Publications associées à A Concise Total Synthesis of (±)-Trigonoliimine B

Insights from an extensive triaxial testing campaign on a shale for comparative site characterization of a deep geological repository

Lyesse Laloui, Alessio Ferrari, Eleonora Crisci

Several boreholes were drilled for site comparison of a deep geological repository (DGR) in Northern Switzerland. The main target of the exploration program was the >100m thick Opalinus Clay, the designated host rock encountered at approximately 450 to 100 ...

Elsevier2024

Modeling friction and wear using an adaptive discrete-continuum coupling

Manon Eugénie Voisin--Leprince

When two objects slide against each other, wear and friction occur at their interface. The accumulation of wear forms what is commonly referred to as a ``third-body''. Understanding third-body evolution has significant applications in industry, where contr ...

EPFL2024

Understanding the mechanisms of adhesive wear for heterogeneous materials through atomistic simulations

Jean-François Molinari, Sacha Zenon Wattel, Antonio Joaquin Garcia Suarez

When two rough surfaces slide against each other, two main behaviors can be observed at the asperity level: A ductile behavior where the asperities tend to smooth out or a brittle behavior where the asperities detach and form debris. Recently, a critical l ...

2022

Common workflows for computing material properties using different quantum engines

Sebastiaan Philippe Huber, Nicola Marzari, Gian-Marco Rignanese, Giovanni Pizzi, Aliaksandr Yakutovich, Berend Smit, Martin Uhrin, Conrad Johnston, Austin Jacob Zadoks, Samuel Poncé, Kristjan Eimre, Marnik Bercx, Christopher John Sewell

The prediction of material properties based on density-functional theory has become routinely common, thanks, in part, to the steady increase in the number and robustness of available simulation packages. This plurality of codes and methods is both a boon ...

2021

Electronic-structure methods for materials design

Nicola Marzari, Andrea Ferretti

Simulations can be used to accelerate the characterization and discovery of materials. Here we Review how electronic-structure methods such as density functional theory work, what properties they can be used to predict and how they can be used to design ma ...

NATURE RESEARCH2021

Crack propagation in CFRP laminates under mode I monotonic and fatigue loads: A methodological study

John Botsis, Charlie Joseph Simon Blondeau, Georgios Pappas

Delamination in composite materials is often accompanied by fiber bridging that increases resistance to crack growth. Here, delamination of two unidirectional carbon/epoxy systems was studied under monotonic and displacement-controlled fatigue loading. One ...

ELSEVIER SCI LTD2021

Adhesive wear regimes on rough surfaces and interaction of micro-contacts

Jean-François Molinari, Son-Jonathan Pham-Ba

We develop an analytical model of adhesive wear between two unlubricated rough surfaces, forming micro-contacts under normal load. The model is based on an energy balance and a crack initiation criteria. We apply the model to the problem of self-affine rou ...

2021

Performance of Embedded Bolt Shear Connectors

Scott Walbridge, Matthew James Sjaarda

A laboratory research program carried out at the University of Waterloo featured the testing of three large-scale steel-concrete composite beam specimens with embedded bolt shear connectors. A detailed assessment of the connector performance was made, faci ...

TAYLOR & FRANCIS LTD2020

Enantioselective (CpRhIII)-Rh-x-Catalyzed Carboaminations of Acrylates

Nicolai Cramer, Coralie Danielle Annick Duchemin

Enantioselective carboaminations of olefins constitute an attractive strategy for a rapid increase in molecular complexity from readily available starting materials. Reported here is an intermolecular asymmetric carboamination of acrylates using rhodium(II ...

Wiley-VCH Verlag GmbH2020

Thermomechanical Nanostraining of Two-Dimensional Materials

Giovanni Boero, Jürgen Brugger, Samuel Tobias Howell, Xia Liu, Ana Conde Rubio

Local bandgap tuning in two-dimensional (2D) materials is of significant importance for electronic and optoelectronic devices but achieving controllable and reproducible strain engineering at the nanoscale remains a challenge. Here, we report on thermomech ...

American Chemical Society (ACS)2020

The history of fiber-reinforced polymer composite laminate fatigue

Anastasios Vassilopoulos

Investigations of the fatigue performance of composite materials have accompanied their introduction in several engineering domains since the 1950s. An abundance of publications have emerged dealing with the experimental investigation of the fatigue perfor ...

ELSEVIER SCI LTD2020

Load history effects in fibre-reinforced polymer composite materials

Abdolvahid Movahedirad

Today, it is widely accepted that fatigue is one of the most common failure mechanisms in structural components, and pure static failure is rarely observed. Engineering structures are subjected to complex mechanical fatigue loading histories, which cause d ...

EPFL2019

Photoredox-Catalyzed Decarboxylation for the Transfer of Alkynes and Nitriles Using Hypervalent Iodine Reagents

Franck Le Vaillant

Aliphatic alkynes and nitriles are privileged motifs in organic chemistry. Therefore, alkynes and nitriles have played a central role for the exploration and development of novel strategies to forge C-C bonds in efficient manner. They are broadly used as v ...

EPFL2019

Development of New Strategies of Umpolung with Cyclic Hypervalent Iodine Reagents

Paola Caramenti

Organic chemistry is essential for the development of a modern society and technical progress requires the continuous development of synthetic methodologies Novel, efficient, selective and flexible protocols are employed to access complex frameworks from s ...

EPFL2019

Multiscale experimental characterisation and modelling of transverse cracking in thin-ply composites

Sébastien Kohler

In this work, the damage dependency on ply thickness is investigated experimentally for three different thin-ply CFRP quasi-isotropic laminates, with constituents spanning a large range of properties. It is shown that free edge damage mechanisms, observed ...

EPFL2019

Bioinspired Viscoelastic Capsules: Delivery Vehicles and Beyond

Esther Amstad, Gianluca Nicolas Etienne, Irvine Lian Hao Ong

Microcapsules are often used as individually dispersed carriers of active ingredients to prolong their shelf life or to protect premature reactions with substances contained in the surrounding. This study goes beyond this application and employs microcapsu ...

Wiley2019

Ultra low cycle fatigue of welded steel joints under multiaxial loading

Albano António De Abreu E Presa De Castro E Sousa

Extreme loading scenarios such as earthquakes, exceptional wind gusts or tides are characterized by very high amplitude and multidirectional cyclic loads applied to a structure. Ultra Low Cycle Fatigue (ULCF) arises in such cases and can be summarily defin ...

EPFL2017

Fatigue performance of a cold-curing structural epoxy adhesive subjected to moist environments

Thomas Keller, Anastasios Vassilopoulos, Maria Savvilotidou

This paper presents the results of an experimental program designed to study the effects of aging and a wet environment on the fatigue behavior of epoxy resins used in bridge applications. Specimens were manufactured, cured, and treated, before the experim ...

Elsevier2017

Ultrafast Laser to Tailor Material Properties: An Enabling Tool in Advanced Three-dimensional Micromanufacturing

Yves Bellouard

The progress made in ultrafast laser technology towards high repetition rate systems have opened new opportunities in micromanufacturing. Non-linear absorption phenomena triggered by femtosecond pulses interacting with transparent materials allow material ...

Swiss Chemical Soc2017

Strength and fracture of silicon second-phase particles in aluminium casting alloys

Martin Guillermo Mueller

The mechanical behaviour of metallic materials that have a microstructure composed of a brittle phase embedded in a ductile matrix is dictated by a complex interplay of factors such as local phase properties, cohesive properties, geometrical characteristic ...

EPFL2017