Publications associées à Data Reconciliation for Reaction Systems Using Extents and Shape Constraints

Global existence for perturbations of the 2D stochastic Navier-Stokes equations with space-time white noise

We prove global in time well-posedness for perturbations of the 2D stochastic Navier-Stokes equations partial derivative( t)u + u center dot del u = Delta u - del p + sigma + xi, u(0, center dot ) = u(0),div (u) = 0, driven by additive space-time white noi ...

Springernature2024

Exploiting the Signal-Leak Bias in Diffusion Models

Sabine Süsstrunk, Radhakrishna Achanta, Mahmut Sami Arpa, Athanasios Fitsios, Martin Nicolas Everaert

There is a bias in the inference pipeline of most diffusion models. This bias arises from a signal leak whose distribution deviates from the noise distribution, creating a discrepancy between training and inference processes. We demonstrate that this signa ...

2024

Setting priorities in CNF particle size measurement: What is needed vs. what is feasible

Tiffany Abitbol

Measuring the size of cellulose nanomaterials can be challenging, especially in the case of branched and entangled cellulose nanofibrils (CNFs). The International Organization for Standardization, Technical Committee 6, Task Group 1-Cellulosic Nanomaterial ...

TECH ASSOC PULP PAPER IND INC2023

Disentangling 1/f noise from confined ion dynamics

Théo Denis Tobias Emmerich

Ion transport through biological and solid-state nanochannels is known to be a highly noisy process. The power spectrum of current fluctuations is empirically known to scale like the inverse of frequency, following the long-standing yet poorly understood H ...

ROYAL SOC CHEMISTRY2023

A holistic investigation of photocatalytic hydrogen generation

Sangram Ashok Savant

Photocatalytic (PC) solar hydrogen production is a promising way to provide green hydrogen using only sunlight and abundant reactants such as water. PC approaches use catalytically active semiconductor particles suspended in liquid electrolytes. The partic ...

EPFL2023

Optimal digital filter selection for remote photoplethysmography (rPPG) signal conditioning

Ata Jedari Golparvar

Remote photoplethysmography (rPPG) using camera-based imaging has shown excellent potential recently in vital signs monitoring due to its contactless nature. However, the optimum filter selection for pre-processing rPPG data in signal conditioning is still ...

IOP Publishing Ltd2023

Synthesis and Applications of Ynimines and Enantioselective Total Synthesis of Artatrovirenol A

Rémi Hugo Lavernhe

The first chapter of this thesis describe the development of a general synthesis of ynimines, an under-exploited motif in organic chemistry. In the presence of an inexpensive copper catalyst and 2,2'-biquinoline, reaction of easily accessible O-acyloximes ...

EPFL2023

Flowing Gas Experiments Reveal Mechanistic Details of Interfacial Reactions on a Molecular Level at Knudsen Flow Conditions

Michel Rossi, Christian Ludwig, Riccardo Iannarelli

Knudsen flow experiments and its interpretation in terms of adsorption/desorption kinetics as well as quantitative uptake on substrates of interest is presented together with the description of critical design parameters of the Knudsen Flow Reactor (KFR). ...

2022

Cross verified independent measurements of correlated bubble property distributions as part of the scale-up of a catalytic bubbling fluidized bed reactor

Philipp Fedor Riechmann

Methanation can be applied as part of a Power-to-Gas (PtG) concept to store renewable electricity. Using a catalytic bubbling fluidized bed (BFB) methanation reactor allows a flexible and economic operation. Properties of bubbles rising through the fluidiz ...

EPFL2022

A Cryo-CMOS Oscillator With an Automatic Common-Mode Resonance Calibration for Quantum Computing Applications

Edoardo Charbon, Fabio Sebastiano, Yue Chen

This article presents a 4-to-5 GHz LC oscillator operating at 4.2K for quantum computing applications. The phase noise (PN) specification of the oscillator is derived based on the control fidelity for a single-qubit operation. To reveal the substantial gap ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Analytical prediction of the final error due to noise in a ϕ-OTDR system

Luc Thévenaz, Li Zhang, Malak Mohamed Hossameldeen Omar Mohamed Galal, Suneetha Sebastian, Yuting Yang

An analytical expression to estimate the uncertainty on the frequency shift in ϕ-OTDR systems is established and confirmed by actual data. ...

