Publications associées à Plaquette order in the SU(6) Heisenberg model on the honeycomb lattice

Catalytic Enantioselective Synthesis of Inherently Chiral Macrocycles by Dynamic Kinetic Resolution

Kinetically fast racemization of chiral substrates through an achiral intermediate and enantioselective functionalization of one of the enantiomeric substrates forms the basis of the dynamic kinetic resolution (DKR) of centrally chiral molecules. We report ...

2024

Frustrated magnets in the limit of infinite dimensions: Dynamics and disorder-free glass transition

Achille Mauri

We study the statistical mechanics and the equilibrium dynamics of a system of classical Heisenberg spins with frustrated interactions on a d -dimensional simple hypercubic lattice, in the limit of infinite dimensionality d -> infinity . In the analysis we ...

Amer Physical Soc2024

Twisted chiral superconductivity in photodoped frustrated Mott insulators

Philipp Georg Werner Seeberger, Markus Müller, Jiajun Li

Recent advances in ultrafast pump-probe spectroscopy provide access to hidden phases of correlated matter, including light-induced superconducting states. The theoretical understanding of these nonequilibrium phases remains limited, particularly for correl ...

AMER PHYSICAL SOC2023

Chiral magnetohydrodynamics with zero total chirality

Kohei Kamada, Jennifer Waltraud Schober

We study the evolution of magnetic fields coupled with chiral fermion asymmetry in the framework of chiral magnetohydrodynamics with zero initial total chirality. The initial magnetic field has a turbulent spectrum peaking at a certain characteristic scale ...

American Physical Society2023

Thermal Conditions in Indoor Environments: Exploring the Reasoning behind Standard-Based Recommendations

Dolaana Khovalyg

Professionals in the building design and operation fields typically look at standards and guidelines as a reliable source of information and guidance with regard to procedural, contractual, and legal scope and requirements that are relevant to accountabili ...

2023

Chemodivergent Asymmetric Synthesis via Catalytically Formed Chiral Auxiliary

Mikus Purins

In summary, the development of the catalytically formed chiral auxiliary concept is described. In this approach, an oxazolidine auxiliary is installed via enantioselective Pd catalysis from readily available starting materials in an enantioselective tether ...

EPFL2023

Level crossings and chiral transitions in transverse-field Ising models of adatom and Rydberg chains

Ivo Aguiar Maceira

This thesis is motivated by recent experiments on systems described by extensions of the one-dimensional transverse-field Ising (TFI) model where (1) finite-size properties of Ising-ordered phases -- specifically, ground state level crossings -- were obser ...

EPFL2022

Spinon-like excitations in spin-1/2 quantum antiferromagnets

Irina Safiulina

Quantum magnetism remains a hot topic in condensed matter physics due to its complexity and possible powerful and significant applications in data storage and memory. To understand how the materials can achieve these goals, one should have a clear idea abo ...

EPFL2022

Tensor network investigation of frustrated Ising models

Jeanne Colbois

In spin systems, geometrical frustration describes the impossibility of minimizing simultaneously all the interactions in a Hamiltonian, often giving rise to macroscopic ground-state degeneracies and emergent low-temperature physics. In this thesis, combin ...

EPFL2022

Conformal and chiral phase transitions in Rydberg chains

Frédéric Mila, Natalia Chepiga, Ivo Aguiar Maceira

Using density matrix renormalization group simulations on open chains, we map out the wave vector in the incommensurate disordered phase of a realistic model of Rydberg chains with 1/r6 interactions, and we locate and characterize the points along the comm ...

AMER PHYSICAL SOC2022

Broken-Symmetry Ground States of the Heisenberg Model on the Pyrochlore Lattice

Giuseppe Carleo, Ao Chen

The spin-1/2 Heisenberg model on the pyrochlore lattice is an iconic frustrated three-dimensional spin system with a rich phase diagram. Besides hosting several ordered phases, the model is debated to possess a spin-liquid ground state when only nearest-ne ...

American Physical Society2021

Evidence of a coupled electron-phonon liquid in NbGe2

Mathieu François Padlewski, Philip Johannes Walter Moll, Matthias Carsten Putzke, Hao Yang

Whereas electron-phonon scattering relaxes the electron's momentum in metals, a perpetual exchange of momentum between phonons and electrons may conserve total momentum and lead to a coupled electron-phonon liquid. Such a phase of matter could be a platfor ...

Nature Portfolio2021

Artificial out-of-plane Ising antiferromagnet on the kagome lattice with very small farther-neighbor couplings

Frédéric Mila, Jeanne Colbois, Xueqiao Wang

Despite their simple formulation, short-range classical antiferromagnetic Ising models on frustrated lattices give rise to exotic phases of matter, in particular, due to their macroscopic ground-state degeneracy. Recent experiments on artificial spin syste ...

2021

Visible-Light-Driven Catalytic Deracemization of Secondary Alcohols

Xile Hu, Zhikun Zhang

Deracemization of racemic chiral compounds is an attractive approach in asymmetric synthesis, but its development has been hindered by energetic and kinetic challenges. Here we describe a catalytic deracemization method for secondary benzylic alcohols whic ...

Wiley-VCH Verlag GmbH2021

Interventions for Softening Can Lead to Hardening of Opinions: Evidence from a Randomized Controlled Trial

Robert West, Ahmad Abu-Akel, Andreas Oliver Spitz

Motivated by the goal of designing interventions for softening polarized opinions on the Web, and building on results from psychology, we hypothesized that people would be moved more easily towards opposing opinions when the latter were voiced by a celebri ...

ASSOC COMPUTING MACHINERY2021

Ultrafast homomorphic encryption models enable secure outsourcing of genotype imputation

Jean-Pierre Hubaux, Jean-Philippe Léonard Bossuat, David Jules Froelicher, Juan Ramón Troncoso-Pastoriza, Yiping Ma

Genotype imputation is a fundamental step in genomic data analysis, where missing variant genotypes are predicted using the existing genotypes of nearby "tag"variants. Although researchers can outsource genotype imputation, privacy concerns may prohibit ge ...

CELL PRESS2021

Static and dynamic properties of non-collinear quantum antiferromagnets explored by neutron scattering

Luc Testa

This thesis is devoted to the investigation of static and dynamic properties of two different sets of quantum magnets with neutron scattering techniques and the help of linear spin wave theory. Both systems are copper-based with spin-1/2, which makes them ...

EPFL2021

Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces

Harald Brune, Roland Widmer, Roland Hany, Michael Bauer, Samuel Thomas Stolz

Achieving fundamental understanding of enantioselective heterogeneous synthesis is marred by the permanent presence of multitudinous arrangements of catalytically active sites in real catalysts. In this study, we address this issue by using structurally co ...

NATURE RESEARCH2021

Arrested phase separation in chiral fluids of colloidal spinners

Ignacio Pagonabarraga Mora

We investigate phase separation in a chiral fluid, made of spinning ferromagnetic colloids that interact both via hydrodynamic and dipolar forces and collectively organize into separated circulating clusters. We show that, at high spinning frequency, hydro ...

AMER PHYSICAL SOC2021

Is there a difference in how people from different socio-environmental contexts perceive discomfort due to glare from daylight?

Magali Bodart, Jan Wienold, Clotilde Marie A Pierson

Exposure to daylight has much to offer and should be optimised to maximise its potential. In order to harvest its benefits, any visual discomfort from daylight should be anticipated and minimised. Hence, there is the need to predict discomfort from dayligh ...

2022