Publications associées à Intermolecular Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes

Teaching Not To

Two design studios were successively taught in two schools of architecture: one at the Harvard Graduate School of Design (GSD) and the other at the Swiss Federal Institute of Technology in Lausanne (EPFL) in Lausanne, Switzerland, based on "A Global Morato ...

Taylor & Francis Inc2024

Rising from rubble - Leveraging existing construction tools for upcycling concrete waste into slender walls

Katrin Beyer, Maxence Grangeot, Corentin Jean Dominique Fivet, Qianqing Wang, Stefana Parascho

In this paper, we present a new method for upcycling concrete rubble waste into slender walls through the lightweight digital augmentation of mainstream construction machines. By using such method, the environmental impact of concrete construction and demo ...

Springer2024

FLO:RE – A new floor system made of reused reinforced concrete and steel elements

Maléna Bastien Masse, Numa Joy Bertola, Célia Marine Küpfer, Corentin Jean Dominique Fivet

Carefully extracting reinforced concrete (RC) elements from soon-to-be demolished structures and reusing them as load-bearing components is an emerging circular low-carbon alternative to building new structures. As floor construction typically accounts for ...

IABSE2024

Catalytic Enantioselective Synthesis of Inherently Chiral Macrocycles by Dynamic Kinetic Resolution

Jieping Zhu, Shuo Tong

Kinetically fast racemization of chiral substrates through an achiral intermediate and enantioselective functionalization of one of the enantiomeric substrates forms the basis of the dynamic kinetic resolution (DKR) of centrally chiral molecules. We report ...

2024

Recent advances in Rh(I)-catalyzed enantioselective C-H functionalization

Nicolai Cramer, Shouguo Wang, Yi Zhang, Zhen Chen

Chiral carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds are pervasive and very essential in natural products, bioactive molecules, and functional materials, and their catalytic construction has emerged as one of the hottest research fields in syntheti ...

Royal Society of Chemistry2024

From Automated Bootstrapping to Collaborative Editing: A Framework for 4D City Reconstruction

Didier Louis Dupertuis, Rémi Guillaume Petitpierre, Paul Robert Guhennec, Beatrice Vaienti

We propose a framework for the construction of 4D scientific models for cities of the past. It leverages both the use of computational methods for bootstrapping, and a collaborative interface for visualisation and edition. This permits to continuously enri ...

Zenodo2023

Appropriations and Uses of Travel Time

Ludy Juliana González Villamizar

Time has always been a central factor in understanding the challenges of daily mobility. For a long time, and still today, methods of economic evaluation of transport projects have monetized time savings so that they can be included in the cost–benefit ana ...

ISTE Wiley2023

Low-tech methods for the reuse of reinforced concrete structural elements

Maléna Bastien Masse, Julie Rachel Devènes, Corentin Jean Dominique Fivet, Nicole Widmer

Most of existing buildings are made of concrete, new buildings are being built with it and others are demolished when still in good structural condition. This drives increased demands for raw materials, greenhouse gas emissions, and an accumulation of demo ...

2023

Asymmetric Construction of α,α‐Disubstituted Piperazinones Enabled by Benzilic Amide Rearrangement

Jieping Zhu, Hua Wu, Yuping He

An unprecedent asymmetric catalytic benzilic amide rearrangement for the synthesis of α,α-disubstituted piperazinones is reported. The reaction proceeds via a domino [4+1] imidazolidination/formal 1,2-nitro- gen shift/1,2-aryl or alkyl migration sequence, ...

Wiley-VCH Verlag GmbH2023

Construction of sequencing libraries from a ribonucleic acid (rna) using tailing and ligation of cdna (tlc)

Didier Trono, Christina Ernst

The present invention provides a method for preparing a sequencing library from a ribonucleic acid (RNA) sample. ...

2023

Extractable Witness Encryption for the Homogeneous Linear Equations Problem

Serge Vaudenay, Bénédikt Minh Dang Tran

Witness encryption is a cryptographic primitive which encrypts a message under an instance of an NP language and decrypts the ciphertext using a witness associated with that instance. In the current state of the art, most of the witness encryption construc ...

Springer2023

Energy dissipation in fiber-polymer composites adhesive joints under cyclic loading

Ghazaleh Eslami

Sustainable development has emerged as a paramount consideration in various fields of industry, including construction, to preserve the environment and its finite resources. Lightweight structures, such as fiber-polymer composite structures, address both s ...

EPFL2023

A Collaborative Workflow to Automate the Design, Analysis, and Construction of Integrally-Attached Timber Plate Structures

Pierre Latteur, Yves Weinand, Aryan Rezaei Rad, Petras Vestartas, Nicolas Henry Pierre Louis Rogeau

This paper introduces a computational framework that fosters collaboration between architects, engineers, and contractors by bridging the gap between architectural design, structural analysis, and digital construction. The present research is oriented towa ...

CAADRIA2022

A note on universal inference

Anthony Christopher Davison, Timmy Rong Tian Tse

Universal inference enables the construction of confidence intervals and tests without regularity conditions by splitting the data into two parts and appealing to Markov's inequality. Previous investigations have shown that the cost of this generality is a ...

WILEY2022

On the Grothendieck-Serre conjecture for classical groups

Eva Bayer Fluckiger

We prove some new cases of the Grothendieck-Serre conjecture for classical groups. This is based on a new construction of the Gersten-Witt complex for Witt groups of Azumaya algebras with involution on regular semilocal rings, with explicit second residue ...

WILEY2022

From Marshall Plan to “Hilton in the wild”: The Transnational History of a Cooperative Housing Block in Esat, Ankara

Sila Karatas

This paper concerns the planning, design, and construction history of a postwar multifamily housing block in Ankara, Turkey, viewed from the perspective of the transnational and local networks behind its realization. Built by the Mintrak Building Cooperati ...

2022

Digital twins for post-earthquake damage assessment of free-standing buildings including damage information

Radhakrishna Achanta, Katrin Beyer, Amir Rezaie, Bryan German Pantoja Rosero

We present a pipeline for the automatic generation of digital twins of free-standing buildings for damage assessment. Our method takes multiple view images of the target building as input and processes them to produce a 3D model in levels of detail (LOD) f ...

2022

Enantio- and diastereoselective construction of vicinal C(sp(3)) centres via nickel-catalysed hydroalkylation of alkenes

Xile Hu, Srikrishna Bera, Chao Fan

In drug discovery, the proportion of aliphatic carbons (C(sp(3))) and the presence of chiral carbons in organic molecules are positively correlated to their chance of clinical success. Although methods exist for the synthesis of chiral C(sp(3))-rich molecu ...

2022

Roadmap on Machine learning in electronic structure

Michele Ceriotti, Andrea Grisafi, Max David Veit, Jigyasa Nigam

In recent years, we have been witnessing a paradigm shift in computational materials science. In fact, traditional methods, mostly developed in the second half of the XXth century, are being complemented, extended, and sometimes even completely replaced by ...

IOP Publishing Ltd2022

Beam Selection and Tracking for Amplify-and-Forward Repeaters

Ruben Merz, Andreas Peter Burg, Adrian Schumacher

Mobile network operators constantly have to upgrade their cellular network to satisfy the public's hunger for increasing data capacity. However, regulatory limits regarding allowed electromagnetic field strength on existing cell sites often limit or preven ...

IEEE2022