Publications associées à A PCP-Pincer RuII-Terpyridine Building Block as a Potential "Antenna Unit" for Intramolecular Sensitization

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

EPFL2024

Analytic Approximation of In-Body Path Loss for Implanted Antennas

Anja Skrivervik, Mingxiang Gao, Zvonimir Sipus

Implantable bioelectronic devices predominantly use wireless links for communication and/or power transfer. When considering transmitting implanted antennas, electromagnetic radiation through biological media is highly attenuated, and previous work has sho ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2023

Bridging Native and Intrinsic Structures of Microhydrated Biomolecules by Cold Ion Spectroscopy

Andrei Zviagin

Solving native structures of such large molecules, like biomolecules, is often challenging, particularly due to the potentially infinite number of non-covalent interactions with water. In this thesis, we report the use of cold ion gas-phase action spectros ...

EPFL2023

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

Ultralow-Profile Circularly Polarized Reflectarray Antenna for CubeSat Intersatellite Links in K-B and

Anja Skrivervik, Miroslav Veljovic

An ultralow-profile circularly polarized (CP) reflectarray (RA) antenna is presented in this article, based on the variable-rotation technique for beam collimation and scanning. Starting from a conventional split-loop element, a new wideband element is des ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2021

On the 5G Communications: Fractal-Shaped Antennas for PPDR Applications

Maria-Alexandra Paun

In this study, one method of using antennas based on fractals to cover few kinds of public protection and disaster relief (PPDR) communications was presented. Dedicated antenna forms, necessary for antenna design by 5G implementation, were enhanced to suit ...

WILEY-HINDAWI2021

Importance of Long-Range Channel Sr Displacements for the Narrow Emission in Sr[Li2Al2O2N2]:Eu2+ Phosphor

Samuel Poncé

The recently discovered Sr[Li2Al2O2N2]:Eu2+ red phosphor, candidate for the next generation of eco-efficient white light-emitting diodes, exhibits excellent emission spectral position and exceptionally small linewidth. It belongs to the UCr4C4-structure fa ...

WILEY-V C H VERLAG GMBH2021

Photo- and thermally-induced electronic and structural dynamics in perovskites and transition metal oxides

Oliviero Cannelli

In this thesis, we exploited optical and X-ray pump-probe methods in a synergistic approach to study the interplay of the electronic, spin and structural degrees of freedom in two class of complex systems relevant for solar energy conversion applications: ...

EPFL2021

In-body Antennas Design Based on Fundamental Limits of Obtainable Power Density

Anja Skrivervik, Zvonimir Sipus

In-body medical implants are one of the most promising solutions for increasing patient healthcare in the future. Many such devices already exist, however, each new design is a challenge due to size constraints and communication issues which arise due to s ...

IEEE2021

A portable picocell antenna for 5G

Danelys Rodríguez Avila

Deployable emergency communication systems are a backbone solution for replacing damaged network infrastructures and/or providing high-end services in case of an emergency event. It is important that such systems are up-to-date with the latest mobile netwo ...

EPFL2021

Structure-Property Relationships of Microphase-Separated Metallosupramolecular Polymers

Emad Oveisi, Stephen Schrettl

The structural, thermomechanical, and viscoelastic properties of metallosupramolecular polymers (MSPs) can be controlled through the choice of the multiligand monomer and the nature of the metal salt from which these materials are assembled. This versatili ...

American Chemical Society2020

Structure and small molecule activation reactivity of a metallasilsesquioxane of divalent ytterbium

Rosario Scopelliti, Marinella Mazzanti, Aurélien René Willauer

The first metallasilsesquioxane of a divalent lanthanide, Yb{Cy7Si7O11(OSiMe3)}(THF),1, was synthesized and structurally characterized. The Cy7Si7O11(OSiMe3)(2-)ligands in1bind two Yb(ii) ions in a bridging mode. The dinuclear complex effects the two- ...

Royal Society of Chemistry2020

Carbon dioxide reduction by lanthanide(iii) complexes supported by redox-active Schiff base ligands

Rosario Scopelliti, Marinella Mazzanti, Davide Toniolo, Nadir Jori

Here we have explored the ability of Schiff bases to act as electron reservoirs and to enable the multi-electron reduction of small molecules by lanthanide complexes. We report the reductive chemistry of the Ln(iii) complexes of the tripodal heptadentate S ...

2020

Zero Index Metamaterial for High Gain Array

Tingyong Jiang

Many metamaterials, including metal wire grid, was invented to enhance the performance of the antenna in the last decade. A novel zero index metamaterial (ZIM), consisting of double metal layers with periodic circular perforation cells, was proposed and st ...

IEEE2020

Colorimetry of Luminescent Lanthanide Complexes

Anne-Sophie Chauvin, Julien Alexandre Andres

Europium, terbium, dysprosium, and samarium are the main trivalent lanthanide ions emitting in the visible spectrum. In this work, the potential of these ions for colorimetric applications and colour reproduction was studied. The conversion of spectral dat ...

2020

Taking lanthanides out of isolation: tuning the optical properties of metal-organic frameworks

Kevin Sivula, Gloria Capano, Muhammad Aiman Bin Rahmanudin Hamdan, Nestor Guijarro Carratala, Berend Smit, Samantha Lynn Anderson, Kyriakos Stylianou, Davide Tiana, Andrzej Gladysiak, Christopher Patrick Ireland, Stavroula Kampouri, Maria Fumanal Quintana

Metal organic frameworks (MOFs) are increasingly used in applications that rely on the optical and electronic properties of these materials. These applications require a fundamental understanding on how the structure of these materials, and in particular t ...

2020

Optical absorption properties of metal-organic frameworks: solid stateversusmolecular perspective

Ivano Tavernelli, Anne-Clémence Corminboeuf, Berend Smit, Maria Fumanal Quintana

The vast chemical space of metal and ligand combinations in Transition Metal Complexes (TMCs) gives rise to a rich variety of electronic excited states with local and non-local character such as intra-ligand (IL), metal-centered (MC), metal-to-ligand (MLCT ...

2020

Picometer Resolution Structure of the Coordination Sphere in the Metal-Binding Site in a Metalloprotein by NMR

David Lyndon Emsley, Andrea Bertarello

Most of our understanding of chemistry derives from atomic-level structures obtained with single-crystal X-ray diffraction. Metal centers in X-ray structures of small organometallic or coordination complexes are often extremely well-defined, with errors in ...

2020

Accelerated Discovery of Metal-Organic Frameworks (MOFs) For Energy Related Applications

Arunraj Chidambaram

Metal-Organic Frameworks (MOFs) are an emerging class of materials that consist of metal ions which are linked with organic ligands via coordination bonds to form extended networks. MOF structures consists predominantly of open voids which makes them among ...

EPFL2020

Modeling of TAE mode excitation with an antenna in realistic X-point geometry

Ambrogio Fasoli, Duccio Testa

Experimentally, it is observed that Toroidal Alfven Eigenmodes (TAEs) are difficult to excite with an external antenna when the plasma is in X-point geometry. Here, the effect of the X-point geometry on the efficiency of the TAE excitation with the externa ...

AMER INST PHYSICS2020