This admixture is designed to avoid thermal cracking of concrete. Depending on the ...

Pergamon-Elsevier Science Ltd2020

Hydration development and thermal performance of calcium sulphoaluminate cements containing microencapsulated phase change materials

Diana Londoño Zuluaga

Microencapsulated phase change materials (MPCM) incorporated in buildings walls can reduce indoor temperature fluctuations, conserving energy and enhancing thermal comfort. MPCM were incorporated in calcium sulphoaluminate cement (CSA) at high concentratio ...

Pergamon-Elsevier Science Ltd2020

A Contribution to the Design of Textile Reinforced Concrete Structures

Patrick Lorenzo Valeri

The reduction of green-house gas emissions is one of the global challenges that our society is facing and the production of cement plays a major role because concrete is the most used material worldwide. For every 1000 kg of cement produced, 900 kg of CO2, ...

EPFL2020

Reusability of filtering facepiece respirators after decontamination through drying and germicidal UV irradiation

David Vernez, Véronique Michaud, Guillaume Suarez, Kiattisak Batsungnoen

Introduction During pandemics, such as the SARS-CoV-2, filtering facepiece respirators plays an essential role in protecting healthcare personnel. The recycling of respirators is possible in case of critical shortage, but it raises the question of the effe ...

2020

Effect of temperature on the water content of C-A-S-H in plain Portland and blended cements

Karen Scrivener, François Henri Avet

This study aims to investigate the change with temperature of the water content of the C-(A)-S-H of plain cement (PC) and Limestone Calcined Clay Cement (LC3). The water content was determined by various methods: thermogravimetric analysis (TGA), H-1-nucle ...

Pergamon-Elsevier Science Ltd2020

Beam duct for the 1 MW neutral beam injector on TCV

Basil Duval, Yves Martin, Stefano Coda, Alexander Karpushov, Frédéric Dolizy, Matthieu Toussaint, Roberto Maurizio

The 1MW power of the neutral beam injector (NBI) enters the plasma of the Tokamak a Configuration Variable (TCV) through a duct. The original beam propagation model predicted a maximal heat flux on the internal faces of the duct below 350 kW/m(2), leading ...

2020

The effect of sodium hydroxide on Al uptake by calcium silicate hydrates (C S H)

Christian Ludwig, Barbara Lothenbach, Sonya Barzgar, Alessio Di Giacomo, Mohamed Tarik

To reduce the CO2 emissions from cement production, Portland cement (PC) is partially replaced by supplementary cementitious materials (SCM). Reactions of SCM with PC during hydration leads to the formation of CSH with more silicon and aluminum than in PC, ...

2020

Rapid, Robust, and Relevant (R3) Reactivity Test for Supplementary Cementitious Materials

Karen Scrivener, François Henri Avet, Ruben Anton Snellings, Xuerun Li

Although supplementary cementitious materials (SCMs) are now commonly accepted and widely used, consensus has not been reached for methods to test their chemical reactivity. A multitude of test methods exist but often fall short on one or more of the key f ...

AMER CONCRETE INST2019