Publications associées à Borophosphonate Cages: Easily Accessible and Constitutionally Dynamic Heterocubane Scaffolds

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

EPFL2024

New Applications of 1,3,2-Diazaphospholenes in Catalysis

Johannes Klett

The constant urge to construct new molecules in an economical and sustainable fashion led to the development of numerous metal-catalyzed transformations. Organocatalysts consisting of abundant and more sustainable elements offer an elegant solution to over ...

EPFL2024

Stabilization versus competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface

Metal-porphyrins are studied intensively due their potential applications, deriving from the variety of electronic and chemical properties, tunable by selecting metal centers and functional groups. Metalation, de- and trans-metalation processes are fundame ...

Royal Soc Chemistry2024

DeepValve: Development and experimental testing of a Reinforcement Learning control framework for occupant-centric heating in offices

Dolaana Khovalyg, Amirreza Heidari

Space heating controls in offices usually follow static schedules detached from actual occupancy, which results in energy waste by unnecessarily heating vacant offices. The uniqueness of stochastic occupancy profile and thermal response time of each office ...

2023

TiCl3-Mediated Reductive Cyclization of Tetrasubstituted Alkenes and Enol Esters Bearing a 2-Nitrophenyl Substituent

Dina Boyarskaya

Indole is one of the most important heterocycles widely present in bioactive natural products, pharmaceuticals, agrochemicals and materials. Being easily accessible, the 2-nitrostyrenes are attractive starting materials for the indole synthesis and the Cad ...

EPFL2023

Nanoscale thermal control of a single living cell enabled by diamond heater-thermometer

Aleksandra Radenovic, Evgenii Glushkov

We report a new approach to controllable thermal stimulation of a single living cell and its compartments. The technique is based on the use of a single polycrystalline diamond particle containing silicon-vacancy (SiV) color centers. Due to the presence of ...

Nature Portfolio2023

Metal Catalysts for the Electrochemical Reduction of CO2

Cedric David Koolen

The world by and large has adopted the The Paris Agreement, which commits any signing party to cut greenhouse emissions drastically and prevent global heating above 2 °C beyond pre-industrial levels. For this ambitious goal to be met, ratifying states need ...

EPFL2023

Renewable Energy Integration and Waste Heat Recovery for the Production of Sustainable Jet Fuel and Decarbonization of Industrial Heating Applications

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos, Réginald Germanier

The process synthesis and optimization methods used in this work include simulation of biomass gasification, hydrogen and synthetic natural gas production, and jet fuel production via a Fisher Tropsch unit. An energy integration approach, carried out by th ...

American Institute of Chemical Engineering2023

Scalable Room-Temperature Synthesis of a Hydrogen-Sieving Zeolitic Membrane on a Polymeric Support

Kumar Varoon Agrawal, Mostapha Dakhchoune, Jian Hao, Xuekui Duan

Thescalable synthesis of high-temperature H-2-sieving membranesfor energy-efficient carbon capture can potentiallyenable the implementation of precombustion carbon capture at a rapidpace. ...

AMER CHEMICAL SOC2023

Understanding the growth mechanism of BaZrS3 chalcogenide perovskite thin films from sulfurized oxide precursors

Anna Fontcuberta i Morral, Elias Zsolt Stutz, Andrea Giunto, Santhanu Panikar Ramanandan, Iléane Tiphaine Françoise Marie Lefevre, Mirjana Dimitrievska

Barium zirconium sulfide (BaZrS3) is an earth-abundant and environmentally friendly chalcogenide perovskite with promising properties for various energy conversion applications. Recently, sulfurization of oxide precursors has been suggested as a viable sol ...

IOP Publishing Ltd2023

Local heating and cooling effectiveness - an evaluation method based on calculated local and overall thermal state

Dolaana Khovalyg, Mohamad Rida

The application of Personal Comfort Systems (PCS) in the buildings demonstrated their potential to improve thermal comfort and reduce energy use by the space conditioning HVAC systems. With its personal controllability (on-demand) PCS is a practical soluti ...

