Publications associées à Manganese Oxidation Induced by Water Table Fluctuations in a Sand Column

Nature-based solution enhances resilience to flooding and catalyzes multi-benefits in coastal cities in the Global South

Jérôme Chenal, Paolo Perona, Charlotte Grossiord, Montana Marshall, Emmanuel Qays Dubois

Coastal cities are facing a rise in groundwater levels induced by sea level rise, further triggering saturation excess flooding where groundwater levels reach the topographic surface or reduce the storage capacity of the soil, thus stressing the existing i ...

2024

Contribution of standardized indexes to understand groundwater level fluctuations in response to meteorological conditions in cold and humid climates

Emmanuel Qays Dubois

Understanding the fluctuations in groundwater levels in response to meteorological conditions is challenging, especially given the slow transit time associated with groundwater reservoirs and the short duration of time series for groundwater levels. Nevert ...

2024

Microstructure - Electrochemical Surface Reactivity Relationship of Electrochemically Grown Manganese Oxides Films

Roberto Cestaro

This Thesis provides a comprehensive and correlative investigation of the microstructure, chemical state, and electrochemical reactivity of manganese oxide (MnOx) films, aiming to gain a deeper understanding of the deposition and dissolution mechanism of M ...

EPFL2024

Data-driven statistical optimization of a groundwater monitoring network

Andrea Rinaldo, Gianluca Botter

We propose a comparative study of three different methods aimed at optimizing existing groundwater monitoring networks. Monitoring piezometric heads in subsurface porous formations is crucial at regional scales to properly characterize the relevant subsurf ...

Elsevier2024

Watertable fluctuations in coastal unconfined aquifers with a sloping sea boundary: Vertical flow and dynamic effective porosity effects

David Andrew Barry, Zhaoyang Luo

Interactions between the tide and sloping sea boundary make watertable fluctuations in coastal unconfined aquifers complicated. Based on a perturbation method, we derived a new analytical solution to predict watertable fluctuations for coastal unconfined a ...

2023

Oxidative Water Treatment: The Track Ahead

Urs von Gunten, Yun Ho Lee

Chemical oxidation has been applied in municipal water treatment for more than a century, initially for disinfection. In the early decades, chlorine disinfection was adopted in the fight against waterborne disease. However, the oxidative properties of chlo ...

2023

Mechanistic insights on interactions of dissolved organic matter with chemical oxidants: quantification of reactive sites and identification of oxidation byproducts

Joanna Maria Houska

Chemical oxidants including ozone (O3), chlorine (HOCl/OCl-) and chlorine dioxide (ClO2) are applied for disinfection of drinking water. To cope with water scarcity and the increased risks associated with the presence of micropollutants, water treatment sy ...

EPFL2023

Effects of Unsaturated Flow on Salt Distributions in Tidally Influenced Coastal Unconfined Aquifers

David Andrew Barry, Zhaoyang Luo

Unsaturated flow influences both the seawater extent under steady-state conditions and the propagation of tides in coastal aquifers. However, its effects on salt distributions in tidally influenced coastal aquifers are little investigated. The present stud ...

2023

Bacterial inactivation in sunlit surface waters is dominated by reactive species that emanate from the synergy between light, iron, and natural organic matter

César Pulgarin, Stefanos Giannakis, Jun Ma, Da Wang, Shuang Song

In this study, the synergistic and antagonistic effects of Fe species and coexisting natural organic matter (NOM) on the efficacy of solar light disinfection of water are investigated. Different initial iron species (Fe2+/Fe3+) and naturalorganic matter ty ...

Elsevier2023

Operando identification of a side-on nickel superoxide intermediate and the mechanism of oxygen evolution on nickel oxyhydroxide

Xile Hu, Lichen Bai, Seunghwa Lee

The oxygen evolution reaction (OER) is a key electrochemical reac-tion relevant to energy storage. Ni-containing bimetallic oxyhydrox-ides are among the most active OER catalysts in alkaline medium, but the mechanism of OER on pure Ni oxyhydroxide remains ...

