Publications associées à Long-term in-situ oxidation of biogenic uraninite in an alluvial aquifer: impact of dissolved oxygen and calcium

Atomic level insight into irradiation effects in nuclear fuel materials

Microstructural evolution during in-pile irradiation, radiation damage effects and fission products behavior in UO2 nuclear fuel are key issues in understanding and for the modeling of the performance as well as safety characteristics of nuclear fuels in t ...

EPFL2024

Nature-based solution enhances resilience to flooding and catalyzes multi-benefits in coastal cities in the Global South

Jérôme Chenal, Paolo Perona, Charlotte Grossiord, Montana Marshall, Emmanuel Qays Dubois

Coastal cities are facing a rise in groundwater levels induced by sea level rise, further triggering saturation excess flooding where groundwater levels reach the topographic surface or reduce the storage capacity of the soil, thus stressing the existing i ...

2024

Contribution of standardized indexes to understand groundwater level fluctuations in response to meteorological conditions in cold and humid climates

Emmanuel Qays Dubois

Understanding the fluctuations in groundwater levels in response to meteorological conditions is challenging, especially given the slow transit time associated with groundwater reservoirs and the short duration of time series for groundwater levels. Nevert ...

2024

Innovative thermophysical characterization of an ATF composite cladding: the case of silicon carbide

Andrea Cavaliere

Nuclear power is a powerful technology that plays an important role in the fight against climate change, and research is continuously engaged in studies that could further improve its safety. After the Fukushima accident, Accident Tolerant Fuels research h ...

EPFL2024

Data-driven statistical optimization of a groundwater monitoring network

Andrea Rinaldo, Gianluca Botter

We propose a comparative study of three different methods aimed at optimizing existing groundwater monitoring networks. Monitoring piezometric heads in subsurface porous formations is crucial at regional scales to properly characterize the relevant subsurf ...

Elsevier2024

Intra-pin Reaction Rate Measurements in the CROCUS Experimental Reactor

Andreas Pautz, Oskari Ville Pakari, Vincent Pierre Lamirand, Mathieu Hursin, Thomas Jean-François Ligonnet, Tom Mager

In response to the need for validating high-fidelity deterministic neutronics solvers capable of providing pin-resolved neutron flux distributions, intra-pin reaction rates measurements were performed in the CROCUS experimental reactor. A specially designe ...

2024

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Dieuwertje Katelijn Modder

In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

EPFL2023

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Dieuwertje Katelijn Modder

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

Wiley-VCH Verlag GmbH2023

Gamma-Blind Fast Neutron Detection for Spent Nuclear Fuel Characterization

Alexander Wolfertz

In this thesis, the development and testing of a system for measuring the axial distribution of fast neutron emission of spent nuclear fuel rods is presented. Emphasis is placed on the novel fast neutron detector used which can reliably work in extremely h ...

EPFL2023

Design of an Instrumented Fuel Rod for Intra-pin Neutron Flux Measurements in the CROCUS Experimental Reactor

Andreas Pautz, Vincent Pierre Lamirand, Mathieu Hursin, Thomas Jean-François Ligonnet, Won Dong Shin, Tom Mager

In response to the need for validating high-fidelity deterministic neutronics solvers capable of pin-resolved neutron flux distributions, an instrumented fuel rod was designed for the experimental reactor CROCUS, operated by EPFL’s Laboratory for Reactor P ...

2023

Watertable fluctuations in coastal unconfined aquifers with a sloping sea boundary: Vertical flow and dynamic effective porosity effects

David Andrew Barry, Zhaoyang Luo

Interactions between the tide and sloping sea boundary make watertable fluctuations in coastal unconfined aquifers complicated. Based on a perturbation method, we derived a new analytical solution to predict watertable fluctuations for coastal unconfined a ...

2023

Shear strength and shear stiffness analysis of compacted Wyoming-type bentonite

Alessio Ferrari

Wyoming-type bentonite is one of the materials to be used as part of the Engineered Barrier System (EBS) in deep geological disposal facilities for the safe disposal of spent nuclear fuel.In the KBS-3 type repository, the canisters containing the spent fue ...

ELSEVIER2023

Applying the Principal Component Analysis for a deeper understanding of the groundwater system: case study of the Bacchiglione Basin (Veneto, Italy)

Andrea Rinaldo

In hydrogeology, it is often difficult to fully understand the hydraulic factors affecting the recharge of groundwater systems. Particularly, at a regional scale, the groundwater system can have different drivers depending on the considered area, i.e., soi ...

PAGEPRESS PUBL2022

Impacts of climate change on Swiss alluvial aquifers - A quantitative forecast focused on natural and artificial groundwater recharge by surface water infiltration

Carl Love Mikael Råman Vinnå, Sebastiano Piccolroaz

The sensitivity of future groundwater recharge and temperature development was investigated for three alluvial aquifers in the urban agglomeration of the city of Basel, Switzerland. For selected climate projections groundwater recharge and the associated t ...

ELSEVIER2022

Biostimulation as a sustainable solution for acid neutralization and uranium immobilization post acidic in-situ recovery

Pierre Rossi, Rizlan Bernier-Latmani, Thomas Coral

Major uranium (U) deposits worldwide are exploited by acid leaching, known as 'in-situ recovery' (ISR). ISR involves the injection of an acid fluid into ore-bearing aquifers and the pumping of the resulting metal-containing solution through cation exchange ...

2022

Multi-electron Transfer by U(II) and Masked U(II) Complexes

Marinella Mazzanti

Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...

SWISS CHEMICAL SOC2022

Data-Driven Predictive Models: Calculational Bias in Characterization of Spent Nuclear Fuel

Characteristics of the spent nuclear fuel (SNF) are typically calculated, requiring validation a priori. The validation process relies on the difference between calculations and measurements, namely the bias. Usually, predicting the bias based on benchmark ...

EPFL2022

Drops: Controlled crystallization of organic crystals and their use as matrix materials for encapsulation of volatiles

Aysu Ceren Okur

Encapsulation techniques open up new possibilities to control the kinetics and location of the release of active ingredients. Despite the progresses achieved to obtain a better control over the dimensions and composition of the capsules, the encapsulation ...

EPFL2022

Approximate analytical solutions for assessing the effects of unsaturated flow on seawater extent in thin unconfined coastal aquifers

David Andrew Barry, Zhaoyang Luo

This study develops approximate analytical solutions for seawater extent in unconfined coastal aquifers considering unsaturated flow, and assuming steady-state, sharp-interface conditions, for both constant flux (flux-controlled aquifers) and constant head ...

2022

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Rosario Scopelliti, Marinella Mazzanti, Luciano Barluzzi, Fang-Che Hsueh

Thorium nitrides are likely intermediates in the reported cleavage and functionalization of dinitrogen by molecular thorium complexes and are attractive compounds for the study of multiple bond formation in f-element chemistry, but only one example of thor ...

2022