Publications associées à Enzyme and Acid Deconjugation of Plasma Sulfated Metanephrines

Contradict mechanism of long-term magnesium and sodium sulfate attacks of nano silica-modified cement mortars - Experimental and thermodynamic modeling

The mechanisms of external sulfate attack on cement mortars containing nano silica have been studied under full immersion conditions after 3 years. The sulfate degradation processes were compared between sodium sulfate and magnesium sulfate solutions with ...

Elsevier Sci Ltd2024

A customized MOF-polymer composite for rapid gold extraction from water matrices

Daniel Teav Sun, Wendy Lee Queen, Li Peng, Olga Syzgantseva, Shuliang Yang, Jun Li

With the fast-growing accumulation of electronic waste and rising demand for rare metals, it is compelling to develop technologies that can promotionally recover targeted metals, like gold, from waste, a process referred to as urban mining. Thus, there is ...

AMER ASSOC ADVANCEMENT SCIENCE2023

Separable Brønsted acidic imidazolium salts for polysaccharide hydrolysis in water

Kedar Ashok Abhyankar

The current reliance on limited petrochemical resources and the resulting ecological outcomes have made the exploration of alternative chemical and energy feedstocks invaluable. As such, the development of sustainable processes with a less harmful total en ...

EPFL2023

Ultimate Limit for Optical Losses in Gold, Revealed by Quantitative Near-Field Microscopy

Sergejs Boroviks

We report thorough measurements of surface plasmon polaritons (SPPs) running along nearly perfect air-gold interfaces formed by atomically flat surfaces of chemically synthesized gold monocrystals. By means of amplitude-and phase-resolved near-field micros ...

AMER CHEMICAL SOC2022

Standard-Free Quantification of Dicarboxylic Acids: Case Studies with Salt-Rich Effluents and Serum

Christian Ludwig, Daniil Salionov, Sasa Bjelic

The present study evaluates the ionization efficiency (IE) of linear and branched C2–C14 dicarboxylic acids (DCAs) by electrospray ionization (ESI) under different conditions. The influence of the concentration of organic modifier (MeOH); mobile phase addi ...

2022

Strength-promoting mechanism of alkanolamines on limestone-calcined clay cement and the role of sulfate

Karen Scrivener, François Henri Avet, Wilasinee Hanpongpun, Xuerun Li, Hong Huang

This paper reports the strength-promoting mechanism of alkanolamines on limestone-calcined clay cement (LC3). The hydration kinetics, phase formation and microstructure of LC3 with triethanolamine (TEA) or triisopropanolamine (TIPA) were investigated. TEA ...

Pergamon-Elsevier Science Ltd2021

The Politics of Participatory Sustainability Assessments: An Analysis of Power

Livia Bianca Fritz, Franziska Meinherz

The participation of societal actors has been advanced as the gold standard of sustainability assessment processes and is thought essential to dealing with the plurality of normative claims surrounding sustainability and the need to take decisions in a con ...

Cambridge University Press2020

Actor neural networks for the robust control of partially measured nonlinear systems showcased for image propagation through diffuse media

Navid Borhani, Demetri Psaltis, Christophe Moser, Damien Claude-Marie Loterie, Babak Rahmani, Eirini Kakkava, Ugur Tegin

The output of physical systems, such as the scrambled pattern formed by shining the spot of a laser pointer through fog, is often easily accessible by direct measurements. However, selection of the input of such a system to obtain a desired output is diffi ...

SPRINGERNATURE2020

Limestone calcined clay cements (LC3): raw material processing, sulfate balance and hydration kinetics

Franco Alberto Zunino Sommariva

Limestone calcined clay cements (LC3) are blended cements that combine clinker, limestone, calcined clay and gypsum. The availability of the materials required to produce LC3 and the good performance that it achieves, makes LC3 suitable as a sustainable re ...