TU Delft2022

Customized Neural Network training to predict the highly imbalanced data of domestic hot water usage

Dolaana Khovalyg, Amirreza Heidari

Despite space heating and cooling, the energy use for hot water production has not changed significantly over time and accounts for a big share in modern, well-insulated buildings. The main challenge of hot water generation lies in the highly stochastic na ...

CLIMA 2022 conference2022

Organic Chemistry and Synthesis Rely More and More upon Catalysts

Pierre Vogel

A few months before the COVID-19 pandemic, Pierre Vogel and Kendall N. Houk published with a new textbook Wiley-VCH, "Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis", with a foreword from the late Roberts H. Grubbs. The book demo ...

MDPI2022

Upgrade of the neutral beam heating system on the TCV tokamak - second high energy neutral beam

Basil Duval, Damien Fasel, Ambrogio Fasoli, Pierre Lavanchy, Blaise Marlétaz, Yves Martin, Holger Reimerdes, Stefano Coda, Ugo Siravo, Alexander Karpushov, Jérémie Dubray, Frédéric Dolizy, Rémy Jacquier, Matthieu Toussaint, Umar Sheikh, Marcelo Baquero Ruiz, Filippo Bagnato, Lorenzo Martinelli, Matteo Vallar, Claudia Colandrea, Dmytry Mykytchuk, Jesús Poley Sanjuán

The TCV tokamak continues to leverage its unique shaping capabilities, flexible heating systems and modern control system to provide a stepladder approach for extrapolations of experimental results from different ma-chines to ITER and DEMO. TCV's configura ...

ELSEVIER SCIENCE SA2022

Disentangling Light- and Temperature-Induced Thermal Effects in Colloidal Au Nanoparticles

Majed Chergui, Lijie Wang, Davood Zare

We present temperature-dependent (from room temperature to 80 degrees C) absorption spectra of Au/SiO2 core-shell nanoparticles (NPs) (core diameter: similar to 25 nm) in water in the range from 1.5 to 4.5 eV, which spans the localized surface plasmon reso ...

AMER CHEMICAL SOC2022

High-Temperature HEMT Mode

Farzan Jazaeri, Nika Sahebghalam

Taking into account the impact of self-heating and temperature rise effects, this work presents a physics-based analytical model for HEMTs, operating continuously from room temperature to high temperatures in linear and saturation regimes. Relying on the c ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Towards multifunctional building elements: thermal activation of a composite interior GFRP slab

Thomas Keller, Madeline Pugin, Dolaana Khovalyg

Modular multifunctional building elements can overcome major disadvantages of the traditional sequential design and become prospective design solutions for sustainable construction. Thus, this work explores lightweight glass fiber-reinforced polymer (GFRP) ...

IOP Science2021

Influence of Joule Effect Heating on Recrystallization Phenomena in Inconel 718

Mathijs Pieter van der Meer, Roland Logé

In this article, the Joule effect heating influence on recrystallization phenomena in the Inconel 718 nickel-based superalloy is investigated in details. On the one hand, static recrystallization kinetic studies at 1020 degrees C after cold deformation up ...

SPRINGER2021

Designing compliant mechanisms composed of shape memory alloy and actuated by induction heating

Paolo Germano, Yves Perriard, Sean Thomas, Adrien Jean-Michel Thabuis, Thomas Guillaume Martinez

Shape Memory Alloys (SMAs) are a type of smart materials that reacts mechanically to heat. Due to their complex behavior, they are often used in a simple geometry such as wires. This constrains the output displacement of the alloy to a simple linear contra ...

2021

Half-clathrochelate Complexes as Versatile Links in Supramolecular Chemistry

Erica Giraldi

Clathrochelate complexes have been widely investigated with different size and shape and used as building blocks for the obtainment of discrete supramolecular architectures. These clathrochelate complexes are very stable and kinetically inert complexes. A ...

EPFL2021