Publications associées à Uranium redox transition pathways in acetate-amended sediments

Atomic level insight into irradiation effects in nuclear fuel materials

Microstructural evolution during in-pile irradiation, radiation damage effects and fission products behavior in UO2 nuclear fuel are key issues in understanding and for the modeling of the performance as well as safety characteristics of nuclear fuels in t ...

EPFL2024

Diagenetic isotope exchange in biocalcites for paleoclimate reconstruction

Deyanira Graciela Cisneros Lazaro

The oxygen isotope compositions of fossil biocalcites, such as foraminifera, bivalves, brachiopods, and belemnites have allowed for reconstructions of sea surface and deep ocean temperatures throughout the Phanerozoic and constitute the most important reco ...

EPFL2024

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Dieuwertje Katelijn Modder

In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

EPFL2023

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Dieuwertje Katelijn Modder

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

Wiley-VCH Verlag GmbH2023

Characterization of Thruster-Induced Turbulence for Fine Sediment Suspension

Giovanni De Cesare, Azin Amini, Montana Marshall, Andre Luis Stakowian

Reservoir sedimentation is a key challenge for storage sustainability because it causes volume loss, affecting hydropower production capacity, dam safety, and flood management. A preliminary EPFL study proposed and studied an innovative device (called SEDM ...

2023

Iron Reduction in Profundal Sediments of Ultraoligotrophic Lake Tahoe under Oxygen-Limited Conditions

Meret Aeppli

Increased periods of bottom water anoxia in deep temperate lakes due to decreasing frequency and depth of water column mixing in a warming climate may result in the reductive dissolution of iron minerals and increased flux of nutrients from the sediment in ...

2023

Experimental modeling of fine sediment routing: SEDMIX device with thrusters

Giovanni De Cesare, Azin Amini, Montana Marshall

Reservoir sedimentation is a key challenge for storage sustainability because it causes volume loss, affecting hydropower production capacity, dam safety, and flood management. A preliminary EPFL study proposed and studied an innovative device (called SEDM ...

CRC Press/Balkema2023

Experimental characterization of root-reinforced riparian sediment deposits in a restored and widened river course

Giovanni De Cesare, Paolo Perona

The Arbogne River is located mainly in the Swiss canton of Fribourg. The River was meandering through the plane at a very low gradient and several exceptional historic floods with large sediment accumulation are mentioned. After important river training wo ...

2023

Clogging of riverbed substrates by fine sediment

Romain Maxime Dubuis

Riverbeds represent the habitat of numerous aquatic species. Exchanges between the groundwater, the hyporheic zone and the surface flow are also essential for river ecosystems. Fine sediment transported by rivers deposits inside or on top of the bed and mo ...

EPFL2023

Ultrasonic sediment flux profiling with ACVP Technology: application to sediment-laden Boundary Layer flows

Giovanni De Cesare, David Hurther

Sediment transport in geophysical boundary layer flows has relevance to a broad spectrum of sciences ranging from the physical and chemical, to the biological, ecological and geological. Advances in sediment transport modelling and prediction strongly suff ...

2023

The clogging of riverbeds: A review of the physical processes

Giovanni De Cesare, Romain Maxime Dubuis

Fine sediment represents an important part of the solid flux of rivers. Due to the size of these particles, they are often transported as suspended load. They gradually fill the pores of the substrate forming the hyporheic zone or cover the substrate by se ...

2023

Influence of the shear stress on fine sediment exchanges with the substrate using UVP measurements

Giovanni De Cesare, Romain Maxime Dubuis

The dynamic of fine sediment in rivers is closely related to the interactions between fine particles, the riverbed and the flow conditions. The accumulation of fine sediment in the riverbed reduces vertical water exchanges and can have detrimental effects ...

2023

Reduction of riverbed clogging related to sediment flushing

Giovanni De Cesare, Romain Maxime Dubuis

The ecological effects of dams on sediment and river flow have been subject to an increasing attention, leading to the implementation of mitigation measures such as environmental flow release and sediment replenishment. However, fine sediment dynamics have ...

CRC Press/Balkema2023

Hydromorphological assessment of sediment augmentation measures in gravel-bed rivers

Christian Mörtl

In the riverine environment, the riverscape, sediment and flow regime are essential drivers for natural habitat dynamics. Today, most water courses in Europe are regulated, and their natural dynamics are impaired. Flood releases coupled with the artificial ...

EPFL2023

Limits between surface and inner clogging of riverbed by fine sediment

Giovanni De Cesare, Romain Maxime Dubuis

The deposition of fine sediment on top of the riverbed affects the reproduction of spawning fishes and some species of benthos. The clogging of the substrate resulting from this deposition is a well-known issue in rivers affected by anthropogenic activity ...

2023

Simulation of fine sediment deposition on floodplains

Giovanni De Cesare, Carmelo Juez Jiménez

Rivers extend beyond the channels that are typically associated with this word. Of particular interest are flood plains, where important hydro- and morphodynamic processes occur as a result of recurrent flooding. Ecologically, they also support the establi ...

2023

Continuous monitoring of morphological changes from sediment augmentation by field measurements and flume experiments

Giovanni De Cesare, Christian Mörtl

In this study, we present results from continuous field monitoring and a flume ex-periment of a sediment augmentation measure in a residual flow reach of the Swiss midlands. A straight morphological channel with fixed bed material was constructed to repres ...

2023

Design of an Instrumented Fuel Rod for Intra-pin Neutron Flux Measurements in the CROCUS Experimental Reactor

Andreas Pautz, Vincent Pierre Lamirand, Mathieu Hursin, Thomas Jean-François Ligonnet, Won Dong Shin, Tom Mager

In response to the need for validating high-fidelity deterministic neutronics solvers capable of pin-resolved neutron flux distributions, an instrumented fuel rod was designed for the experimental reactor CROCUS, operated by EPFL’s Laboratory for Reactor P ...

2023

Exploring the efficacy of reservoir fine sediment management measures through numerical simulations

Giovanni De Cesare, Azin Amini, Samuel Luke Vorlet, Montana Marshall

Reservoir sedimentation is one of the main challenges in the sustainable operation of large reservoirs because it causes volume loss, affecting hydropower production capacity, dam safety, and flood management. To ensure the sustainability of deep reservoir ...

CRC Press/Balkema2023

Stay close, but not too close: aerial image analysis reveals patterns of social distancing in seal colonies

Devis Tuia, Benjamin Alexander Kellenberger

Many species aggregate in dense colonies. Species-specific spatial patterns provide clues about how colonies are shaped by various (a)biotic factors, including predation, temperature regulation or disease transmission. Using aerial imagery, we examined the ...

2023