EPFL2020

Scattering HCl Molecules from Au(111) and Ag(111) Surfaces

Jan Daniel Geweke

In this thesis, I present an experimental molecular beam surface scattering study of dynamical processes involved when HCl molecules are scattered from Au(111) and Ag(111) surfaces. I investigated vibrational excitation, translational inelasticity and diss ...

EPFL2019

Electrochemical Co-Deposition of Gold and Carbon Nanocapsules from a Colloidal Suspension

Stefano Mischler

This paper shows the preparation of a gold suspension containing carbon nanocapsules and their co-deposition from the colloidal galvanic bath on a nickel electrode to obtain gold/nanocapsules composite coatings. The incorporation of the nanocapsules was co ...

ELECTROCHEMICAL SOC INC2019

One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

Nicolai Cramer, Coralie Danielle Annick Duchemin

N-Enoxyimides have become attractive substrates for novel catalytic transformations, yet their tedious multi-step synthesis hampers full exploitation of their synthetic potential. We report a gold(I)-catalyzed protocol to access N-enoxyimides from simple a ...

2019

Hydrothermally Stable Sulfonated Carbons as Solid Acid Catalysts for the Hydrolysis of Lignocellulose

David Ferdinand Scholz

The recycling of homogeneous acids imposes great challenges to the feasibility of lignocellulose hydrolysis processes. Although heterogeneous catalysts would offer a perspective to circumvent these challenges, conventional solid acids are instable under th ...

EPFL2019

Effects of water-soluble organic carbon on aerosol pH

Athanasios Nenes

Water-soluble organic carbon (WSOC) is a ubiquitous and significant fraction of fine particulate matter. Despite advances in aerosol thermodynamic equilibrium models, there is limited understanding on the comprehensive impacts of WSOC on aerosol acidity (p ...

Copernicus GmbH2019

Rapid, Selective Extraction of Trace Amounts of Gold from Complex Water Mixtures with a Metal-Organic Framework (MOF)/Polymer Composite

Emad Oveisi, Natalia Gasilova, Daniel Teav Sun, Wendy Lee Queen, Shuliang Yang

With the ever-increasing production of electronics, there is an ensuing need for gold extraction from sources other than virgin mines. Currently, there are no technologies reported to date that can effectively and selectively concentrate ultratrace amounts ...

AMER CHEMICAL SOC2018

Nanoparticle on mirror plasmonic nanostructure for molecular cavity optomechanics

Christophe Marcel Georges Galland, Nils Kipfer, Tianqi Zhu, Aqeel Ahmed, Santiago Tarrago Velez

The plasmonic response of gold can be utilized to enhance the incident electromagnetic (EM) field by several orders of magnitude. When a gold nanoparticle is placed in close proximity to a gold film, the incident field can excite a deeply confined plasmon, ...

IEEE2018

Recent Advances in the Synthesis and Applications of Multimodal Gold-Iron Nanoparticles

Francesco Stellacci

Bimetallic particles based on gold and iron have been gathering increasing interest in biomedical applications because of the synergic combination of the plasmonic features of the inert gold component with the magnetic properties of the iron or iron oxide ...

Bentham Science Publishers2017

Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: new insights into the reaction mechanism

Jérôme Waser, Yifan Li, Paola Caramenti

Gold-catalyzed domino processes constitute a useful alternative to C-H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynyl ...

2017

Limestone reaction in calcium aluminate cement–calcium sulfate systems

Karen Scrivener, Julien Bizzozero

This paper reports a study of ternary blends composed of calcium aluminate cement, calcium sulfate hemihydrate and limestone. Compressive strength tests and hydration kinetics were studied as a function of limestone and calcium sulfate content. The phase e ...

Pergamon-Elsevier Science Ltd2015

Application of Image Analysis Based on SEM and Chemical Mapping on PC Mortars under Sulfate Attack

Cheng Yu, Wei Sun

The degradation mechanisms of cementitious materials exposed to sulfate solutions have been controversial, despite considerable research. In this paper, two methodologies of image analysis based on scanning electron microscope and chemical mapping are used ...

Journal Wuhan Univ Technology2014