Publications associées à Distribution de temps de séjour

Flowing Gas Experiments Reveal Mechanistic Details of Interfacial Reactions on a Molecular Level at Knudsen Flow Conditions

Christian Ludwig, Michel Rossi, Riccardo Iannarelli

Knudsen flow experiments and its interpretation in terms of adsorption/desorption kinetics as well as quantitative uptake on substrates of interest is presented together with the description of critical design parameters of the Knudsen Flow Reactor (KFR). ...

2022

Model-based scale-up of a continuously operated consolidated bioprocess based on a microbial consortium for the production of ethanol

David Beat Dempfle

This work demonstrated that consolidated bioprocessing is a promising concept for conversion of lignocellulose to ethanol at industrial scale. CBP offers great cost saving potential, is feasible to be operated continuously and may be scaled up due to exten ...

EPFL2022

A generalised water retention model with soil fabric evolution

Lyesse Laloui, Angelica Tuttolomondo, Yafei Qiao, Xingbang Lu

This paper introduces a novel soil water retention curve model that considers two different mechanisms of water retention –namely capillarity and adsorption – and their evolution with soil fabric along a generalized stress path. The model is formulated bas ...

2021

Mechanical energy budget and mixing efficiency for a radiatively heated ice-covered waterbody

Alfred Johny Wüest, Damien Bouffard, Hugo Nicolás Ulloa Sánchez

Ice-covered waterbodies are far from being quiescent systems. In this paper, we investigate ice-covered freshwater basins heated by solar radiation that penetrates across waters with temperatures below or near the temperature of maximum density. In this sc ...

Cambridge University Press2018

Supercritical CO2 injection and residence time in fluid-saturated rocks: Evidence for CO2 and mineral dissolution and effects on rock integrity

Lucas Xan Pimienta, Ke Liu

CO2 injection and storage in geological reservoirs is an attractive prospect for mitigating the anthropogenic production of greenhouse gases and global warming. The technology could lead to mineral precipitation and therefore stable storage over geological ...

Elsevier Sci Ltd2017

Fast Estimation of Plant Steady State, with Application to Static RTO

Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Diogo Filipe Mateus Rodrigues

Experimental assessment or prediction of plant steady state is important for many applications in the area of modeling and operation of continuous processes. For example, the iterative implementation of static real-time optimization requires reaching stead ...

2016

Experiments in hydrologic solute transport

Pierre Claude Jean Queloz

This thesis deal with experimental, field and modeling studies on reactive solute transport within hydrologic control volumes. The substances used in open environments for plant protection and other purposes are likely to be flushed by rainfall and enter i ...

EPFL2015

Practical silicon deposition rules derived from silane monitoring during plasma-enhanced chemical vapor deposition

Christophe Ballif, Stefaan De Wolf, Bénédicte Demaurex

We clarify the difference between the SiH4 consumption efficiency eta and the SiH4 depletion fraction D, as measured in the pumping line and the actual reactor of an industrial plasma-enhanced chemical vapor deposition system. In the absence of significant ...

American Institute of Physics2015

Long-term organic carbon turnover rates in natural and semi-natural topsoils

Robert Thomas Edmund Mills

We combined published and new radiocarbon and ancillary data for uncultivated topsoils (typically 15 cm depth), to make two databases, one for the United Kingdom (133 sites), and one global (114 sites). Forest topsoils are significantly higher in radiocarb ...

Springer2014

Intensification of slow reversible chemical transformation: carboxylation of resorcinol as a case study

Lioubov Kiwi, Charline Berguerand, Anne-Laure Dessimoz

Conjugated kinetic and thermodynamic modeling is suggested as a suitable approach to identify a novel process window (NPW) for the intensification of slow reversible reactions. The aqueous Kolbe-Schmitt synthesis of beta-resorcylic acid is taken as a model ...

De Gruyter2013

Kinematics of age mixing in advection-dispersion models

Andrea Rinaldo, Paolo Benettin, Gianluca Botter

This paper investigates age mixing processes arising in advection-dispersion models, where large-scale travel and residence time distributions can be explicitly calculated based on the underlying velocity field. In particular, we analyze spatially integrat ...

American Geophysical Union2013

Heat Management for Process Intensification of Fast Exothermic Reactions in Microstructured Reactors

Julien Haber

Nowadays, the production in fine chemical and pharmaceutical industry is mostly carried out in large scale batch reactors having typically dimensions of a few meters to satisfy the demand of the market. Even though this technology has been widely used and ...

EPFL2013

An investigation into the water retention behaviour of deformable soils

Lyesse Laloui, Alessio Ferrari, Mathieu Nuth, Simon Salager

The paper presents an experimental and modelling approach for the soil water retention behaviour of two deformable soils. The objective is to investigate the physical mechanisms that govern the soil water retention properties and to propose a constitutive ...

National Research Council Canada2013

The importance of hydraulic groundwater theory in catchment hydrology: The legacy of Wilfried Brutsaert and Jean-Yves Parlange

Alexis Berne

Based on a literature overview, this paper summarizes the impact and legacy of the contributions of Wilfried Brutsaert and Jean-Yves Parlange (Cornell University) with respect to the current state-of-the-art understanding in hydraulic groundwater theory. F ...

American Geophysical Union2013

Effective Heat and Mass Transport Properties of Anisotropic Porous Ceria for Solar Thermochemical Fuel Generation

Sophia Haussener, Aldo Steinfeld

High-resolution X-ray computed tomography is employed to obtain the exact 3D geometrical configuration of porous anisotropic ceria applied in solar-driven thermochemical cycles for splitting H2O and CO2. The tomography data are, in turn, used in direct por ...

MDPI2012

Catchment travel time distributions and water flow in soils

Andrea Rinaldo, Enrico Bertuzzo, Ludovico Nicotina, Gianluca Botter

Many details about the flow of water in soils in a hillslope are unknowable given current technologies. One way of learning about the bulk effects of water velocity distributions on hillslopes is through the use of tracers. However, this paper will demonst ...

2011

Impact of a large tropical reservoir on riverine transport of sediment, carbon, and nutrients to downstream wetlands

Alfred Johny Wüest, Bernhard Wehrli

Large dams can have major ecological and biogeochemical impacts on downstream ecosystems such as wetlands and riparian habitats. We examined sediment removal and carbon (C), nitrogen (N), and phosphorus (P) cycling in Itezhi-Tezhi Reservoir (ITT; area = 36 ...

Amer Geophysical Union2011

Catchment residence and travel time distributions: The master equation

Andrea Rinaldo, Enrico Bertuzzo, Gianluca Botter

The probability density functions (pdf's) of travel and residence times are key descriptors of the mechanisms through which catchments retain and release old and event water, transporting solutes to receiving water bodies. In this paper we analyze theoreti ...

American Geophysical Union2011

Transport in the hydrologic response: Travel time distributions, soil moisture dynamics, and the old water paradox

Andrea Rinaldo, Enrico Bertuzzo, Gianluca Botter

We propose a mathematical framework for the general definition and computation of travel time distributions defined by the closure of a catchment control volume, where the input flux is an arbitrary rainfall pattern and the output fluxes are green and blue ...

American Geophysical Union2010

Powder formation in SiH[sub 4]–H[sub 2] discharge in large area capacitively coupled reactors: A study of the combined effect of interelectrode distance and pressure

Christoph Hollenstein, Benjamin Strahm

One of the main challenges for silicon thin film deposition for solar cell applications is to achieve high rate deposition in order to reduce the manufacturing costs. However, when silane and hydrogen are used as precursor gas in parallel plate plasma-enha ...

American Institute of Physics2010