Publications associées à Quadrupolar susceptibility modeling of substrated metasurfaces with application to the generalized Brewster effect

Biomimetic Photodegradation of Glyphosate in Carborane-Functionalized Nanoconfined Spaces

The removal of organophosphorus (OP) herbicides fromwater hasbeen studied using adsorptive removal, chemical oxidation, electrooxidation,enzymatic degradation, and photodegradation. The OP herbicide glyphosate(GP) is one of the most used herbicides worldwi ...

AMER CHEMICAL SOC2023

Self-Assembly of N-Rich Triimidazoles on Ag(111): Mixing the Pleasures and Pains of Epitaxy and Strain

Ulrich Aschauer, Christian Wäckerlin, Xing Wang, Mehdi Heydari

In the present report, homochiral hydrogen-bonded assemblies of heavily N-doped (C9H6N6) heterocyclic triimidazole (TT) molecules on an Ag(111) substrate were investigated using scanning tunneling microscopy (STM) and low energy electron diffraction (LEED) ...

Amer Chemical Soc2023

Dielectric metasurfaces and their applications for optical biosensing

Yasaman Jahani

Over the past century, our understanding of life has been focused on its most fundamental building blocks: molecules. Biological molecules, such as proteins found in blood, other body fluids, or tissues, are excellent guides to identifying a normal or abno ...

EPFL2023

Dipole polarizability of time-varying particles

Romain Christophe Rémy Fleury, Theodoros Koutserimpas, Mohammad Sajjad Mirmoosa

Invariance under time translation (or stationarity) is probably one of the most important assumptions made when investigating electromagnetic phenomena. Breaking this assumption is expected to open up novel possibilities and result in exceeding conventiona ...

2022

Metasurface Near-Field Measurements with Incident Field Reconstruction Using a Single Horn Antenna

Shourya Dutta Gupta, Ville Tuovi Tiukuvaara

Metasurfaces (MSs) are the 2-D equivalent of metaterials, the latter being a class of artificial engineered materials exhibiting peculiar electromagnetic properties [1], [2]. Generally constructed as arrays of deeply sub-wavelength resonant particles on a ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Structures of the (Imidazole)(n)H+ ... Ar (n=1,2,3) complexes determined from IR spectroscopy and quantum chemical calculations

Valeriu Scutelnic

Here, we present new cryogenic infrared spectra of the (Imidazole) H-n(+) (n=1,2,3) ions. The data was obtained using helium tagging infrared predissociation spectroscopy. The new results were compared with the data obtained by Gerardi et al. (Chem. Phys. ...

SPRINGER/PLENUM PUBLISHERS2023

Multipolar Modeling of Spatially Dispersive Metasurfaces

Olivier Martin, Karim Achouri, Ville Tuovi Tiukuvaara

There is today a growing need to accurately model the angular scattering response of metasurfaces for optical analog processing applications. However, the current metasurface modeling techniques are not well suited for such a task since they are limited to ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Robustness Analysis of Metasurfaces: Perfect Structures Are Not Always the Best

Olivier Martin, Karim Achouri, Hsiang-Chu Wang

Optical metasurfaces rely on subwavelength scale nanostructures, which puts significant constraints on nanofabrication accuracies. These constraints are becoming increasingly important, as metasurfaces are maturing toward real applications that require the ...

AMER CHEMICAL SOC2022

Effects of surface rigidity and metallicity on dielectric properties and ion interactions at aqueous hydrophobic interfaces

Philip Robin Loche

Using classical molecular dynamics simulations, we investigate the dielectric properties at interfaces of water with graphene, graphite, hexane, and water vapor. For graphite, we compare metallic and nonmetallic versions. At the vapor-liquid water and hexa ...

AIP Publishing2022

Metasurfaces for label-free biosensing mid-infrared optics and active photonic devices

Aleksandrs Leitis

Novel two-dimensional metamaterials, known as metasurfaces, have emerged as a breakthrough platform for controlling electromagnetic wave properties at the nanoscale. These metasurfaces consist of subwavelength nanoantennas or so-called meta-atoms, which ca ...

