Publications associées à An Enantioselective Total Synthesis of (−)-Isoschizogamine

Data-driven Methods for Control: from Linear to Lifting

The progress towards intelligent systems and digitalization relies heavily on the use of automation technology. However, the growing diversity of control objects presents significant challenges for traditional control approaches, as they are highly depende ...

EPFL2023

Data-driven and Safe Networked Control with Applications to Microgrids

Mustafa Sahin Turan

Today, automatic control is integrated into a wide spectrum of real-world systems such as electrical grids and transportation networks. Many of these systems comprise numerous interconnected agents, perform safety-critical operations, or generate large amo ...

EPFL2022

A combined Control by Interconnection—Model Predictive Control design for constrained Port-Hamiltonian systems

Anna Ngoc Minh Trang Vu

This paper proposes a Control by Interconnection design, for a class of constrained Port-Hamiltonian systems, which is based on an associated Model Predictive Control optimization problem. This associated optimization problem allows to consider both state ...

2022

Whole Body Model Predictive Control with a Memory of Motion: Experiments on a Torque-Controlled Talos

Sylvain Calinon, Rohan Budhiraja, Teguh Santoso Lembono

This paper presents the first successful experiment implementing whole-body model predictive control with state feedback on a torque-control humanoid robot. We demonstrate that our control scheme is able to do whole-body target tracking, control the balanc ...

IEEE2021

Asymmetric (CpRh)-Rh-x(III)-Catalyzed Acrylic Acid C-H Functionalization with Allenes Provides Chiral gamma-Lactones

Nicolai Cramer, Shouguo Wang

A chiral cyclopentadienyl (Cp-x) ligand featuring the semi-saturated H8-binaphthyl backbone as the chiral element was developed. Its application potential was demonstrated by (CpRhIII)-Rh-x-catalyzed C-H bond functionalization of acryl acids and allenes, e ...

AMER CHEMICAL SOC2020

Data driven model free adaptive iterative learning perimeter control for large-scale urban road networks

Nikolaos Geroliminis, Isik Ilber Sirmatel, Ye Ren

Most perimeter control methods in literature are the model-based schemes designing the controller based on the available accurate macroscopic fundamental diagram (MFD) function with well known techniques of modern control methods. However, accurate modelin ...

2020

Security-aware Routing and Scheduling for Control Applications on Ethernet TSN Networks

Amir Aminifar

Today, it is common knowledge in the cyber-physical systems domain that the tight interaction between the cyber and physical elements provides the possibility of substantially improving the performance of these systems that is otherwise impossible. On the ...

ASSOC COMPUTING MACHINERY2020

Shape and size control of colloidal CdSe nanocrystals in the presence of carboxylate and alkylamine ligands

Xiaopeng Huang

In this thesis, we focus on investigating the shape and size evolution of colloidal CdSe nanomaterials in the presence of carboxylate and alkylamine surface ligands. By elaborating the combination of carboxylates and alkylamines with different hydrocarbon ...

EPFL2019

Model-based predictive control methods for distributed energy resources in smart grids

Luca Fabietti

This thesis develops optimization-based techniques for the control of distributed energy resources to provide multiple services to the power network. It is divided into three parts. The first part of this thesis focuses on the development of a framework f ...

EPFL2019

Organocatalysts in C-N Bond Forming Reactions of Amines with CO2

Martin Hulla

The thesis describes a simple approach for N-formylation of amines with CO2 and hydrosilane reducing agents, the use of organic salts as N-formylation catalysts, their physical properties required for high catalytic activity and their role in the catalytic ...

EPFL2019

Low-Complexity Optimization-Based Control: Design, Methods and Applications

Ivan Pejcic

Optimization-based controllers are advanced control systems whose mechanism of determining control inputs requires the solution of a mathematical optimization problem. In this thesis, several contributions related to the computational effort required for o ...

EPFL2019

Indole Alkaloids, Macrocycles and Heterocycles : Interplay between Methodological Development and Total Synthesis

Cyril Piemontesi

An enantioselective total synthesis of (-)-terengganensine A, a heptacyclic monoterpene indole alkaloid, was performed. A short sequence allowed to obtain the enantio-enriched target in good overall yield. The synthesis featured a key asymmetric transfer h ...

EPFL2018

A Data-Driven Frequency-Domain Approach for Robust Controller Design via Convex Optimization

Achille Nicoletti

The objective of this dissertation is to develop data-driven frequency-domain methods for designing robust controllers through the use of convex optimization algorithms. Many of today's industrial processes are becoming more complex, and modeling accurate ...

EPFL2018

Dearomatization of electron poor six-membered N-heterocycles through [3+2] annulation with aminocyclopropanes

Jérôme Waser, Shyamal Chakrabarty, Johannes Preindl

Many abundant and highly bioactive natural alkaloids contain an indolizidine skeleton. A simple, high yielding method to synthesize this scaffold from N-heterocycles was developed. A wide range of pyridines, quinolines and isoquinolines reacted with donor- ...

2017

Predictive Control of Buildings for Demand Response and Ancillary Services Provision

Faran Ahmed Qureshi

This thesis develops optimization based techniques for the control of building heating, ventilation, and air-conditioning (HVAC) systems for the provision of demand response and ancillary services to the electric grid. The first part of the thesis focuses ...

EPFL2017

In Situ Tethering Strategies for the 3-Component Synthesis of Vicinal Amino Alcohols and Diamines via Pd-Catalyzed Carboetherification and Carboamination

Ugo Jonathan Orcel

Vicinal amino alcohols and diamines are privileged motifs in organic chemistry. As such, they have been targets of choice for exploring and developing novel and more efficient strategies in organic synthesis. In this context, the difunctionalization of ole ...

EPFL2017

Enantioselective Total Synthesis of (−)-Terengganensine A

Cyril Piemontesi, Qian Wang, Jieping Zhu

A seven-step enantioselective total synthesis of (-)-terengganensine A, a complex heptacyclic monoterpene indole alkaloid, was accomplished. Key steps included: a) Noyori's catalytic enantioselective transfer hydrogenation of the iminium salt to set up the ...

Wiley-Blackwell2016

Reliable and Real-Time Distributed Abstractions

David Kozhaya

The celebrated distributed computing approach for building systems and services using multiple machines continues to expand to new domains. Computation devices nowadays have additional sensing and communication capabilities, while becoming, at the same tim ...

EPFL2016

Control of Reaction Systems via Rate Estimation and Feedback Linearization

Dominique Bonvin, Julien Léo Billeter, Diogo Filipe Mateus Rodrigues

Abstract of the conference paper The kinetic identification of chemical reaction systems often represents a time-consuming and complex task. This contribution presents an approach that uses rate estimation and feedback linearization to implement ...

Elsevier2015

Closed-loop magnetic bearing and angular velocity control of a reaction sphere actuator

Yves Perriard, Leopoldo Rossini

This article presents the first closed-loop magnetic bearing and angular velocity experimental results of a reaction sphere actuator for satellite attitude control. The proposed reaction sphere is a permanent magnet spherical actuator whose rotor is suppor ...

Pergamon-Elsevier Science Ltd2015