Publications associées à Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds

Verification of the Fourier-enhanced 3D finite element Poisson solver of the gyrokinetic full-f code PICLS

Stephan Brunner, Laurent Villard, Alberto Bottino, Moahan Murugappan

We introduce and derive the Fourier -enhanced 3D electrostatic field solver of the gyrokinetic full -f PIC code PICLS. The solver makes use of a Fourier representation in one periodic direction of the domain to make the solving of the system easily paralle ...

Elsevier2024

Catalytic Enantioselective Synthesis of Inherently Chiral Macrocycles by Dynamic Kinetic Resolution

Jieping Zhu, Shuo Tong

Kinetically fast racemization of chiral substrates through an achiral intermediate and enantioselective functionalization of one of the enantiomeric substrates forms the basis of the dynamic kinetic resolution (DKR) of centrally chiral molecules. We report ...

2024

Impact of beam-coupling impedance on the Schottky spectrum of bunched beam

Tatiana Pieloni, Nicolas Frank Mounet, Christophe Emmanuel R. Lannoy

The Schottky monitors of the Large Hadron Collider (LHC) can be used for non-invasive beam diagnostics to estimate various bunch characteristics, such as tune, chromaticity, bunch profile or synchrotron frequency distribution. However, collective effects, ...

Iop Publishing Ltd2024

Nonlinear interactions of ion acoustic waves explored using fast imaging decompositions

Fast camera imaging is used to study ion acoustic waves propagating azimuthally in a magnetized plasma column. The high-speed image sequences are analyzed using proper orthogonal decomposition and 2D Fourier transform, allowing to evaluate the assets and d ...

2023

The Claude Debussy Solo Piano Corpus

Martin Alois Rohrmeier, Johannes Hentschel, Gabriele Cecchetti, Ludovica Schaerf, Sabrina Laneve

This dataset originates from the DCML corpus initiative and contains musicological research data. For more information, please refer to its documentation page https://dcmlab.github.io/debussy_piano Please cite this dataset as Laneve, S., Schaerf ...

Zenodo2023

The diachronic development of Debussy’s musical style: a corpus study with Discrete Fourier Transform

Martin Alois Rohrmeier, Johannes Hentschel, Gabriele Cecchetti, Ludovica Schaerf, Sabrina Laneve

Claude Debussy’s personal style is typically characterised as a departure from earlier diatonic tonality, including a greater variety of pitch-class materials organised in fragmented yet coherent compositions. Exploiting the music-theoretical interpretabil ...

2023

Efficient Meso-Scale Modeling of Alkali-Silica-Reaction Damage in Concrete

Ali Falsafi

The alkali-silica reaction (ASR), also known as concrete cancer, is one of the most prevalent causes of concrete degradation. In this chemical reaction, amorphous silica in the aggregates reacts with alkalis in the pore solution. By absorbing water, hydrop ...

EPFL2022

midiVERTO: A Web Application to Visualize Tonality in Real Time

Daniel Harasim, Fabian Claude Moss

This paper presents a web application for visualizing the tonality of a piece of music-the organization of its chords and scales-at a high level of abstraction and with coordinated playback. The application applies the discrete Fourier transform to the pit ...

SPRINGER INTERNATIONAL PUBLISHING AG2022

LHC Schottky Spectrum from Macro-Particle Simulations

Tatiana Pieloni, Nicolas Frank Mounet, Christophe Emmanuel R. Lannoy

We introduce a method for building Schottky spectra from macro-particle simulations performed with the PyHEADTAIL code, applied to LHC beam conditions. In this case, the use of a standard Fast Fourier Transform (FFT) algorithm to recover the spectral conte ...

JACoW Publishing2022

Phantom Curves: Scientific Discovery through Interactive Music Visualization

Daniel Harasim, Fabian Claude Moss

We introduce phantom curves, a novel music-theoretical concept based on the discrete Fourier transform (DFT), and document the creative process that led to their discovery. In particular, we emphasize the importance of interactive web applications for musi ...