EPFL2021

Wafer‐Scale Functional Metasurfaces for Mid‐Infrared Photonics and Biosensing

Hatice Altug, Aurélian Michel John-Herpin, Aleksandrs Leitis, Ming-Lun Tseng

Metasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale and enabling on-demand optical functionalities for next-generation biosensing, imaging, and light-generating photonic devices. However, translating this technology ...

Wiley2021

Structural and analytical identifications of biomolecules by cold ion spectroscopy of non-covalent complexes

Erik Saparbayev

Non-covalent interactions are ubiquitous in nature. The diversity and functionality of these interactions are employed by nature as a universal tool for building the molecular mechanism of life. Although weak, these interactions play a key role in both for ...

EPFL2021

DORI Reveals the Influence of Noncovalent Interactions on Covalent Bonding Patterns in Molecular Crystals Under Pressure

Laurent Alexis Clément Vannay, Anne-Clémence Corminboeuf, Berend Smit, Senja Dominique Barthel, Amber Kashan Mace, Benjamin André René Meyer

The study of organic molecular crystals under high pressure provides fundamental insight into crystal packing distortions and reveals mechanisms of phase transitions and the crystallization of polymorphs. These solid-state transformations can be monitored ...

2019

Interplay of H-Bonds with Aromatics in Isolated Complexes Identifies Isomeric Carbohydrates

Oleg Boyarkine, Vladimir Kopysov, Aleksandr Pereverzev, Ruslan Yamaletdinov

The tremendous isomeric diversity of carbohydrates enables a wide range of their biological functions but makes the identification and study of these molecules difficult. We investigated the ability of intermolecular interactions to communicate structural ...

Wiley-VCH Verlag GmbH2019

Accurate molecular polarizabilities with coupled cluster theory and machine learning

Michele Ceriotti, David Mark Wilkins, Andrea Grisafi, Yang Yang

The molecular dipole polarizability describes the tendency of a molecule to change its dipole moment in response to an applied electric field. This quantity governs key intra- and intermolecular interactions, such as induction and dispersion; plays a vital ...

2019

Extending the Scope of the Density Overlap Region Indicator

Laurent Alexis Clément Vannay

In this thesis, original applications of the Density Overlap Region Indicator (DORI), a density dependent bonding descriptor capable of simultaneously capturing covalent and noncovalent interactions, are discussed. The use of scalar fields, such as DORI, w ...

EPFL2018

Advanced Plasmonic Nanostructures for Engineering Fluorescence Applications

Xiaolong Wang

The appeal of plasmonics lies in the unique properties of coinage metal nanoparticles to strongly confine and enhance electromagnetic fields at the subwavelength. A simple 50 nm colloidal plasmonic particle can not only break the classical diffraction limi ...

EPFL2017

Multifunctional Plasmonic Metasurfaces for Novel Spectral and Spatial Applications

Chen Yan

Intensive developments of plasmonic nanomaterials over recent decades have inspired appealing applications in biosensing, optical trapping, fluorescence enhancement and light harvesting in solar cells. These nanostructures supporting unique light-matter in ...

EPFL2017

Subwavelength Focusing of Bloch Surface Waves

Hans Peter Herzig, Myun Sik Kim, Nicolas Maxime André Descharmes, Babak Vosoughi Lahijani

Microsized spheres can focus light into subwavelength spatial domains, a phenomenon called photonic nanojet. Even though well studied in three-dimensional (3D) configurations, only a few attempts have been reported to observe similar phenomena in two-dimen ...

Amer Chemical Soc2017

Origin of the Strong Interaction between Polar Molecules and Copper(II) Paddle-Wheels in Metal Organic Frameworks

Berend Smit, Daniele Ongari, Davide Tiana

The copper paddle-wheel is the building unit of many metal organic frameworks. Because of the ability of the copper cations to attract polar molecules, copper paddle-wheels are promising for carbon dioxide adsorption and separation. They have therefore bee ...

American Chemical Society2017