Publications associées à Maldi device and methods of preparation and use thereof

Temperature, humidity, and ionisation effect of iodine oxoacid nucleation

Andrea Baccarini, Lubna Dada, Houssni Lamkaddam, Imad El Haddad

Iodine oxoacids are recognised for their significant contribution to the formation of new particles in marine and polar atmospheres. Nevertheless, to incorporate the iodine oxoacid nucleation mechanism into global simulations, it is essential to comprehend ...

Royal Soc Chemistry2024

CEERS: Diversity of Lyα Emitters during the Epoch of Reionization

Michaela Hirschmann

We analyze rest-frame ultraviolet to optical spectra of three z similar or equal to 7.47-7.75 galaxies whose Ly alpha emission lines were previously detected with Keck/MOSFIRE observations, using the JWST/NIRSpec observations from the Cosmic Evolution Earl ...

Iop Publishing Ltd2024

Positive Streamer Initiation in SF6/CO2 Based on Zener's Field Ionization

Guang-Yu Sun

In this study, experiments were performed to measure the inception and breakdown voltages of SF6/CO2 mixed gases with varying mixing ratios at two different pressures (1 and 2 bar). Using the preliminary data obtained from the experiments, a 3D particle mo ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2023

High-frequency gaseous and particulate chemical characterization using extractive electrospray ionization mass spectrometry (Dual-Phase-EESI-TOF)

Andrea Baccarini, Houssni Lamkaddam, Imad El Haddad, Mihnea Surdu

To elucidate the sources and chemical reaction pathways of organic vapors and particulate matter in the ambient atmosphere, real-time detection of both the gas and particle phase is needed. State-of-the-art techniques often suffer from thermal decompositio ...

COPERNICUS GESELLSCHAFT MBH2022

Standard-Free Quantification of Dicarboxylic Acids: Case Studies with Salt-Rich Effluents and Serum

Christian Ludwig, Daniil Salionov, Sasa Bjelic

The present study evaluates the ionization efficiency (IE) of linear and branched C2–C14 dicarboxylic acids (DCAs) by electrospray ionization (ESI) under different conditions. The influence of the concentration of organic modifier (MeOH); mobile phase addi ...

2022

High-useful yield and new autoionizing state of resonantly ionized tungsten

Reto Georg Trappitsch

In order to measure tungsten isotopic composition in presolar stardust grains that contain a limited number of atoms, we developed a new three-photon three-color resonance ionization scheme using titanium:sapphire lasers and the Laser Ionization of Neutral ...

ROYAL SOC CHEMISTRY2022

Fragment ion-functional group relationships in organic aerosols using aerosol mass spectrometry and mid-infrared spectroscopy

Satoshi Takahama, Nikunj Dudani, Amir Yazdani, Imad El Haddad

Aerosol mass spectrometry (AMS) and mid-infrared spectroscopy (MIR) are two analytical methods for characterizing the chemical composition of OM. While AMS provides high-temporal-resolution bulk measurements, the extensive fragmentation during the electron ...

2022

Charging and ion ejection dynamics of large helium nanodroplets exposed to intense femtosecond soft X-ray pulses

Daniela Rupp, Camila Bacellar Cases Da Silveira, Christoph Bostedt

Ion ejection from charged helium nanodroplets exposed to intense femtosecond soft X-ray pulses is studied by single-pulse ion time-of-flight (TOF) spectroscopy in coincidence with small-angle X-ray scattering. Scattering images encode the droplet size and ...

SPRINGER HEIDELBERG2021

Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation

Yandong Tong, Julia Schmale, Imad El Haddad

Online characterization of aerosol composition at the near-molecular level is key to understanding chemical reaction mechanisms, kinetics, and sources under various atmospheric conditions. The recently developed extractive electrospray ionization time-of-f ...

2021

Investigation of the density shoulder formation by using self-consistent simulations of plasma turbulence and neutral kinetic dynamics

Paolo Ricci, Nicola Vianello, Maurizio Giacomin, Davide Mancini

Simulations of plasma turbulence in a lower single-null magnetic configurations are presented. The plasma dynamics is modelled by the drift-reduced two-fluid Braginskii equations that are coupled with a kinetic model for a single neutral species that consi ...

IOP Publishing Ltd2021

The operational space for divertor power exhaust in DEMO with a super-X divertor

Holger Reimerdes, Marco Wischmeier, Mirko Wensing

SOLPS-ITER simulations of the European DEMO reactor with a Super-X divertor, which has larger major radius at the outer target and increased connection length, show an increased operational space for divertor power exhaust compared to the conventional sing ...