ACM2022

Visible light activated BINOL-derived chiroptical switches based on boron integrated hydrazone complexes

Lukas Pfeifer

Chiral optical switches, which use light to control chirality in a reversible manner, offer unique properties and fascinating prospects in the areas of molecular switching and responsive systems, new photochromic materials and molecular data processing and ...

ROYAL SOC CHEMISTRY2022

Visible-Light-Driven Catalytic Deracemization of Secondary Alcohols

Xile Hu, Zhikun Zhang

Deracemization of racemic chiral compounds is an attractive approach in asymmetric synthesis, but its development has been hindered by energetic and kinetic challenges. Here we describe a catalytic deracemization method for secondary benzylic alcohols whic ...

Wiley-VCH Verlag GmbH2021

Schiff base ligands derived from 1,2-bis(2 '-nitro-/amino-phenoxy)-3-R-benzene and 2-hydroxy-1-naphthaldehyde and their Cu/Zn(II) complexes: synthesis, characterization, X-ray structures and computational studies

Rosario Scopelliti

1,2-Bis(2'-nitrophenoxy)-3-R-benzenes {R = H (1), CH3 (2) and OCH3 (3)} have been prepared from the S-N-Ar reaction between 1-fluoro-2-nitrobenzene and 3-R-catechol (aromatic diol), and are then reduced to the corresponding diamines 1,2-bis(2'-aminophenoxy ...

ROYAL SOC CHEMISTRY2021

Function Integration, Reconstruction And Approximation Using Rank-1 Lattices

Fabio Nobile, Giovanni Migliorati

We consider rank-1 lattices for integration and reconstruction of functions with series expansion supported on a finite index set. We explore the connection between the periodic Fourier space and the non-periodic cosine space and Chebyshev space, via tent ...

2021

Arrested phase separation in chiral fluids of colloidal spinners

Ignacio Pagonabarraga Mora

We investigate phase separation in a chiral fluid, made of spinning ferromagnetic colloids that interact both via hydrodynamic and dipolar forces and collectively organize into separated circulating clusters. We show that, at high spinning frequency, hydro ...

AMER PHYSICAL SOC2021

New Vinylation and Alkynylation Strategies with Hypervalent Iodine Reagents and Diazo Compounds

Guillaume Dominique Pisella

The development of a sequential copper-catalyzed oxy-alkynylation/intramolecular [4+2] cycloaddition of allenes and arenes was investigated at first. This one-pot protocol allowed the construction of complex polycylic architectures with high efficiency fro ...

EPFL2021

Near-Enantiopure Trimerization of 9-Ethynylphenanthrene on a Chiral Metal Surface

Harald Brune, Jan Prinz, Roland Widmer, Aliaksandr Yakutovich, Samuel Thomas Stolz

Enantioselectivity in heterogeneous catalysis strongly depends on the chirality transfer between catalyst surface and all reactants, intermediates, and the product along the reaction pathway. Herein we report the first enantioselective on-surface synthesis ...

Wiley-VCH Verlag GmbH2020

Chiral Cyclopentadienyl Ligands: Design, Syntheses, and Applications in Asymmetric Catalysis

Nicolai Cramer, Benoît Daniel Bertrand Audic, Aragorn Nathan Laverny

The creation of new chiral ligands capable of providing high stereocontrol in metal-catalyzed reactions is crucial in modern organic synthesis. The production of bioactive molecules as single enantiomers is increasingly required, and asymmetric catalysis w ...

Wiley-VCH Verlag GmbH2021

Energy-based comparison between the Fourier-Galerkin method and the finite element method

Thomas Willem Jan de Geus

The Fourier-Galerkin method (in short FFTH) has gained popularity in numerical homogenisation because it can treat problems with a huge number of degrees of freedom. Because the method incorporates the fast Fourier transform (FFT) in the linear solver, it ...

ELSEVIER2020

Fourier Sampling in Signal Processing and Numerical Linear Algebra

Amir Zandieh

This thesis focuses on developing efficient algorithmic tools for processing large datasets. In many modern data analysis tasks, the sheer volume of available datasets far outstrips our abilities to process them. This scenario commonly arises in tasks incl ...

EPFL2020