Publications associées à Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization

Development of Sustainable Carbohydrate-Based Solvents by Acetal Functionalisation of Biomass

Organic solvents are ubiquitous in industrial and domestic applications from the production of pharmaceuticals to household consumer products. The negative impact of most traditional solvents, especially aprotic types, on the environment, health, and safet ...

EPFL2024

New Polymers from Biomass-Derived Hydroxycinnamic Acid Derivatives

Ghezae Tekleab

Polymers play a central role in shaping our world across various fields, but their heavy reliance on petrochemicals poses climate change, environmental and health risks. To address and alleviate these issues, transitioning to sustainable polymers, sourced ...

EPFL2024

Decarbonizing the fertilizers sector: an alternative pathway for urea and nitric acid production

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

In order to alleviate the environmental impact that nitrogen fertilizers production is responsible for, several efforts have been addressed to incentivize the partial or total decarbonization of the supply chains of ammonia and its derivatives. The decarbo ...

2024

Selecting Suitable Near-Native Lignins for Research

Jeremy Luterbacher

There are several methods to isolate near-native lignins, including milled-wood lignin, enzymatic lignin, cellulolytic enzyme lignin, and enzymatic mild-acidolysis lignin. Which one is the most representative of the native lignin? Herein, near-native ligni ...

Amer Chemical Soc2023

Direct conversion of lignin to functionalized diaryl ethers via oxidative cross-coupling

Paul Joseph Dyson, Mingyang Liu

Efficient valorization of lignin, a sustainable source of functionalized aromatic products, would reduce dependence on fossil-derived feedstocks. Oxidative depolymerization is frequently applied to lignin to generate phenolic mono- mers. However, due to th ...

Nature Research2023

Integrated production of urea and nitric acid in the pulp industry: techno-economic and environmental analysis of black liquor gasification-based processes

François Maréchal, Shivom Sharma, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

The pursuit of alternative energy sources for the nitrogen fertilizers sector has recently earned renewed interest due to increasing concerns regarding the world dependence on non-renewable energy resources and also motivated by the more stringent environm ...

2022

Lignin Hydrogenolysis: Phenolic Monomers from Lignin and Associated Phenolates across Plant Clades

Jeremy Luterbacher, Yuan Li

The chemical complexity of lignin remains a major challengeforlignin valorization into commodity and fine chemicals. A knowledgeof the lignin features that favor its valorization and which plantsproduce such lignins can be used in plant selection or to eng ...

AMER CHEMICAL SOC2023

Investigation of Biomass Hydrothermal Conversion Products by HRMS

Daniil Salionov

The dependency on fossil fuels and their impact on the environment is a matter of great concern for the future sustainability of modern society. The development of the "green" technologies which utilize renewable energy sources is now under investigation. ...

EPFL2023

Lignin, from biomass waste to sustainable materials for food packaging, antiviral coatings and agriculture

Alice Boarino

Our planet has been challenged for years by our reckless use of fossil fuels, which has led to the ongoing climate change and energy crisis. The transition to the use of renewable alternative sources has now became urgent and inevitable. The valorization o ...

EPFL2023

Extraction and controlled functionalization of lignin for materials applications

Stefania Bertella

Lignin is a renewable aromatic polymer that due to its abundance and unique chemical structure is a promising candidate to replace aromatic materials that are currently sourced from fossil oil. The same structure of lignin poses however drawbacks for its v ...

EPFL2022

An optimized high throughput platform, from genetic transformation to fermentation, to screen for secreted laccases in Aspergillus niger

Laure Marie Colette Leynaud-Kieffer Curran

Many challenges are faced in the conversion of biomass into advanced biofuels, one of which is finding the correct organism for the job. The filamentous fungus Aspergillus niger has been chosen as a biocatalyst for cellulose, hemicellulose, and lignin degr ...

EPFL2021

Developing structure-oriented models for enzymatic hydrolysis of lignocellulosic biomass

Jessica Charlène Rohrbach

With the unsustainable use of fossil fuels increasing strains on human institutions and ecosystems, the development of a renewable energy alternative is of paramount importance. Second generation biorefineries, based on the production of fuels and chemical ...

EPFL2021

Diformylxylose as a new polar aprotic solvent produced from renewable biomass

Jeremy Luterbacher, Graham Reid Dick, Anastasiia Komarova

Lignin is a promising candidate for the replacement of fossil-based materials, due to its natural abundance and aromatic structure. This same structure poses major challenges to lignin's exploitation for material development. The harsh conditions generally ...

2021

Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite films

Muhammad Farooq, Xun Liao

A "waste-valorization" approach was developed to transform recalcitrant hydrolysis lignin (HL) from secondgeneration bioethanol production into multifunctional bio-based products. The hydrolysis lignin (HL) was extracted with aqueous acetone, yielding two ...

ELSEVIER2021

Guidelines for performing lignin-first biorefining

Jeremy Luterbacher, Feng Wang

The valorisation of the plant biopolymer lignin is now recognised as essential to enabling the economic viability of the lignocellulosic biorefining industry. In this context, the "lignin-first" biorefining approach, in which lignin valorisation is conside ...

2021

A study on synergies of combined pulp and fuel production

François Maréchal, Tuong-Van Nguyen, Erina Clare Mcdonald, Julia Granacher

To limit climate change by reducing global greenhouse gas emissions, a transition away from fossil fuels is required. Biofuels represent a promising low carbon alternative for sectors that are hard to electrify, such as aviation. The integration of bio ref ...

2021

Lignin Functionalization for the Production of Novel Materials

Jeremy Luterbacher, Stefania Bertella

Lignin, a major constituent of lignocellulosic biomass, is the largest natural source of aromatic molecules and thus is an attractive feedstock for renewable chemical production. Direct incorporation of isolated lignin into materials has long been research ...

2020

Aldehyde-Assisted Lignocellulose Fractionation Provides Unique Lignin Oligomers for the Design of Tunable Polyurethane Bioresins

Jeremy Luterbacher, Raymond Gérard Buser, Florent Emmanuel Héroguel, Jean Thierry C Behaghel de Bueren, Chloé Wegmann

Thanks to chemical stabilization, aldehyde-assisted fractionation (AAF) of lignocellulosic biomass has recently emerged as a powerful tool for the production of largely uncondensed lignin. Depolymerization of AAF lignin via ether deavage provides aromatic ...

American Chemical Society2020

Aldehyde-Assisted Fractionation Enhances Lignin Valorization in Endocarp Waste Biomass

Jeremy Luterbacher, Raymond Gérard Buser, Florent Emmanuel Héroguel, Jean Thierry C Behaghel de Bueren, Chloé Wegmann, Graham Reid Dick

Endocarp biomass, which forms much of the inedible portion of nuts and stone fruits, is a promising feedstock for aromatic chemical production due to its high lignin content and because it is a food industry waste. Here, we tested the nut shells and fruit ...

2020

Topology of Pretreated Wood Fibers Using Dynamic Nuclear Polarization

Jeremy Luterbacher, Arthur César Pinon, David Lyndon Emsley, Jasmine Viger-Gravel, Wu Lan, Michel Bardet, Pierrick Berruyer

In the continuously developing field of lignocellulosic biomass, high-yield lignin depolymerization processes are sought to optimize its productivity and profitability. Recently, formaldehyde stabilization during lignin extraction and biomass pretreatment ...

2019