Publications associées à Multi-objective Optimization of Supercritical Water Gasification of Leftover Brazilian Ginseng Roots After Phytochemical Recovery Steps

Continuous Supercritical Water Impregnation Method for the Preparation of Metal Oxide on Activated Carbon Composite Materials

Metal oxide (MexOy) nanomaterials are used as catalysts and/or sorbents in processes taking place in supercritical water (scH2O), which is the “green” solvent needed to obtain energy-relevant products. Their properties are significantly influenced by the s ...

2024

Investigation of Biomass Hydrothermal Conversion Products by HRMS

Daniil Salionov

The dependency on fossil fuels and their impact on the environment is a matter of great concern for the future sustainability of modern society. The development of the "green" technologies which utilize renewable energy sources is now under investigation. ...

EPFL2023

Renewable Energy Integration and Waste Heat Recovery for the Production of Sustainable Jet Fuel and Decarbonization of Industrial Heating Applications

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos, Réginald Germanier

The process synthesis and optimization methods used in this work include simulation of biomass gasification, hydrogen and synthetic natural gas production, and jet fuel production via a Fisher Tropsch unit. An energy integration approach, carried out by th ...

American Institute of Chemical Engineering2023

Alternative energy supply approach for industrial complexes and district heating networks based on biomass integrated gasification

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

In this work, a systematic approach combining different energy solutions and the time-varying energy demands is used to identify the operating conditions and arrangements for industrial complexes. A kraft pulp mill integrated to an urban district heating n ...

Universidad de Las Palmas de Gran Canaria2023

Particle Size Effects in Ru/CNF Catalysts during Supercritical Water Gasification of Glycerol

Frédéric Vogel, Oliver Kröcher, David Baudouin, Ayush Agarwal

Ru/CNF catalysts of different Ru nanoparticle (NP) sizes (0.9-2.7 nm) were assessed for their performance in continuous supercritical water gasification (SCWG) of glycerol. A structure sensitivity of Ru was demonstrated, with high initial turnover frequenc ...

2022

Supported ruthenium nanoparticles for supercritical water gasification - synthesis, activity and stability

Christopher Marc Hunston

Supercritical water gasification (SCWG) is a promising and versatile technology for the conversion of a variety of wet biomass streams into renewable natural gas. In this work, the focus was set on methane production with the help of an active and stable m ...

EPFL2021

A study on synergies of combined pulp and fuel production

François Maréchal, Tuong-Van Nguyen, Erina Clare Mcdonald, Julia Granacher

To limit climate change by reducing global greenhouse gas emissions, a transition away from fossil fuels is required. Biofuels represent a promising low carbon alternative for sectors that are hard to electrify, such as aviation. The integration of bio ref ...

2021

Visualization of supercritical water pseudo-boiling at Widom line crossover

Andrea Testino, Christian Ludwig

Supercritical water is a green solvent used in many technological applications including materials synthesis, nuclear engineering, bioenergy, or waste treatment and it occurs in nature. Despite its relevance in natural systems and technical applications, t ...

Nature Research2019

Supercritical water anomalies in the vicinity of the Widom line

Christian Ludwig

Supercritical water is used in a variety of chemical and industrial applications. As a consequence, a detailed knowledge of the structure-properties correlations is of uttermost importance. Although supercritical water was considered as a homogeneous fluid ...

Nature Research2019

Next generation cogeneration system for industry - Combined heat and fuel plant using biomass resources

François Maréchal, Adriano Viana Ensinas, Ayse Dilan Celebi

The requirement for sustainable development has prompted the researchers to explore solutions for better utilization of renewable energy resources in the future. Biomass is a promising resource and it can be converted to multiple products and services incl ...

Elsevier2019

Comparison of extraction techniques for product diversification in a supercritical water gasification-based sugarcane-wet microalgae biorefinery: Thermoeconomic and environmental analysis

François Maréchal, Adriano Viana Ensinas

This study presents a thermoeconomic and environmental assessment of the extraction of lipids and proteins from wet microalgal biomass in a 3G biorefinery by two different technologies: supercritical fluid extraction (SFE) and low-pressure solvent extracti ...

ELSEVIER SCI LTD2018

Multiple Inflow Branches at Supercritical-Type Vortex Drop Shaft

Jean-Marc Ribi, Thierry Fuchsmann, Michael Pfister, Corrado Gisonni, Gaetano Crispino

Vortex drop shafts serve to overcome important elevation differences in drainage systems. If well designed, they are performant in terms of energy dissipation and safety. However, the standard design requires well-defined approach flow conditions to ensure ...

ASCE-AMER SOC CIVIL ENGINEERS2018

Methodologies for simultaneous optimization of heat, mass, and power in industrial processes

Maziar Kermani

Efficient consumption of energy and material resources, including water, is the primary focus for process industries to reduce their environmental impact. The Conference of Parties in Paris (COP21) highlighted the prominent role of industrial energy effici ...

EPFL2018

Robust multi-objective optimization of solid oxide fuel cell–gas turbine hybrid cycle and uncertainty analysis

François Maréchal, Shivom Sharma

Chemical process optimization problems often have multiple and conflicting objectives, such as capital cost, operating cost, production cost, profit, energy consumptions and environmental impacts. In such cases, Multi-Objective Optimization (MOO) is suitab ...

2018

The impact of sorbent geometry on the sulphur adsorption under supercritical water conditions: a numerical study

Andrea Testino, Christian Ludwig

A numerical model to show the impact of the adsorption bed geometry on the desulfurization process of wet biomass under supercritical water (SCW) gasification process has been developed. Three different geometries, straight channels (pipe), sharp-edged cha ...

Springer Heidelberg2017

Fermi resonance in CO2: Mode assignment and quantum nuclear effects from first principles molecular dynamics

Sara Bonella, Guillaume André Jean Fraux

Vibrational spectroscopy is a fundamental tool to investigate local atomic arrangements and the effect of the environment, provided that the spectral features can be correctly assigned. This can be challenging in experiments and simulations when double pea ...

Amer Inst Physics2017

Thermo-economic and environmental comparison of supercritical water and enzymatic hydrolysis of sugarcane bagasse in a biorefinery concept

François Maréchal, Adriano Viana Ensinas

In this study, we discuss the difference regarding thermo-economic and environmental (water intake) aspects between two methods of biomass hydrolysis. A thermo-economic model was developed using Aspen Plus® and MATLAB software in order to analyze the energ ...

2017

Product diversification in the sugarcane biorefinery through algae growth and supercritical CO 2 extraction: Thermal and economic analysis

François Maréchal, Adriano Viana Ensinas

The sugarcane sector in Brazil has undergone a major modernization in the last thirty years. Embracing the biorefinery concept, this sector is investigating bioproduct diversification and mostly putting a lot of effort and investment on second generation e ...

Pergamon-Elsevier Science Ltd2017

Multi-objective Optimization of Solid Oxide Fuel Cell–Gas Turbine Hybrid Cycle and Uncertainty Analysis

François Maréchal, Emanuela Peduzzi, Ayse Dilan Celebi, Shivom Sharma

Chemical process optimization problems often have multiple and conflicting objectives, such as capital cost, operating cost, production cost, profit, energy consumption and environmental impact. There are several conversion technologies that can convert Sy ...

University of Ljubljana2016

Photocatalytic and Electrocatalytic Reduction of Carbon Dioxide in Pressurized Systems

Patrick Voyame

The depletion of carbon-based fossil fuels and the rise in atmospheric carbon dioxide concentration will force an inevitable change in the future global energy landscape. CO2 reduction presents the advantages of decreasing its atmospheric concentration and ...

EPFL2016