ELSEVIER2023

Impacts of climate change on Swiss alluvial aquifers - A quantitative forecast focused on natural and artificial groundwater recharge by surface water infiltration

Carl Love Mikael Råman Vinnå, Sebastiano Piccolroaz

The sensitivity of future groundwater recharge and temperature development was investigated for three alluvial aquifers in the urban agglomeration of the city of Basel, Switzerland. For selected climate projections groundwater recharge and the associated t ...

ELSEVIER2022

Comment on “Groundwater Affects the Geomorphic and Hydrologic Properties of Coevolved Landscapes” by Litwin et al

Shashank Kumar Anand, Sara Bonetti

The objective of this comment is to correct two sets of statements in Litwin et al. (2022, https://doi.org/10.1029/2021JF006239), which consider our research work (Bonetti et al., 2018, https://doi.org/10.1098/rspa.2017.0693; Bonetti et al., 2020, https:// ...

2022

Applying the Principal Component Analysis for a deeper understanding of the groundwater system: case study of the Bacchiglione Basin (Veneto, Italy)

Andrea Rinaldo

In hydrogeology, it is often difficult to fully understand the hydraulic factors affecting the recharge of groundwater systems. Particularly, at a regional scale, the groundwater system can have different drivers depending on the considered area, i.e., soi ...

PAGEPRESS PUBL2022

Dynamic Effective Porosity Explains Laboratory Experiments on Watertable Fluctuations in Coastal Unconfined Aquifers

David Andrew Barry, Zhaoyang Luo

Watertable fluctuations are a characteristic feature of coastal unconfined aquifers. They interact with the vadose zone creating a dynamic effective porosity, for which a new (empirical) expression is proposed based on a dimensionless parameter related to ...

2023

Approximate analytical solutions for assessing the effects of unsaturated flow on seawater extent in thin unconfined coastal aquifers

David Andrew Barry, Zhaoyang Luo

This study develops approximate analytical solutions for seawater extent in unconfined coastal aquifers considering unsaturated flow, and assuming steady-state, sharp-interface conditions, for both constant flux (flux-controlled aquifers) and constant head ...

2022

Synthesizing the impacts of baseflow contribution on concentration-discharge (C-Q) relationships across Australia using a Bayesian hierarchical model

Camille Roland Marie Minaudo

Understanding concentration-discharge (C - Q) relationships can inform catchment solute and particulate export processes. Previous studies have shown that the extent to which baseflow contributes to streamflow can affect C-Q relationships in some catchment ...

COPERNICUS GESELLSCHAFT MBH2022

Reactions of amines with ozone and chlorine: Two novel oxidative methods to evaluate the N-DBP formation potential from dissolved organic nitrogen

Karim-Alexandre Essaied, Urs von Gunten, Lucy Victoria Brown

The composition of oxidant-reactive dissolved organic nitrogen (DON) is poorly characterized, although its ozonation is likely to form a great variety of disinfection by-products containing a nitrogen-oxygen bond (NDBPs). In this study, two chemical oxidat ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Climate change effects on groundwater recharge and temperatures in Swiss alluvial aquifers

Adrien Michel

Climate change will have both quantitative and qualitative effects on groundwater resources. These impacts differ for aquifers in solid and unconsolidated rock, in urban or rural locations, and in the principal processes of groundwater recharge. Having kno ...

2021

Permanganate Reduction by Hydrogen Peroxide: Formation of Reactive Manganese Species and Superoxide and Enhanced Micropollutant Abatement

Urs von Gunten, Ke Xu

Permanganate (MnO4-, Mn(VII)) is widely applied at the initial stage of water treatment to, e.g., abate taste and odor compounds, Mn(II) and Fe(II). However, its selectivity limits its application for micropollutant abatement. Hydrogen peroxide (H2O2), whi ...

AMER CHEMICAL SOC2021

Missing water from the Qiangtang Basin on the Tibetan Plateau

David Andrew Barry, Tao Wang, Jiaqi Chen

The Qiangtang Basin is a large endorheic basin in the inner part of the Tibetan Plateau and has been thought to be a dry region in contrast with its wet surrounding outer region that feeds all the major Asian rivers. Combining surface hydrological data wit ...

2021