Optica Publishing Group2022

(4+3) Annulation of Donor-Acceptor Cyclopropanes and Azadienes: Highly Stereoselective Synthesis of Azepanones

Jérôme Waser, Stefano Nicolai

Azepanes are important seven-membered heterocycles, which are present in numerous natural and synthetic compounds. However, the development of convergent synthetic methods to access them remains challenging. Herein, we report the Lewis acid catalyzed (4+3) ...

Wiley-VCH Verlag GmbH2022

The influence of sulfate addition on hydration kinetics and C-S-H morphology of C3S and C3S/C(3)A systems

Karen Scrivener, Franco Alberto Zunino Sommariva

A comprehensive understanding of hydration kinetics, sulfate requirement and phase assemblage of Portland cement is crucial for further optimization of early-age performance, especially when part of cement is replaced by mineral additions in blended cement ...

Pergamon-Elsevier Science Ltd2022

Score Matching Enables Causal Discovery of Nonlinear Additive Noise Models

Volkan Cevher, Paul Thierry Yves Rolland

This paper demonstrates how to recover causal graphs from the score of the data distribution in non-linear additive (Gaussian) noise models. Using score matching algorithms as a building block, we show how to design a new generation of scalable causal disc ...

JMLR-JOURNAL MACHINE LEARNING RESEARCH2022

Assessment of the Bundle SNSPD Plus FPGA-Based TDC for High-Performance Time Measurements

Christophe Marcel Georges Galland, Andrea Costa, Santiago Tarrago Velez

Counting single photons and measuring their arrival time is of crucial importance for imaging and quantum applications that use single photons to outperform classical techniques. The investigation of the coincidence, i.e. correlation, between photons can b ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Enhanced Solar-to-Fuel Efficiency of Ceria-Based Thermochemical Cycles via Integrated Electrochemical Oxygen Pumping

Sophia Haussener, Meng Lin, Clemens Gregor Suter

The solar thermochemical cycle based on ceria is a promising route for renewable fuel production. The solar-to-fuel efficiency of a thermochemical reactor is highly dependent on the oxygen removal during the reduction step. Conventional nitrogen sweeping ( ...

AMER CHEMICAL SOC2022

An Efficient Signal-to-noise Approximation for Eccentric Inspiraling Binaries

Alexandra Shelest

Eccentricity has emerged as a potentially useful tool for helping to identify the origin of black hole mergers. However, eccentric templates can be computationally very expensive owing to the large number of harmonics, making statistical analyses to distin ...

IOP Publishing Ltd2022

PoGaIN: Poisson-Gaussian Image Noise Modeling From Paired Samples

Sabine Süsstrunk, Majed El Helou, Kaan Okumus

Image noise can often be accurately fitted to a Poisson-Gaussian distribution. However, estimating the distribution parameters from a noisy image only is a challenging task. Here, we study the case when paired noisy and noise-free samples are accessible. N ...

IEEE Institute of Electrical and Electronics Engineers2022

A Comparison of optimal measurement-system design with engineering judgement for bridge load testing

Ian Smith, Numa Joy Bertola

Due to conservative approaches in construction design and practice, infrastructure often has hidden reserve capacity. When quantified, this reserve has potential to improve decisions related to asset management. Field measurements, collected through load t ...

2021

Hydrogen production on demand by redox-mediated electrocatalysis: A kinetic study

Hubert Girault, Sunny Isaïe Maye, Danick Reynard

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety, membrane degradation, purity and flexibility. Herein, vanadium-mediated hydrogen ...

ELSEVIER SCIENCE SA2021