IOP Publishing Ltd2021

A gas phase approach for glycan analysis: Combining ultrahigh-resolution ion mobility spectrometry with cryogenic vibrational spectroscopy

Ahmed Ben Faleh

The last decades have been punctuated by the development of revolutionary analytical technologies that have enabled the analysis of biomolecular structures and unraveled the roles they play in biological systems. However, certain classes of biomolecules re ...

EPFL2021

Analyzing glycans cleaved from a biotherapeutic protein using a combination of ion mobility spectrometry and cryogenic ion spectroscopy

Natalia Yalovenko

The characterization of biomolecules plays a central role in biomedical research. The development of state-of-the-art technologies is needed to make such analyses faster, more sensitive, and more accurate. While mass spectrometry continues to play a centra ...

EPFL2021

Unveiling the role of dielectric trap states on capacitively coupled radio-frequency plasma discharge: dynamic charging behaviors

Arnas Volcokas, Guang-Yu Sun

The influence of charge trap states in the dielectric boundary material on capacitively coupled radio-frequency (RF) plasma discharge is investigated with theory and particle-in-cell/Monte Carlo collision simulation. It is found that the trap states of the ...

2021

LC-APCI(-)-MS Determination of 1-Chloro-2,4-dinitrobenzene, a Model Substrate for Glutathione S-Transferases

Kristin Schirmer, Alena Tierbach

1-Chloro-2,4-dinitrobenzene (CDNB) is widely used as a model substrate for measuring the enzyme activity of glutathione S-transferases in toxicity studies and in studies focusing on the metabolic capacity of different test systems. To allow the quantificat ...

AMER CHEMICAL SOC2020

Innovative Lab on Fiber dosimeters for ionizing radiation monitoring at ultra-high doses

Georgi Gorine, Federico Ravotti

We report on a innovative Lab on Fiber (LOF) dosimeter for ionizing radiation monitoring at ultra-high doses. The new dosimeter consists in a metallo-dielectric resonator at sub-wavelength scale supporting localized surface plasmon resonances realized on t ...

SPIE-INT SOC OPTICAL ENGINEERING2019

A rubidium vapor source for a plasma source for AWAKE

Gennady Plyushchev

We present the scheme for a rubidium vapor source that is used as a plasma source in the AWAKE plasma wakefield acceleration experiment. The plasma wakefield acceleration process requires a number of stringent parameters for the plasma: electron density ad ...

2018

Modelling of the neutron production in a mixed beam DT neutron generator

Patrick Blanchard, Basil Duval, Ambrogio Fasoli, Yves Martin, Richard Pitts, Olivier Sauter, Henri Weisen, Robin Humphry-Baker, Stefano Coda, Martinus Gijs, Partha Dutta, Marco Wischmeier, Jan Horacek, Vlad Trifa, Yann Camenen, Jonathan Graves, Duccio Testa, Miguel Fernández Ruiz, Sun Hee Kim, Mikhail Maslov, Javier García Hernández, David Pfefferlé, José Pedro Rebelo Ferreira Marques, Julio Rodriguez, Pedro Camilo de Oliveira e Silva, Rebecca Hill, Daniel Scott Alessi, Jonnathan Cesar Hidalgo Acosta, Ana Francisca Leal Silva Soares, Dalziel Joseph Wilson, Pierre-Thomas Paul Brun, Jonathan Marc Philippe Faustin, Federico Nespoli, Alberto Hernando de Castro, Hamish William Patten, Bruno Emanuel Ferreira De Sousa Correia, Li Shuai, Nicola Vianello, Antonio José Pereira de Figueiredo, , , , , , , , ,

New ionization and tagging methods for mass spectrometry

Xiaoqin Zhong

Mass spectrometry (MS) is an essential detection tool in bioanalytical chemistry owing to its exceptional selectivity and sensitivity, paired with rapid analyte identification and quantification. In this thesis, two classical MS and a newly developed ioniz ...

EPFL2017

A High Space Density of Luminous Ly alpha Emitters at z similar to 6.5

Hakim Atek, Patrick Mccarthy

We present the results of a systematic search for Ly alpha emitters (LAEs) at 6 less than or similar to z less than or similar to 7.6 using the HST WFC3 Infrared Spectroscopic Parallel (WISP) Survey. Our total volume over this redshift range is similar to ...

Iop Publishing Ltd2017